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Contamination of dab (Limanda limanda) with explosive chemicals leaking from marine dumped munition

Description: Conventional munition dumped into the North Sea and the Baltic Sea close to the German coastline is corroding. A major concern is that biota, including fish, take up toxic explosives leaking into marine environments. With the present study, we investigated bile fluids of fish living in close proximity to munition dumping sites for the explosives 2,4,6-trinitrotoluene (TNT), its metabolites 2-amino-4,6-dinitrolouene and 4-amino-2,6-dinitrolouene as well as octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) using HPLC-MS/MS (high performance liquid chromatography with mass selective detection) as device. The flat fish species common dab (Limanda limanda) was used as a model, since it lives in the vicinity of dumping sites and exhibits minor migratory activity.

Global identifier:

Doi(
    "10.1594/PANGAEA.968913",
)

Types:
DataMeasurements(
    DataMeasurements {
        domain: Unspecified,
        station: None,
        measured_variables: [
            "Cruise/expedition",
            "DATE/TIME",
            "DEPTH, water",
            "Event label",
            "LATITUDE",
            "LONGITUDE",
            "Limanda limanda, age",
            "Limanda limanda, bile, 2,4,6-trinitrotoluene",
            "Limanda limanda, bile, 2-amino-4,6-dinitrolouene",
            "Limanda limanda, bile, 4-amino-2,6-dinitrolouene",
            "Limanda limanda, bile, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine",
            "Limanda limanda, sex",
            "Location",
            "Location ID",
        ],
        methods: [
            "Ultra high performance liquid chromatograph (UHPLC), Agilent, 1290 Infinity; coupled with Triple quadrupole tandem mass spectrometer (LC-MS/MS), SCIEX, QTRAP 5500",
        ],
    },
)

Tags: Munitionsaltlast ? Fisch ? Munition ? Geografische Koordinaten ? Deponie ? Kind ? Trinitrotoluol ? Chemikalien ? Studie ? Wohnung ? Wasser ? Nordsee ? Ostsee ? HMX ? bile ? metabolites ?

Region: Oste Reef Light Vessel (historical) Spiekeroog Borkum Haffkrug Kolberger Heide Langeoog Schleimünde Oberförsterei Wetter-West Weser mouth Wangerooge North, Minsener Oog Wangerooge North Spiekeroog fairway North Pelzerhaken East Norderney North

Bounding boxes: 6.674067° .. 10.91395° x 53.699183° .. 54.71645° 6.69153° .. 6.69153° x 53.58094° .. 53.58094° 8.71667° .. 8.71667° x 50.9° .. 50.9°

License: Creative Commons Namensnennung 4.0

Language: Englisch/English

Organisations

Persons

Issued: 2024-07-15

Modified: 2026-02-17

Time ranges: 2021-07-15 - 2023-07-12

Resources

Status

Quality score

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