API src

Found 69 results.

Similar terms

s/azetat/Acetat/gi

Fabrik\Silizium-Modul-mono-DE-2005

Herstellung von Silizium-PV-Modulen aus monokristallinen Siliziumzellen, Daten nach #1, Tabelle VI. Solarzellen-, EVA- und Rückenfolienabfall vernachlässigt Folgende Daten beziehen sich auf die Herstellung eines Moduls mit 175Wp. Fläche 1,25 m², Gewicht 17,4 kg davon Solar cells 0,760424 kg Aluminium profile 3,8 kg Polyphenylenoxid 0,2 kg Glass sheet, low iron, tempered 11,4 kg Ethyl Vinyl Acetate 1,3 kg zusätzlicher Reststoff Glas (0,01 kg/kg), der in Recycling geht Auslastung: 5000h/a Brenn-/Einsatzstoff: Rohstoffe gesicherte Leistung: 100% Jahr: 2005 Lebensdauer: 20a Leistung: 1t/h Nutzungsgrad: 2290% Produkt: Rohstoffe

Fabrik\Silizium-Modul-multi-DE-2005

Herstellung von Silizium-PV-Modulen aus multikristallinen Siliziumzellen, Daten nach #1, Tabelle VI. Solarzellen-, EVA- und Rückenfolienabfall vernachlässigt zusätzlicher Reststoff Glas (0,01 kg/kg), der in Recycling geht Die folgenden Daten beziehen sich auf die Hersellung eines Modul mit einer Leistung von 165Wp. Fläche 1,25 m² Gewicht 17,4 kg Solar cells 0,760424 kg Aluminium profile 3,8 kg Polyphenylenoxid 0,2 kg Glass sheet, low iron, tempered 11,4 kg Ethyl Vinyl Acetate 1,3 kg Auslastung: 5000h/a Brenn-/Einsatzstoff: Rohstoffe gesicherte Leistung: 100% Jahr: 2005 Lebensdauer: 20a Leistung: 1t/h Nutzungsgrad: 2290% Produkt: Rohstoffe

Toxicological basic data for the derivation of EU-LCI values for five substances from building products

The subject of this project was the preparation of substance reports for the following compounds: dipropylene glycol mono n(t)-butyl ether (CAS No. 29911-28-2, 35884-42-5, 132739-31-2), 2-(2-hexyloxyethoxy)-ethanol (CAS No. 112-59-4), 1-propenylbenzene (CAS No. 637-50-3, 873-66-5), dipropylene glycol mono methyl ether acetate (CAS No. 88917-22-0) and hydroxyacetone (CAS No. 116-09-6). For these substances, the toxicological data basis were researched, compiled and evaluated, and EU-LCI values were proposed. The EU-LCI values form the basis for assessing health effects of emissions from construction products and allow the harmonisation of the health assessment of construction product emissions throughout Europe. The final EU-LCI values are set by the EU-LCI Working Group, a group of experts from ten European countries, and may differ from the proposals contained in this report. The EU-LCI Working Group is currently developing a harmonised European list of substances and their associated emission limits (EU-LCI values). The substance reports developed within this project support and accelerate this process. Veröffentlicht in Texte | 16/2020.

Markt für Essigsäure, ohne Wasser, in 98%iger Lösung

technologyComment of acetaldehyde oxidation (RER, RoW): Oxidation of acetaldehyde technologyComment of acetic acid production, product in 98% solution state (RER, RoW): The process represents the Celanese process (which is an optimized version of the Monsanto process) in which methanol reacts with carbon monoxide under the influence of a rhodium catalyst. It is assumed that 50% of the off-gas is burned as fuel, thus VOC emissions are reduced and CO2 is higher. References: Le Berre, C., Serp, P., Kalck, P. and Torrence, G. P. 2014. Acetic Acid. Ullmann's Encyclopedia of Industrial Chemistry. technologyComment of oxidation of butane (RoW): Oxidation of butane technologyComment of oxidation of butane (RER): The liquid-phase oxidation of hydrocarbons is an important process to produce acetic acid, formic acid or methyl acetate. About 43 kg of formic acid is produced per ton of acetic acid. Unreacted hydrocarbons, volatile neutral constituents, and water are separated first from the oxidation product. Formic acid is separated in the next column; azeotropic distillation is generally used for this purpose. The formic acid contains about 2 wt % acetic acid, 5 wt % water, and 3 wt % benzene. Formic acid with a content of about 98 wt % can be produced by further distillation. Reference: Gräfje, H., Körnig, W., Weitz, H.-M., Reiß, W.: Butanediols, Butenediol, and Butynediol, Chapter 1. In: Ullmann's Encyclopedia of Industrial Chemistry, Sev-enth Edition, 2004 Electronic Release (ed. Fiedler E., Grossmann G., Kersebohm D., Weiss G. and Witte C.). 7 th Electronic Release Edition. WileyInterScience, New York, Online-Version under: http://www.mrw.interscience.wiley.com/ueic/articles/a04_455/frame.html

Markt für Ameisensäure

Production mix technologyComment of decarboxylative cyclization of adipic acid (RER): decarboxylative cyclization of adipic acid technologyComment of formic acid production, methyl formate route (RER): The worldwide installed capacity for producing formic acid was about 330 000 t/a in 1988. Synthesis of formic acid by hydrolysis of methyl formate is based on a two-stage process: in the first stage, methanol is carbonylated with carbon monoxide; in the second stage, methyl formate is hydrolyzed to formic acid and methanol. The methanol is returned to the first stage. Although the carbonylation of methanol is relatively problem-free and has been carried out industrially for a long time, only recently has the hydrolysis of methyl formate been developed into an economically feasible process. The main problems are associated with work-up of the hydrolysis mixture. Because of the unfavorable position of the equilibrium, reesterification of methanol and formic acid to methyl formate occurs rapidly during the separation of unreacted methyl formate. Problems also arise in the selection of sufficiently corrosion-resistant materials Carbonylation of Methanol In the two processes mentioned, the first stage involves carbonylation of methanol in the liquid phase with carbon monoxide, in the presence of a basic catalyst: imageUrlTagReplacea0ec6e15-92c8-4d44-82bb-84e90e58b171 As a rule, the catalyst is sodium methoxide. Potassium methoxide has also been proposed as a catalyst; it is more soluble in methyl formate and gives a higher reaction rate. Although fairly high pressures were initially preferred, carbonylation is carried out in new plants at lower pressure. Under these conditions, reaction temperature and catalyst concentration must be increased to achieve acceptable conversion. According to published data, ca. 4.5 MPa, 80 °C, and 2.5 wt % sodium methoxide are employed. About 95 % carbon monoxide, but only about 30 % methanol, is converted under these circumstances. Nearly quantitative conversion of methanol to methyl formate can, nevertheless, be achieved by recycling the unreacted methanol. The carbonylation of methanol is an equilibrium reaction. The reaction rate can be raised by increasing the temperature, the carbon monoxide partial pressure, the catalyst concentration, and the interface between gas and liquid. To synthesize methyl formate, gas mixtures with a low proportion of carbon monoxide must first be concentrated. In a side reaction, sodium methoxide reacts with methyl formate to form sodium formate and dimethyl ether, and becomes inactivated. The substances used must be anhydrous; otherwise, sodium formate is precipitated to an increasing extent. Sodium formate is considerably less soluble in methyl formate than in methanol. The risk of encrustation and blockage due to precipitation of sodium formate can be reduced by adding poly(ethylene glycol). The carbon monoxide used must contain only a small amount of carbon dioxide; otherwise, the catalytically inactive carbonate is precipitated. Basic catalysts may reverse the reaction, and methyl formate decomposes into methanol and carbon monoxide. Therefore, undecomposed sodium methoxide in the methyl formate must be neutralized. Hydrolysis of Methyl Formate In the second stage, the methyl formate obtained is hydrolyzed: imageUrlTagReplace2ddc19c0-905f-42c3-b14c-e68332befec9 The equilibrium constant for methyl formate hydrolysis depends on the water: ester ratio. With a molar ratio of 1, the constant is 0.14, but with a water: methyl formate molar ratio of 15, it is 0.24. Because of the unfavorable position of this equilibrium, a large excess of either water or methyl formate must be used to obtain an economically worthwhile methyl formate conversion. If methyl formate and water are used in a molar ratio of 1 : 1, the conversion is only 30 %, but if the molar ratio of water to methyl formate is increased to 5 – 6, the conversion of methyl formate rises to 60 %. However, a dilute aqueous solution of formic acid is obtained this way, and excess water must be removed from the formic acid with the expenditure of as little energy as possible. Another way to overcome the unfavorable position of the equilibrium is to hydrolyze methyl formate in the presence of a tertiary amine, e.g., 1-(n-pentyl)imidazole. The base forms a salt-like compound with formic acid; therefore, the concentration of free formic acid decreases and the hydrolysis equilibrium is shifted in the direction of products. In a subsequent step formic acid can be distilled from the base without decomposition. A two-stage hydrolysis has been suggested, in which a water-soluble formamide is used in the second stage; this forms a salt-like compound with formic acid. It also shifts the equilibrium in the direction of formic acid. To keep undesirable reesterification as low as possible, the time of direct contact between methanol and formic acid must be as short as possible, and separation must be carried out at the lowest possible temperature. Introduction of methyl formate into the lower part of the column in which lower boiling methyl formate and methanol are separated from water and formic acid, has also been suggested. This largely prevents reesterification because of the excess methyl formate present in the critical region of the column. Dehydration of the Hydrolysis Mixture Formic acid is marketed in concentrations exceeding 85 wt %; therefore, dehydration of the hydrolysis mixture is an important step in the production of formic acid from methyl formate. For dehydration, the azeotropic point must be overcome. The concentration of formic acid in the azeotropic mixture increases if distillation is carried out under pressure, but the higher boiling point at high pressure also increases the decomposition rate of formic acid. At the same time, the selection of sufficiently corrosion-resistant materials presents considerable problems. A number of entrainers have been proposed for azeotropic distillation. Reference: Gräfje, H., Körnig, W., Weitz, H.-M., Reiß, W.: Butanediols, Butenediol, and Butynediol, Chapter 1. In: Ullmann's Encyclopedia of Industrial Chemistry, Sev-enth Edition, 2004 Electronic Release (ed. Fiedler E., Grossmann G., Kersebohm D., Weiss G. and Witte C.). 7 th Electronic Release Edition. WileyInterScience, New York, Online-Version under: http://www.mrw.interscience.wiley.com/ueic/articles/a04_455/frame.html technologyComment of oxidation of butane (RER): The liquid-phase oxidation of hydrocarbons is an important process to produce acetic acid, formic acid or methyl acetate. About 43 kg of formic acid is produced per ton of acetic acid. Unreacted hydrocarbons, volatile neutral constituents, and water are separated first from the oxidation product. Formic acid is separated in the next column; azeotropic distillation is generally used for this purpose. The formic acid contains about 2 wt % acetic acid, 5 wt % water, and 3 wt % benzene. Formic acid with a content of about 98 wt % can be produced by further distillation. Reference: Gräfje, H., Körnig, W., Weitz, H.-M., Reiß, W.: Butanediols, Butenediol, and Butynediol, Chapter 1. In: Ullmann's Encyclopedia of Industrial Chemistry, Sev-enth Edition, 2004 Electronic Release (ed. Fiedler E., Grossmann G., Kersebohm D., Weiss G. and Witte C.). 7 th Electronic Release Edition. WileyInterScience, New York, Online-Version under: http://www.mrw.interscience.wiley.com/ueic/articles/a04_455/frame.html

Extrahierbare anorganische Komponenten aus Böden

Die Extraktion anorganischer Komponenten aus Böden ergibt aus ihrer Untersuchung eine spezielle Form bodenanalytischen Daten. Es handelt sich um bodenchemische Daten. Sie werden im Labor des LUNG M-V erhoben (Meß-Rohdaten, kombinierte Daten, Meßreihen, statistische Aussagen über Daten). Sie sind verteilt abgelegt in Laborbüchern, Rohdatenfiles der Meßgeräte, Spreadsheet-Daten. Es existieren Daten zu den Extraktionsmitteln Doppellactat, Dithionit, Reinstwasser, Oxalat, Calciumchlorid, Strontiumchlorid und Azetaten.

Accuracy of methane emissions predicted from milk mid-infrared spectra and measured by laser methane detectors in Brown Swiss dairy cows

Since heritability of CH4 emissions in ruminants was demonstrated, various attempts to generate large individual animal CH4 data sets have been initiated. Predicting individual CH4 emissions based on equations using milk mid-infrared (MIR) spectra is currently considered promising as a low-cost proxy. However, the CH4 emission predicted by MIR in individuals still has to be confirmed by measurements. In addition, it remains unclear how low CH4 emitting cows differ in intake, digestion, and efficiency from high CH4 emitters. In the current study, putatively low and putatively high CH4 emitting Brown Swiss cows were selected from the entire Swiss herdbook population (176,611 cows), using an MIR-based prediction equation. Eventually, 15 low and 15 high CH4 emitters from 29 different farms were chosen for a respiration chamber (RC) experiment in which all cows were fed the same forage-based diet. Several traits related to intake, digestion, and efficiency were quantified over 8 d, and CH4 emission was measured in 4 open circuit RC. Daily CH4 emissions were also estimated using data from 2 laser CH4 detectors (LMD). The MIR-predicted CH4 production (g/d) was quite constant in low and high emission categories, in individuals across sites (home farm, experimental station), and within equations (first available and refined versions). The variation of the MIR-predicted values was substantially lower using the refined equation. However, the predicted low and high emitting cows (n = 28) did not differ on average in daily CH4 emissions measured either with RC or estimated using LMD, and no correlation was found between CH4 predictions (MIR) and CH4 emissions measured in RC. When individuals were recategorized based on CH4 yield measured in RC, differences between categories of 10 low and 10 high CH4 emitters were about 20%. Low CH4 emitting cows had a higher feed intake, milk yield, and residual feed intake, but they differed only weakly in eating pattern and digesta mean retention times. Low CH4 emitters were characterized by lower acetate and higher propionate proportions of total ruminal volatile fatty acids. We concluded that the current MIR-based CH4 predictions are not accurate enough to be implemented in breeding programs for cows fed forage-based diets. In addition, low CH4 emitting cows have to be characterized in more detail using mechanistic studies to clarify in more detail the properties that explain the functional differences found in comparison with other cows. © 2019 American Dairy Science Association®

Bekanntmachung gemäß §5 UVPG - OQ Chemicals Produktion GmbH & Co.KG

Die Firma OQ Chemicals Produktion GmbH & Co. KG, Paul-Baumann-Straße 1 in 45772 Marl hat die Genehmigung zur wesentlichen Änderung und zum Betrieb der Acetate- und Harzfabrik zur Herstellung von Acetaten und Harz auf dem Grundstück Paul-Baumann-Straße 1 in 45772 Marl (Gemarkung Marl, Flure 53, 63, Flurstücke 15, 30, 129) beantragt. Gegenstand des Antrages ist die Umsetzung von Maßnahmen aus dem überarbeiteten Sicherheitskonzept und die Erhöhung der Kapazität von 4.000 t/a auf 6.000 t/a Harze.

Wesentliche Änderung einer Anlage zum Polyolrecycling in Oberroßbach, Fa. Soprema GmbH

Wesentliche Änderung einer Anlage zur Herstellung von Stoffen oder Stoffgruppen durch chemische, biochemische oder biologische Umwandlung in industriellem Umfang zur Herstellung von sauerstoffhaltigen Kohlenwasserstoffen wie Alkohole, Aldehyde, Ketone, Carbonsäuren, Ester, Acetate, Ether, Peroxide, Epoxide nach Nr. 4.1.2 des Anhangs 1 der 4. BImSchV in der Gemarkung Oberroßbach, Flur 7, Flurstücke 109/9 sowie 75/1

Änderungsgenehmigungsverfahren für die Chemische Synthese der 3M Deutschland GmbH, Standort Seefeld

Die 3M Deutschland GmbH hat mit Antrag vom 02.10.2019 die immissionsschutzrechtliche Änderungsgenehmigung gemäß § 16 Bundes-Immissionsschutzgesetz (BImSchG) für die Inbetriebnahme von 18 weiteren chemischen Verfahren, die zur Herstellung von chemischen Zwischenprodukten dienen, sowie die Anhebung der Chargenanzahl und Änderung der Chargengröße bei einzelnen bereits genehmigten Verfahren in ihrer Betriebseinheit Chemischen Synthese am Standort Seefeld auf dem Grundstück Fl.Nr. 727 Gemarkung Oberalting-Seefeld beantragt. Die Betriebseinheit Chemische Synthese der 3M Deutschland GmbH unterliegt als Anlage zur Herstellung von Stoffen oder Stoffgruppen durch chemische, biochemische oder biologische Umwandlung in industriellem Umfang, insbesondere zur Herstellung von sauerstoffhaltigen Kohlenwasserstoffen wie Alkohole, Aldehyde, Ketone, Carbonsäuren, Ester, Acetate, Ether, Peroxide und Epoxide der immissionsschutzrechtlichen Genehmigungspflicht nach § 4 Abs. 1 BImSchG i. V. m. § 1 Abs. 1 der Verordnung über genehmigungsbedürftige Anlagen (4. BIm-SchV) und Nr. 4.1.2 des Anhangs 1 zur 4. BImSchV. Für die Betriebseinheit Chemische Synthese wurden in der Vergangenheit bereits 161 Verfahren mit unterschiedlichen Chargendurchsätzen genehmigt. Da es sich bei dem Änderungsvorhaben um eine wesentliche Änderung der Chemischen Synthese handelt, ist ein Änderungsgenehmigungsverfahren nach § 16 BImSchG durchzuführen.

1 2 3 4 5 6 7