FP1-ENVPROT 4C, Entwicklung automatisierter chemischer Sensoren fuer Messungen der trockenen Deposition nach der Gradientenmethode

Description: Die Bestimmung der trockenen Deposition von Spurenstoffen nach der Methode der Messung des vertikalen Konzentrationsgradienten erfordert Nachweisgeraete mit grosser Empfindlichkeit (sub-ppbv-Bereich), Spurenstoffspezifitaet und besonders hoher Genauigkeit (unter 3 Prozent rel). Denudersysteme zum Nachweis von HNO3, HNO2, NH3, HCl, HF, H2O2, SO2, CH2O genuegen den Anforderungen bezueglich der geforderten Empfindlichkeit und Spezifitaet. Durch die Weiter-, Neuentwicklung bzw Automatisierung der sogenannten 'Thermodenuder' bzw 'rotierender Fluessigkeitsfilmdenuder' soll die erforderliche Genauigkeit und damit der (Langzeit-)Einsatz dieser Systeme fuer Gradientenmessungen erreicht werden. Der Vergleich dieser Systeme mit entsprechenden Standardmessgeraeten (Spurengasmonitore, 'Tunable-Diode-Laser'-, 'Eddy Correlation'-Systeme) wird unter Feldbedingungen durchgefuehrt.

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Origins: /Bund/UBA/UFORDAT

Tags: Wasserstoffperoxid ? Ammoniak ? Chlorwasserstoff ? Fluorwasserstoff ? Messgerät ? Immissionsmesstechnik ? Salpetersäure ? Salpetrige Säure ? Sensor ? Spurengas ? Formaldehyd ? Trockene Deposition ? Schadstoffdeposition ? Schwefeldioxid ? Spurenstoff ? Staubniederschlag ? Automatisierung ? Bestimmungsmethode ? Messverfahren ? Vergleichsanalyse ? Gradientenmethode ? Messgenauigkeit ? Schadstoffnachweis ? Trockene-Deposition ?

Region: Bavaria

Bounding boxes: 11.5° .. 11.5° x 49° .. 49°

License: cc-by-nc-nd/4.0

Language: Deutsch

Organisations

• CNR Roma, Istituto sull'Inquinamento Atmosferico (Mitwirkung)
• Fraunhofer-Gesellschaft zur Förderung der Angewandten Forschung, Fraunhofer-Institut für Atmosphärische Umweltforschung (Projektverantwortung)
• Kommission der Europäischen Gemeinschaften Brüssel (Finanzielle Förderung)
• Kommission der Europäischen Gemeinschaften, Generaldirektion XII Wissenschaft, Forschung und Entwicklung (Mitwirkung)
• Netherlands Energy Research Foundation , Stichting Energie-onderzoek Centrum Nederland (Mitwirkung)
• Umweltbundesamt (Bereitstellung)

Time ranges: 1988-03-01 - 1991-08-30

Alternatives

• Language: Englisch/English
  Title: Development of automated chemical sensors for measurements of dry deposition according to the gradient method
  Description: Objective: To develop automated denuder techniques for dry deposition measurements of acidic substances: General information: two different types of denuder are developed to measure dry deposition of so2, hno3, hno2, nh3, h2so4 and hcl: thermo denuder and wet denuder system. Both denuder systems are tested against other methods at different locations in southern Bavaria, which are representative of many other locations with extensive forest damage. The project includes proposal 275 of Fraunhofer Institute, Garmisch-Partenkirchen, entrusted with the overall coordination, proposal 418 of ecn petten and proposal 354 of cnr rome. The development of these techniques may be the future basis to perform spatially wide spread dry deposition measurements during long time periods. Achievements: Research has been carried out into the development of new and/or the improvement of already existing denuder based chemical sensors for dry deposition measurements in the field by a micrometeorological (gradient) technique. The development or improvement was limited to: the automated rotating wet denuder; the continuous flow rotating denuder technique; to the automated thermo denuder technique, the nonautomated annular (differential) denuder technique. Improvement of denuder and micrometeorological systems involved: using a set up consisting of 1 sodium chloride and 2 sodium carbonate glycerol coated annular denuders fitted in series; the completion of the wet denuder technique by a portable ion chromatography system for online analysis of sulphate, nitrate, nitrite and chlorine ions in samples of the wet denuder system (this further automation is the final improvement step for the application of the wet denuder technique in long term studies of dry deposition of sulphur dioxide, nitric acid, ammonia and hydrochloric acid); improvement of an existing multilevel dry and wet bulb temperature measurement system. As far as the nonautomated (differential) annular denuder technique is concerned, two new methods were developed. The general conclusion from intercomparisions is that the results of the determined gaseous pollutants (by denuder and filter pack techniques) agree sufficiently good. For the filter pack technique, which was not specifically addressed in this research, the agreement for particulate matter determination was not satisfactory. Corresponding improvement is definitely needed, since vertical fluxes of gaseous and particulate nitrate and ammonia could be strongly interrelated. Field experiments were then carried out on dry deposition fluxes. In conclusion, the precision of the denuder systems for the acidifying compounds such as ammonia, nitric acid, nitrous acid, ammonium nitrate and sulphur dioxide was 5 per cent or better, which allows the mea surement of atmosphere surface exchange fluxes by the gradient method. https://ufordat.uba.de/UFORDAT/pages/PublicRedirect.aspx?TYP=PR&DSNR=27072

Status

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