Der schnelle Fortschritt der elektronischen Geräte erhöht die Nachfrage nach verbesserten Li-Ionen Batterien. Kommerziell erhältliche Li-Zellen nutzen meist Lithiumkobaltoxid für die positive Elektrode. Doch gerade dieses Material ist ein Hindernis für eine weitere Optimierung, insbesondere für eine Kostensenkung. Vor allem für größere Anwendungen wie Hybrid- oder Elektrofahrzeuge müssen alternative Materialen erforscht werden, die billiger, sicherer und umweltverträglicher sind. Daher wird im ISEA derzeit ein neues Forschungsprojekt ins Leben gerufen und die dafür benötigte Infrastruktur geschaffen. Die Forschung wird sich auf die Untersuchung geeigneter Übergangsmetalloxide und Polyanionen konzentrieren, die besonders gut zur Einlagerung von Li-Ionen geeignet sind. Es werden neue Herstellungsverfahren unter Verwendung wässriger Precurser-Substanzen untersucht, die Verbindungen mit überlegenen Eigenschaften erzeugen und außerdem leicht an eine Massenproduktion angepasst werden können. Ziel der Arbeiten ist, preisgünstiges Elektrodenmaterial zu entwickeln, das eine spezifische Energie von über 200 Wh/kg und eine Leistungsdichte von 400 W/kg aufweist. Außerdem werden Arbeiten im Bereich der physikalisch-chemischen Charakterisierung der neuen Materialien stattfinden sowie elektrochemische Analysen der gesamten Zellen- und Batteriesysteme durchgeführt. Das elektrodynamische Verhalten der neuen Zellen wird u. a. mit Hilfe der elektrochemischen Impedanzspektroskopie analysiert, um präzise und zuverlässige Algorithmen für ein späteres Batteriemonitoring im realen Betrieb zu finden.
During the first project period we developed a general approach to quantify soil pore structure based on X-ray micro-tomography Vogel et al. (2010) which is applicable at various scales to cover soil pores larger that 0.05 mm in a representative way. Based on this method we generated equivalent network models to numerically simulate flow and transport of dissolved chemicals. The existing network model was extended to handle reactive transport and infiltration processes which are especially critical for matter flux in soil. The results were compared to experimental findings. The original research question 'what does a particle see on its way through soil' could be answered quantitatively for various boundary conditions including steady state flux and infiltration. However, we identified various critical aspects of the proposed modeling concept which will be in the focus of the second period. This includes 1) the spatial arrangement of interfaces having different quality which is crucial for chemical interactions and pore scale water dynamics, 2) the realistic multiphase dynamics at the pore scale which need to reflect the dynamic pressure and movement of trapped non-wetting phase and 3) the parametrization of structural complexity which need to be developed beyond the measurement of continuous Minkowski functions to allow the development of quantitative relations between structure and function. These aspects will be explored in a joint experiments in cooperation with partners within the SPP.
Terrestrial green algae and cyanobacteria are typical and abundant components of biological soil crusts in the Polar Regions. These communities form water-stable aggregates that have important ecological roles in primary production, nitrogen fixation, nutrient cycling, water retention and stabilization of soils. Although available data on green algae and cyanobacteria are generally very limited for the Arctic and Antarctica, their functional importance as ecosystem developers in nutrient poor environments is regarded as high. Therefore, the main goal of the interdisciplinary project is, for the first time, a precise evaluation of their 1.) Biodiversity as well as of 2.) The infra-specific genetic diversity, 3.) ecophysiological performance and 4.) transcriptomics of the most abundant taxa in biological soil crusts isolated from the Antarctic Peninsula and Arctic Svalbard. Biodiversity will be investigated using a classical culture approach in combination with molecular-taxonomical methods as well as with metagenomics. The infra-specific genetic diversity of the most abundant green algae and cyanobacteria will be studied using fingerprinting techniques, and a range of selected populations characterized in relation to their physiological plasticity. Temperature and water availability, two key environmental factors for terrestrial organisms, are currently changing in Polar Regions due to global warming, and hence their effect on growth and photosynthesis response patterns will be comparatively investigated. The data will indicate whether and how global change influence population structure and ecological performance of key organisms in polar soil crusts, and help to make predictions on the future significance of the ecological functions of these pioneer communities. Such a multiphasic approach has never been applied before to soil algae and cyanobacteria in both Polar Regions, and hence represents one of the key innovations of this proposal.
Whether primordial bodies in the solar system possessed internally-generated dynamos is a fundamental constraint to understand the dynamics and timing of early planetary formation. Paleointensity studies on several meteorites reveal that their host planets possessed magnetic fields within an order-of magnitude of the present Earths field. Interpretation of paleointensity data relies heavily on fundamental knowledge of the magnetic properties of the magnetic carriers, such as the single to multidomain size threshold or how the saturation magnetization varies as a function of grain size, yet very little knowledge exists about these key parameters for some of the main magnetic recorders in meteorites: the iron-nickel alloys. Moreover, most meteorites have experienced some amount of shock during their histories, yet the consequence of even very small stresses on paleointensity data is poorly known.We wish to fill these gaps by magnetically characterizing Fe-Ni alloys as a function of grain size and by determining how absolute and relative paleointensity data are biased by strain levels lower than those petrologically observable (less than 4-5 GPa). For example, our preliminary work shows that an imposed stress of 0.6 GPa will reduce absolute paleointensity estimates by 46Prozent for single domain magnetite-bearing rocks. In general, paleointensity determinations possess inherent disadvantages regarding measurement precision and the inordinate amount of human time investment. We intend to overcome these limitations by extending and improving our fully automated magnetic workstation known as the SushiBar.
The classical point wise Cornell-McGuire probabilistic seismic hazard assessment (PSHA), which is widely used for seismic hazard mapping and development of design codes, does not allow direct estimation of multiple-location hazard for distributed structures and facilities: what is the (annual) probability that specific level of ground motion will be exceeded simultaneously in several sites? It is possible to extent the classical methodology to the multiple sites problem considering also ground-motion correlation. We study multiple-location PSHA, as compared with the classical point wise PSHA, using Monte Carlo simulation. Specific items are:(1) Development of the algorithms for multiple-location PSHA;(2) Analysis of the role of the geometry of multiple sites, correlation of ground motion, and evel of seimicity for multiple-location PSHA;(3) Study of correspondence and differences between multiple-location PSHA and classical point wise PSHA and analysis of possibility of utilization of classical PSHA procedures for simplified multiple-location hazard assessment.The project is innovative because only few attempts have been made so far regarding our research questions.
The development of sustainable and efficient energy conversion processes at interfaces is at the center of the rapidly growing field of basic energy science. How successful this challenge can be addressed will ultimately depend on the acquired degree of molecular-level understanding. In this respect, the severe knowledge gap in electro- or photocatalytic conversions compared to corresponding thermal processes in heterogeneous catalysis is staggering. This discrepancy is most blatant in the present status of predictive-quality, viz. first-principles based modelling in the two fields, which largely owes to multifactorial methodological issues connected with the treatment of the electrochemical environment and the description of the surface redox chemistry driven by the photo-excited charges or external potentials.Successfully tackling these complexities will advance modelling methodology in (photo)electrocatalysis to a similar level as already established in heterogeneous catalysis, with an impact that likely even supersedes the one seen there in the last decade. A corresponding method development is the core objective of the present proposal, with particular emphasis on numerically efficient approaches that will ultimately allow to reach comprehensive microkinetic formulations. Synergistically combining the methodological expertise of the two participating groups we specifically aim to implement and advance implicit and mixed implicit/explicit solvation models, as well as QM/MM approaches to describe energy-related processes at solid-liquid interfaces. With the clear objective to develop general-purpose methodology we will illustrate their use with applications to hydrogen generation through water splitting. Disentangling the electro- resp. photocatalytic effect with respect to the corresponding dark reaction, this concerns both the hydrogen evolution reaction at metal electrodes like Pt and direct water splitting at oxide photocatalysts like TiO2. Through this we expect to arrive at a detailed mechanistic understanding that will culminate in the formulation of comprehensive microkinetic models of the light- or potential-driven redox process. Evaluating these models with kinetic Monte Carlo simulations will unambiguously identify the rate-determining and overpotential-creating steps and therewith provide the basis for a rational optimization of the overall process. As such our study will provide a key example of how systematic method development in computational approaches to basic energy sciences leads to breakthrough progress and serves both fundamental understanding and cutting-edge application.
Webanwendung mit ca. 230 Merkmalen der Amtlichen Statistik; u. a. Daten zu den Bereichen Bevölkerung, Wanderungen, Arbeitsmarkt, SGB II, Bautätigkeit, Produzierendes Gewerbe, Handel, Tourismus, Verkehr und Verdienste. Die Aktualisierung der hinterlegten Datenbank erfolgt täglich.
Bamboos (Poaceae) are widespread in tropical and subtropical forests. Particularly in Asia, bamboos are cultivated by smallholders and increasingly in large plantations. In contrast to trees, reliable assessments of water use characteristics for bamboo are very scarce. Recently we tested a set of methods for assessing bamboo water use and obtained first results. Objectives of the proposed project are (1) to further test and develop the methods, (2) to compare the water use of different bamboo species, (3) to analyze the water use to bamboo size relationship across species, and (4) to assess effects of bamboo culm density on the stand-level transpiration. The study shall be conducted in South China where bamboos are very abundant. It is planned to work in a common garden (method testing), a botanical garden (species comparison, water use to size relationship), and on-farm (effects of culm density). Method testing will include a variety of approaches (thermal dissipation probes, stem heat balance, deuterium tracing and gravimetry), whereas subsequent steps will be based on thermal methods. The results may contribute to an improved understanding of bamboo water use characteristics and a more appropriate management of bamboo with respect to water resources.
Perennial fodder cropping potentially increases subsoil biopore density by formation of extensive root systems and temporary soil rest. We will quantify root length density, earthworm abundance and biopore size classes after Medicago sativa, Cichorium intybus and Festuca arundinacea grown for 1, 2 and 3 years respectively in the applied research unit's Central Field Trial (CeFiT) which is established and maintained by our working group. Shoot parameters including transpiration, gas exchange and chlorophyll fluorescence will frequently be recorded. Precrop effects on oilseed rape and cereals will be quantified with regard to crop yield, nutrient transfer and H2-release. The soil associated with biopores (i.e. the driloshpere) is generally rich in nutrients as compared to the bulk soil and is therefore supposed to be a potential hot spot for nutrient acquisition. However, contact areas between roots and the pore wall have been reported to be low. It is still unclear to which extent the nutrients present in the drilosphere are used and which potential relevance subsoil biopores may have for the nutrient supply of crops. We will use a flexible videoscope to determine the root-soil contact in biopores. Nitrogen input into the drilosphere by earthworms and potential re-uptake of nitrogen from the drilosphere by subsequent crops with different rooting systems (oilseed rape vs. cereals) will be quantified using 15N as a tracer.
Evidence is compelling for a positive correlation between urbanisation and increment of allergic sensitisation and diseases. The reason for this association is not clear to date. Some data point to a pro-allergic effect of anthropogenic factors on susceptible individuals. Data analysing the impact of environmental - natural and anthropogenic - factors on the allergenicity of allergen carriers such as pollen grains are scarce, and if applicable only taken from in vitro experimental designs. This study will analyse one of the most common allergy inducers in northern Europe - the birch pollen. Under natural exposure conditions, birch pollen will be analysed with respect to their allergenicity. Within an interdisciplinary research team this study will evaluate the effect of natural (e.g. soil, climate, genetic background) and anthropogenic (e.g. traffic pollutants) factors on birch pollen in a holistic approach including analysis of allergen bioavailability, release of pollen associated lipid mediators from birch pollen grains, in vitro immunostimulatory activity and in vivo allergenic potential. These data collected in the time course of three years will significantly add to our understanding how urbanisation and climate change influence the allergenicity of birch pollen and will help us in the future to set up primary prevention studies.
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