Description: Conventional munition dumped into the North Sea and the Baltic Sea close to the German coastline is corroding. A major concern is that biota, including fish, take up toxic explosives leaking into marine environments. With the present study, we investigated bile fluids of fish living in close proximity to munition dumping sites for the explosives 2,4,6-trinitrotoluene (TNT), its metabolites 2-amino-4,6-dinitrolouene and 4-amino-2,6-dinitrolouene as well as octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) using HPLC-MS/MS (high performance liquid chromatography with mass selective detection) as device. The flat fish species common dab (Limanda limanda) was used as a model, since it lives in the vicinity of dumping sites and exhibits minor migratory activity.
Global identifier:
Doi(
"10.1594/PANGAEA.968913",
)
Measurements {
domain: Unspecified,
station: None,
measured_variables: [
"Event label",
"LATITUDE",
"LONGITUDE",
"DEPTH, water",
"DATE/TIME",
"Cruise/expedition",
"Location ID",
"Location",
"Limanda limanda, sex",
"Limanda limanda, age",
"Limanda limanda, bile, 2,4,6-trinitrotoluene",
"Limanda limanda, bile, 2-amino-4,6-dinitrolouene",
"Limanda limanda, bile, 4-amino-2,6-dinitrolouene",
"Limanda limanda, bile, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine",
],
methods: [
"Ultra high performance liquid chromatograph (UHPLC), Agilent, 1290 Infinity; coupled with Triple quadrupole tandem mass spectrometer (LC-MS/MS), SCIEX, QTRAP 5500",
"Ultra high performance liquid chromatograph (UHPLC), Agilent, 1290 Infinity; coupled with Triple quadrupole tandem mass spectrometer (LC-MS/MS), SCIEX, QTRAP 5500",
"Ultra high performance liquid chromatograph (UHPLC), Agilent, 1290 Infinity; coupled with Triple quadrupole tandem mass spectrometer (LC-MS/MS), SCIEX, QTRAP 5500",
"Ultra high performance liquid chromatograph (UHPLC), Agilent, 1290 Infinity; coupled with Triple quadrupole tandem mass spectrometer (LC-MS/MS), SCIEX, QTRAP 5500",
],
}
Dataset
Origins: /Wissenschaft/Helmholtz-Gemeinschaft/HEREON /Wissenschaft/PANGAEA
Tags: Wohnung ? Munitionsaltlast ? Fisch ? Munition ? Geografische Koordinaten ? Deponie ? Kind ? Trinitrotoluol ? Chemikalien ? Standortwahl ? Studie ? Wasser ? Nordsee ? Ostsee ? HMX ? bile ? metabolites ?
Region: Oste Reef Light Vessel (historical) Kolberger Heide Langeoog Minsener Oog Hafen von Norderney Schleimünde Insel Spiekeroog Wangerooge Weser mouth Spiekeroog fairway North Pelzerhaken East Heligoland West-North-West Haffkrug North Borkum
Bounding boxes: 6.674067° .. 10.91395° x 53.699183° .. 54.71645°
License: cc-by/4.0
Language: Englisch/English
Issued: 2024-07-15
Modified: 2024-07-15
Time ranges: 2021-07-15 - 2023-07-12
Accessed 1 times.