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Kinetic and Thermodynamic Investigations of the Complexation of Heavy Metal Ions to well Defined Components of Soil

Description: Das Projekt "Kinetic and Thermodynamic Investigations of the Complexation of Heavy Metal Ions to well Defined Components of Soil" wird/wurde gefördert durch: Deutscher Akademischer Austausch Dienst / Forschungszentrum Jülich GmbH / Universität Bielefeld, GFT e.V.. Es wird/wurde ausgeführt durch: Universität Bielefeld, Fakultät für Chemie, Arbeitsgruppe Physikalische Chemie II.The mobility of toxic metal ions in nature is to a great extent controlled by complexation reactions at natural polyelectrolytes as humic acids, clay minerals or polycarboxylates. In all those systems the metal ions compete with the ubiquitous protons for the binding sites. Due to the very complex structure of the polyelectrolytes, the binding mechanism and the equilibria involved can be obtaines only by the evaluation of equilibrium combined with kinetic measurements. In this project we study the binding of nickel and cadmium ions to humic acids and clay minerals and discuss the results by comparing them with results obtained for model ligands as di- and tricarboxylates and salycilate.

Types:
SupportProgram

Origin: /Bund/UBA/UFORDAT

Tags: Nickel ? Portugal ? Cadmium ? Huminstoff ? Schwermetall ? Komplexverbindung ? Schwermetallmobilisierung ? Metall ? Bodenhorizont ? Ionen ? Standortwahl ? Studie ? Komplexbildung ? Chemische Reaktion ? Mineral ? Chemisch-physikalische Behandlung ? Braganca ? Clay-Minerals ? Heavy-Metal-Ions ? Humic-Acid ? Polyelectrolytes ?

Region: Nordrhein-Westfalen

Bounding boxes: 6.76339° .. 6.76339° x 51.21895° .. 51.21895°

License: cc-by-nc-nd/4.0

Language: Englisch/English

Organisations

Time ranges: 1997-07-01 - 2000-06-30

Status

Quality score

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