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Fabrik\Silizium-Modul-mono-DE-2005

Herstellung von Silizium-PV-Modulen aus monokristallinen Siliziumzellen, Daten nach #1, Tabelle VI. Solarzellen-, EVA- und Rückenfolienabfall vernachlässigt Folgende Daten beziehen sich auf die Herstellung eines Moduls mit 175Wp. Fläche 1,25 m², Gewicht 17,4 kg davon Solar cells 0,760424 kg Aluminium profile 3,8 kg Polyphenylenoxid 0,2 kg Glass sheet, low iron, tempered 11,4 kg Ethyl Vinyl Acetate 1,3 kg zusätzlicher Reststoff Glas (0,01 kg/kg), der in Recycling geht Auslastung: 5000h/a Brenn-/Einsatzstoff: Rohstoffe gesicherte Leistung: 100% Jahr: 2005 Lebensdauer: 20a Leistung: 1t/h Nutzungsgrad: 2290% Produkt: Rohstoffe

Fabrik\Silizium-Modul-multi-DE-2005

Herstellung von Silizium-PV-Modulen aus multikristallinen Siliziumzellen, Daten nach #1, Tabelle VI. Solarzellen-, EVA- und Rückenfolienabfall vernachlässigt zusätzlicher Reststoff Glas (0,01 kg/kg), der in Recycling geht Die folgenden Daten beziehen sich auf die Hersellung eines Modul mit einer Leistung von 165Wp. Fläche 1,25 m² Gewicht 17,4 kg Solar cells 0,760424 kg Aluminium profile 3,8 kg Polyphenylenoxid 0,2 kg Glass sheet, low iron, tempered 11,4 kg Ethyl Vinyl Acetate 1,3 kg Auslastung: 5000h/a Brenn-/Einsatzstoff: Rohstoffe gesicherte Leistung: 100% Jahr: 2005 Lebensdauer: 20a Leistung: 1t/h Nutzungsgrad: 2290% Produkt: Rohstoffe

Zonierung Nationalpark Nds. Wattenmeer

(1) Der Nationalpark ist in drei Zonen gegliedert, die in dem in § 3 Abs. 1 genannten Kartenwerk ausgewiesen sind: 1. Ruhezone (Zone I) - rot, 2. Zwischenzone (Zone II) - grün, 3. Erholungszone (Zone III) - gelb. In den Karten der Anlagen 2 und 3 sind die einzelnen Gebiete der Zone I durch Nummern mit arabischen Ziffern gekennzeichnet. (2) Soweit in den Absätzen 3 und 4 nichts anderes bestimmt ist, ist für die Abgrenzung der Zonen untereinander das in § 3 Abs. 1 genannte Kartenwerk maßgeblich. (3) Die Gebiete der Ruhezone sind in der Anlage 1 beschrieben. 2Für die Abgrenzung der Ruhezonengebiete gilt Folgendes: 1. Unveränderliche Grenzpunkte sind durch geografische Koordinaten bestimmt. 2. Für den Verlauf der in dem in § 3 Abs. 1 genannten Kartenwerk mit einer durchgezogenen Linie als feststehend gekennzeichneten Grenzen der Ruhezone ist die Karte maßgeblich. 3. Der Verlauf der in dem in § 3 Abs. 1 genannten Kartenwerk durch eine unterbrochene Linie als veränderlich gekennzeichneten Grenzen der Ruhezone wird durch die in der Anlage 1 enthaltenen Angaben - auf See in Verbindung mit der jeweils gültigen amtlichen Seekarte - beschrieben. Wird eine Grenze der Ruhezone durch die Außenseite einer Plate oder eines Sandes gebildet, so ist die Seekartennull-Linie maßgebend; wird die Grenze der Ruhezone durch einen Priel, eine Balje oder ein Gat gebildet, so ist die Seekartennull-Linie auf der der Ruhezone zugewandten Seite maßgebend. Wird die Grenze durch Tonnen, einen Dünenfuß oder andere vor Ort erkennbare natürliche oder künstliche Merkpunkte gebildet, so ist deren Standort maßgebend. (4) Die seewärtige Grenze der Erholungszone wird durch die mittlere Hochwasserlinie gebildet, soweit die Anlage 3 nicht niedriger liegende Flächen als Erholungszone ausweist. 2In diesem Fall wird die durch eine durchgezogene Linie gekennzeichnete seewärtige Grenze durch eine mittels Koordinaten gebildete Linie gebildet; die seitliche Grenze ergibt sich dort aus der geraden Linie zwischen Markierungspfählen, die gemäß den Vorgaben der Anlage 3 jeweils an der mittleren Hochwasserlinie und oberhalb dieser Linie stehen. 3Die Abgrenzung niedriger liegender Flächen der Erholungszone im Übrigen ergibt sich aus der Darstellung in der Anlage 3. Der Datensatz liefert die aktuelle Zonierung. Die GIS-Daten können unter der Rubrik "Verweise" herunter geladen werden.

Markt für Gold

technologyComment of gold mine operation and refining (SE): OPEN PIT MINING: The ore is mined in four steps: drilling, blasting, loading and hauling. In the case of a surface mine, a pattern of holes is drilled in the pit and filled with explosives. The explosives are detonated in order to break up the ground so large shovels or front-end loaders can load it into haul trucks. ORE AND WASTE HAULAGE: The haul trucks transport the ore to various areas for processing. The grade and type of ore determine the processing method used. Higher-grade ores are taken to a mill. Lower grade ores are taken to leach pads. Some ores may be stockpiled for later processing. HEAP LEACHING: The ore is crushed or placed directly on lined leach pads where a dilute cyanide solution is applied to the surface of the heap. The solution percolates down through the ore, where it leaches the gold and flows to a central collection location. The solution is recovered in this closed system. The pregnant leach solution is fed to electrowinning cells and undergoes the same steps as described below from Electro-winning. ORE PROCESSING: Milling: The ore is fed into a series of grinding mills where steel balls grind the ore to a fine slurry or powder. Oxidization and leaching: Some types of ore require further processing before gold is recovered. In this case, the slurry is pressure-oxidized in an autoclave before going to the leaching tanks or a dry powder is fed through a roaster in which it is oxidized using heat before being sent to the leaching tanks as a slurry. The slurry is thickened and runs through a series of leaching tanks. The gold in the slurry adheres to carbon in the tanks. Stripping: The carbon is then moved into a stripping vessel where the gold is removed from the carbon by pumping a hot caustic solution through the carbon. The carbon is later recycled. Electro-winning: The gold-bearing solution is pumped through electro-winning cells or through a zinc precipitation circuit where the gold is recovered from the solution. Smelting: The gold is then melted in a furnace at about 1’064°C and poured into moulds, creating doré bars. Doré bars are unrefined gold bullion bars containing between 60% and 95% gold. References: Newmont (2004) How gold is mined. Newmont. Retrieved from http://www.newmont.com/en/gold/howmined/index.asp technologyComment of gold production (US): OPEN PIT MINING: The ore is mined in four steps: drilling, blasting, loading and hauling. In the case of a surface mine, a pattern of holes is drilled in the pit and filled with explosives. The explosives are detonated in order to break up the ground so large shovels or front-end loaders can load it into haul trucks. UNDERGROUND MINING: Some ore bodies are more economically mined underground. In this case, a tunnel called an adit or a shaft is dug into the earth. Sort tunnels leading from the adit or shaft, called stopes, are dug to access the ore. The surface containing the ore, called a face, is drilled and loaded with explosives. Following blasting, the broken ore is loaded onto electric trucks and taken to the surface. Once mining is completed in a particular stope, it is backfilled with a cement compound. BENEFICIATION: Bald Mountain Mines: The ore treatment method is based on conventional heap leaching technology followed by carbon absorption. The loaded carbon is stripped and refined in the newly commissioned refinery on site. Water is supplied by wells located on the mine property. Grid power was brought to Bald Mountain Mine in 1996. For this purpose, one 27-kilometre 69 KVA power line was constructed from the Alligator Ridge Mine substation to the grid. Golden Sunlight Mines: The ore treatment plant is based on conventional carbon-in-pulp technology, with the addition of a Sand Tailings Retreatment (STR) gold recovery plant to recover gold that would otherwise be lost to tailings. The STR circuit removes the heavier gold bearing pyrite from the sand portion of the tailings by gravity separation. The gold is refined into doré at the mine. Tailing from the mill is discharged to an impoundment area where the solids are allowed to settle so the water can be reused. A cyanide recovery/destruction process was commissioned in 1998. It eliminates the hazard posed to wildlife at the tailings impoundment by lowering cyanide concentrations below 20 mg/l. Fresh water for ore processing, dust suppression, and fire control is supplied from the Jefferson Slough, which is an old natural channel of the Jefferson River. Ore processing also uses water pumped from the tailings impoundment. Pit water is treated in a facility located in the mill complex prior to disposal or for use in dust control. Drinking water is made available by filtering fresh water through an on-site treatment plant. Electric power is provided from a substation at the south property boundary. North-Western Energy supplies electricity the substation. Small diesel generators are used for emergency lighting. A natural gas pipeline supplies gas for heating buildings, a crusher, air scrubber, boiler, carbon reactivation kiln, and refining furnaces. Cortez Mine: Three different metallurgical processes are employed for the recovery of gold. The process used for a particular ore is determined based on grade and metallurgical character of that ore. Lower grade oxide ore is heap leached, while higher-grade non-refractory ore is treated in a conventional mill using cyanidation and a carbon-in-leach (“CIL”) process. When carbonaceous ore is processed by Barrick, it is first dry ground, and then oxidized in a circulating fluid bed roaster, followed by CIL recovery. In 2002 a new leach pad and process plant was commissioned; this plant is capable of processing 164 million tonnes of heap leach ore over the life of the asset. Heap leach ore production is hauled directly to heap leach pads for gold recovery. Water for process use is supplied from the open pit dewatering system. Approximately 90 litres per second of the pit dewatering volume is diverted for plant use. Electric power is supplied by Sierra Pacific Power Company (“SPPC”) through a 73 kilometre, 120 kV transmission line. A long-term agreement is in place with SPPC to provide power through the regulated power system. The average power requirement of the mine is about 160 GWh/year. REFINING: Wohlwill electrolysis. It is assumed that the gold doré-bars from both mines undergo the treatment of Wohlwill electrolysis. This process uses an electrolyte containing 2.5 mol/l of HCl and 2 mol/l of HAuCl4 acid. Electrolysis is carried out with agitation at 65 – 75 °C. The raw gold is intro-duced as cast anode plates. The cathodes, on which the pure gold is deposited, were for many years made of fine gold of 0.25 mm thickness. These have now largely been replaced by sheet titanium or tantalum cathodes, from which the thick layer of fine gold can be peeled off. In a typical electrolysis cell, gold anodes weighing 12 kg and having dimensions 280×230×12 mm (0.138 m2 surface) are used. Opposite to them are conductively connected cathode plates, arranged by two or three on a support rail. One cell normally contains five or six cathode units and four or five anodes. The maximum cell voltage [V] is 1.5 V and the maximum anodic current density [A] 1500 A/m2. The South African Rand refinery gives a specific gold production rate of 0.2 kg per hour Wohlwill electrolysis. Assuming a current efficiency of 95% the energy consumption is [V] x [A] / 0.2 [kg/h] = 1.63 kWh per kg gold refined. No emissions are assumed because of the purity and the high value of the material processed. The resulting sludge contains the PGM present in the electric scrap and is sold for further processing. OTHER MINES: Information about the technology used in the remaining mines is described in the References. WATER EMISSIONS: Water effluents are discharged into rivers. References: Auerswald D. A. and Radcliffe P. H. (2005) Process technology development at Rand Refinery. In: Minerals Engineering, 18(8), pp. 748-753, Online-Version under: http://dx.doi.org/10.1016/j.mineng.2005.03.011. Newmont (2004) How gold is mined. Newmont. Retrieved from http://www.newmont.com/en/gold/howmined/index.asp Renner H., Schlamp G., Hollmann D., Lüschow H. M., Rothaut J., Knödler A., Hecht C., Schlott M., Drieselmann R., Peter C. and Schiele R. (2002) Gold, Gold Alloys, and Gold Compounds. In: Ullmann's Encyclopedia of Industrial Chemistry. Online version, posting date: September 15, 2000 Edition. Wiley-Interscience, Online-Version under: http://dx.doi.org/10.1002/14356007.a12_ 499. Barrick (2006b) Environment: Performance Tables from http://www.barrick. com/Default.aspx?SectionID=8906c4bd-4ee4-4f15-bf1b-565e357c01e1& LanguageId=1 Newmont (2005b) Now & Beyond: Sustainability Reports. Newmont Mining Corporation. Retrieved from http://www.newmont.com/en/social/reporting/ index.asp technologyComment of gold production (CA): OPEN PIT MINING: The ore is mined in four steps: drilling, blasting, loading and hauling. In the case of a surface mine, a pattern of holes is drilled in the pit and filled with explosives. The explosives are detonated in order to break up the ground so large shovels or front-end loaders can load it into haul trucks. UNDERGROUND MINING: Some ore bodies are more economically mined underground. In this case, a tunnel called an adit or a shaft is dug into the earth. Sort tunnels leading from the adit or shaft, called stopes, are dug to access the ore. The surface containing the ore, called a face, is drilled and loaded with explosives. Following blasting, the broken ore is loaded onto electric trucks and taken to the surface. Once mining is completed in a particular stope, it is backfilled with a cement compound. ORE AND WASTE HAULAGE: The haul trucks transport the ore to various areas for processing. The grade and type of ore determine the processing method used. Higher-grade ores are taken to a mill. Lower grade ores are taken to leach pads. Some ores may be stockpiled for later processing. BENEFICIATION: In the Porcupine Mines, gold is recovered using a combination of gravity concentration, milling and cyanidation techniques. The milling process consists of primary crushing, secondary crushing, rod/ball mill grinding, gravity concentration, cyanide leaching, carbon-in-pulp gold recovery, stripping, electrowinning and refining. In the Campbell Mine, the ore from the mine, after crushing and grinding, is processed by gravity separation, flotation, pressure oxidation, cyanidation and carbon-in-pulp process followed by electro-winning and gold refining to doré on site. The Musselwhite Mine uses gravity separation, carbon in pulp, electro¬winning and gold refining to doré on site. REFINING: Wohlwill electrolysis. It is assumed that the gold doré-bars from both mines undergo the treatment of Wohlwill electrolysis. This process uses an electrolyte containing 2.5 mol/l of HCl and 2 mol/l of HAuCl4 acid. Electrolysis is carried out with agitation at 65 – 75 °C. The raw gold is intro-duced as cast anode plates. The cathodes, on which the pure gold is deposited, were for many years made of fine gold of 0.25 mm thickness. These have now largely been replaced by sheet titanium or tantalum cathodes, from which the thick layer of fine gold can be peeled off. In a typical electrolysis cell, gold anodes weighing 12 kg and having dimensions 280×230×12 mm (0.138 m2 surface) are used. Opposite to them are conductively connected cathode plates, arranged by two or three on a support rail. One cell normally contains five or six cathode units and four or five anodes. The maximum cell voltage [V] is 1.5 V and the maximum anodic current density [A] 1500 A/m2. The South African Rand refinery gives a specific gold production rate of 0.2 kg per hour Wohlwill electrolysis. Assuming a current efficiency of 95% the energy consumption is [V] x [A] / 0.2 [kg/h] = 1.63 kWh per kg gold refined. No emissions are assumed because of the purity and the high value of the material processed. The resulting sludge contains the PGM present in the electric scrap and is sold for further processing. WATER EMISSIONS: Effluents are discharged into the ocean. REFERENCES: Newmont (2004) How gold is mined. Newmont. Retrieved from http://www.newmont.com/en/gold/howmined/index.asp Renner H., Schlamp G., Hollmann D., Lüschow H. M., Rothaut J., Knödler A., Hecht C., Schlott M., Drieselmann R., Peter C. and Schiele R. (2002) Gold, Gold Alloys, and Gold Compounds. In: Ullmann's Encyclopedia of Industrial Chemistry. Online version, posting date: September 15, 2000 Edition. Wiley-Interscience, Online-Version under: http://dx.doi.org/10.1002/14356007.a12_ 499. Auerswald D. A. and Radcliffe P. H. (2005) Process technology development at Rand Refinery. In: Minerals Engineering, 18(8), pp. 748-753, Online-Version under: http://dx.doi.org/10.1016/j.mineng.2005.03.011. technologyComment of gold production (AU): OPEN PIT MINING: The ore is mined in four steps: drilling, blasting, loading and hauling. In the case of a surface mine, a pattern of holes is drilled in the pit and filled with explosives. The explosives are detonated in order to break up the ground so large shovels or front-end loaders can load it into haul trucks. UNDERGROUND MINING: Some ore bodies are more economically mined underground. In this case, a tunnel called an adit or a shaft is dug into the earth. Sort tunnels leading from the adit or shaft, called stopes, are dug to access the ore. The surface containing the ore, called a face, is drilled and loaded with explosives. Following blasting, the broken ore is loaded onto electric trucks and taken to the surface. Once mining is completed in a particular stope, it is backfilled with a cement compound. ORE AND WASTE HAULAGE: The haul trucks transport the ore to various areas for processing. The grade and type of ore determine the processing method used. Higher-grade ores are taken to a mill. Lower grade ores are taken to leach pads. Some ores may be stockpiled for later processing. LEACHING: The ore is crushed or placed directly on lined leach pads where a dilute cyanide solution is applied to the surface of the heap. The solution percolates down through the ore, where it leaches the gold and flows to a central collection location. The solution is recovered in this closed system. The pregnant leach solution is fed to electrowinning cells and undergoes the same steps as described below from Electro-winning. ORE PROCESSING: Milling: The ore is fed into a series of grinding mills where steel balls grind the ore to a fine slurry or powder. Oxidization and leaching: Some types of ore require further processing before gold is recovered. In this case, the slurry is pressure-oxidized in an autoclave before going to the leaching tanks or a dry powder is fed through a roaster in which it is oxidized using heat before being sent to the leaching tanks as a slurry. The slurry is thickened and runs through a series of leaching tanks. The gold in the slurry adheres to carbon in the tanks. Stripping: The carbon is then moved into a stripping vessel where the gold is removed from the carbon by pumping a hot caustic solution through the carbon. The carbon is later recycled. Electro-winning: The gold-bearing solution is pumped through electro-winning cells or through a zinc precipitation circuit where the gold is recovered from the solution. Smelting: The gold is then melted in a furnace at about 1’064°C and poured into moulds, creating doré bars. Doré bars are unrefined gold bullion bars containing between 60% and 95% gold. REFINING: Wohlwill electrolysis. It is assumed that the gold doré-bars from both mines undergo the treatment of Wohlwill electrolysis. This process uses an electrolyte containing 2.5 mol/l of HCl and 2 mol/l of HAuCl4 acid. Electrolysis is carried out with agitation at 65 – 75 °C. The raw gold is intro-duced as cast anode plates. The cathodes, on which the pure gold is deposited, were for many years made of fine gold of 0.25 mm thickness. These have now largely been replaced by sheet titanium or tantalum cathodes, from which the thick layer of fine gold can be peeled off. In a typical electrolysis cell, gold anodes weighing 12 kg and having dimensions 280×230×12 mm (0.138 m2 surface) are used. Opposite to them are conductively connected cathode plates, arranged by two or three on a support rail. One cell normally contains five or six cathode units and four or five anodes. The maximum cell voltage [V] is 1.5 V and the maximum anodic current density [A] 1500 A/m2. The South African Rand refinery gives a specific gold production rate of 0.2 kg per hour Wohlwill electrolysis. Assuming a current efficiency of 95% the energy consumption is [V] x [A] / 0.2 [kg/h] = 1.63 kWh per kg gold refined. No emissions are assumed because of the purity and the high value of the material processed. The resulting sludge contains the PGM present in the electric scrap and is sold for further processing. WATER EMISSIONS: Water effluents are discharged into rivers. REFERENCES: Newmont (2004) How gold is mined. Newmont. Retrieved from http://www.newmont.com/en/gold/howmined/index.asp Renner H., Schlamp G., Hollmann D., Lüschow H. M., Rothaut J., Knödler A., Hecht C., Schlott M., Drieselmann R., Peter C. and Schiele R. (2002) Gold, Gold Alloys, and Gold Compounds. In: Ullmann's Encyclopedia of Industrial Chemistry. Online version, posting date: September 15, 2000 Edition. Wiley-Interscience, Online-Version under: http://dx.doi.org/10.1002/14356007.a12_ 499. Auerswald D. A. and Radcliffe P. H. (2005) Process technology development at Rand Refinery. In: Minerals Engineering, 18(8), pp. 748-753, Online-Version under: http://dx.doi.org/10.1016/j.mineng.2005.03.011. technologyComment of gold production (TZ): The mining of ore from open pit and underground mines is considered. technologyComment of gold refinery operation (ZA): REFINING: The refinery, which provides a same day refining service, employs the widely used Miller Chlorination Process to upgrade the gold bullion it receives from mines to at least 99.50% fine gold, the minimum standard required for gold sold on the world bullion markets. It also employs the world’s leading silver refining technology. To further refine gold and silver to 99.99% the cost-effective once-through Wohlwill electrolytic refining process is used. MILLER CHLORINATION PROCESS: This is a pyrometallurgical process whereby gold dore is heated in furnace crucibles. The process is able to separate gold from impurities by using chlorine gas which is added to the crucibles once the gold is molten. Chlorine gas does not react with gold but will combine with silver and base metals to form chlorides. Once the chlorides have formed they float to the surface as slag or escape as volatile gases. The surface melt and the fumes containing the impurities are collected and further refined to extract the gold and silver. This process can take up to 90 minutes produces gold which is at least 99.5% pure with silver being the main remaining component. This gold can be cast into bars as 99.5% gold purity meets the minimum London Good Delivery. However some customers such as jewellers and other industrial end users require gold that is almost 100% pure, so further refining is necessary. In this case, gold using the Miller process is cast into anodes which are then sent to an electrolytic plant. The final product is 99.99% pure gold sponge that can then be melted to produce various end products suited to the needs of the customer. WOHLWILL PROCESS - The electrolytic method of gold refining was first developed by Dr. Emil Wohlwill of Norddeutsche Affinerie in Hamburg in 1874. Dr. Wohlwill’s process is based on the solubility of gold but the insolubility of silver in an electrolyte solution of gold chloride (AuCl3) in hydrochloric acid. Figure below provide the overview of the refining process (source Rand Refinery Brochure) imageUrlTagReplace7f46a8e2-2df0-4cf4-99a8-2878640be562 Emissions includes also HCl to air: 7.48e-03 Calculated from rand refinery scrubber and baghouse emmission values Metal concentrators, Emmision report 2016 http://www.environmentalconsultants.co.za/wp-content/uploads/2016/11/Appendix-D1.pdf technologyComment of gold refinery operation (RoW): REFINING: The refinery, which provides a same day refining service, employs the widely used Miller Chlorination Process to upgrade the gold bullion it receives from mines to at least 99.50% fine gold, the minimum standard required for gold sold on the world bullion markets. It also employs the world’s leading silver refining technology. To further refine gold and silver to 99.99% the cost-effective once-through Wohlwill electrolytic refining process is used. MILLER CHLORINATION PROCESS: This is a pyrometallurgical process whereby gold dore is heated in furnace crucibles. The process is able to separate gold from impurities by using chlorine gas which is added to the crucibles once the gold is molten. Chlorine gas does not react with gold but will combine with silver and base metals to form chlorides. Once the chlorides have formed they float to the surface as slag or escape as volatile gases. The surface melt and the fumes containing the impurities are collected and further refined to extract the gold and silver. This process can take up to 90 minutes produces gold which is at least 99.5% pure with silver being the main remaining component. This gold can be cast into bars as 99.5% gold purity meets the minimum London Good Delivery. However some customers such as jewellers and other industrial end users require gold that is almost 100% pure, so further refining is necessary. In this case, gold using the Miller process is cast into anodes which are then sent to an electrolytic plant. The final product is 99.99% pure gold sponge that can then be melted to produce various end products suited to the needs of the customer. WOHLWILL PROCESS - The electrolytic method of gold refining was first developed by Dr. Emil Wohlwill of Norddeutsche Affinerie in Hamburg in 1874. Dr. Wohlwill’s process is based on the solubility of gold but the insolubility of silver in an electrolyte solution of gold chloride (AuCl3) in hydrochloric acid. Figure below provide the overview of the refining process (source Rand Refinery Brochure) imageUrlTagReplace7f46a8e2-2df0-4cf4-99a8-2878640be562 Emissions includes also HCl to air: 7.48e-03 Calculated from rand refinery scrubber and baghouse emmission values Metal concentrators, Emmision report 2016 http://www.environmentalconsultants.co.za/wp-content/uploads/2016/11/Appendix-D1.pdf technologyComment of gold-silver mine operation with refinery (PG): OPEN PIT MINING: The ore is mined in four steps: drilling, blasting, loading and hauling. In the case of a surface mine, a pattern of holes is drilled in the pit and filled with explosives. The explosives are detonated in order to break up the ground so large shovels or front-end loaders can load it into haul trucks. ORE AND WASTE HAULAGE: The haul trucks transport the ore to various areas for processing. The grade and type of ore determine the processing method used. Higher-grade ores are taken to a mill. Lower grade ores are taken to leach pads. Some ores may be stockpiled for later processing. HEAP LEACHING: The recovery processes of the Misima Mine are cyanide leach and carbon in pulp (CIP). The ore is crushed or placed directly on lined leach pads where a dilute cyanide solution is applied to the surface of the heap. The solution percolates down through the ore, where it leaches the gold and flows to a central collection location. The solution is recovered in this closed system. The pregnant leach solution is fed to electrowinning cells and undergoes the same steps as described below from Electro-winning. ORE PROCESSING: Milling: The ore is fed into a series of grinding mills where steel balls grind the ore to a fine slurry or powder. Oxidization and leaching: The recovery process in the Porgera Mine is pressure oxidation and cyanide leach. The slurry is pressure-oxidized in an autoclave before going to the leaching tanks or a dry powder is fed through a roaster in which it is oxidized using heat before being sent to the leaching tanks as a slurry. The slurry is thickened and runs through a series of leaching tanks. The gold in the slurry adheres to carbon in the tanks. Stripping: The carbon is then moved into a stripping vessel where the gold is removed from the carbon by pumping a hot caustic solution through the carbon. The carbon is later recycled. Electro-winning: The gold-bearing solution is pumped through electro-winning cells or through a zinc precipitation circuit where the gold is recovered from the solution. Smelting: The gold is then melted in a furnace at about 1’064°C and poured into moulds, creating doré bars. Doré bars are unrefined gold bullion bars containing between 60% and 95% gold. WATER SUPPLY: For Misima Mine, process water is supplied from pit dewatering bores and in-pit water. Potable water is sourced from boreholes in the coastal limestone. For Porgera Mine, the main water supply of the mine is the Waile Creek Dam, located approximately 7 kilometres from the mine. The reservoir has a capacity of approximately 717, 000 m3 of water. Water for the grinding circuit is also extracted from Kogai Creek, which is located adjacent to the grinding circuit. The mine operates four water treatment plants for potable water and five sewage treatment plants. ENERGY SUPPLY: For Misima Mine, electricity is produced by the mine on site or with own power generators, from diesel and heavy fuel oil. For Porgera Mine, electricity is produced by the mine on site. Assumed with Mobius / Wohlwill electrolysis. Porgera's principal source of power is supplied by a 73-kilometre transmission line from the gas fired and PJV-owned Hides Power Station. The station has a total output of 62 megawatts (“MW”). A back up diesel power station is located at the mine and has an output of 13MW. The average power requirement of the mine is about 60 MW. For both Misima and Porgera Mines, an 18 MW diesel fired power station supplies electrical power. Diesel was used in the station due to the unavailability of previously supplied heavy fuel oil. technologyComment of gold-silver mine operation with refinery (CA-QC): One of the modelled mine is an open-pit mine and the two others are underground. technologyComment of gold-silver mine operation with refinery (RoW): The mining of ore from open pit mines is considered. technologyComment of platinum group metal, extraction and refinery operations (ZA): The ores from the different ore bodies are processed in concentrators where a PGM concentrate is produced with a tailing by product. The PGM base metal concentrate product from the different concentrators processing the different ores are blended during the smelting phase to balance the sulphur content in the final matte product. Smelter operators also carry out toll smelting from third part concentrators. The smelter product is send to the Base metal refinery where the PGMs are separated from the Base Metals. Precious metal refinery is carried out on PGM concentrate from the Base metal refinery to split the PGMs into individual metal products. Water analyses measurements for Anglo Platinum obtained from literature (Slatter et.al, 2009). Mudd, G., 2010. Platinum group metals: a unique case study in the sustainability of mineral resources, in: The 4th International Platinum Conference, Platinum in Transition “Boom or Bust.” Water share between MC and EC from Mudd (2010). Mudd, G., 2010. Platinum group metals: a unique case study in the sustainability of mineral resources, in: The 4th International Platinum Conference, Platinum in Transition “Boom or Bust.” technologyComment of primary zinc production from concentrate (RoW): The technological representativeness of this dataset is considered to be high as smelting methods for zinc are consistent in all regions. Refined zinc produced pyro-metallurgically represents less than 5% of global zinc production and less than 2% of this dataset. Electrometallurgical Smelting The main unit processes for electrometallurgical zinc smelting are roasting, leaching, purification, electrolysis, and melting. In both electrometallurgical and pyro-metallurgical zinc production routes, the first step is to remove the sulfur from the concentrate. Roasting or sintering achieves this. The concentrate is heated in a furnace with operating temperature above 900 °C (exothermic, autogenous process) to convert the zinc sulfide to calcine (zinc oxide). Simultaneously, sulfur reacts with oxygen to produce sulfur dioxide, which is subsequently converted to sulfuric acid in acid plants, usually located with zinc-smelting facilities. During the leaching process, the calcine is dissolved in dilute sulfuric acid solution (re-circulated back from the electrolysis cells) to produce aqueous zinc sulfate solution. The iron impurities dissolve as well and are precipitated out as jarosite or goethite in the presence of calcine and possibly ammonia. Jarosite and goethite are usually disposed of in tailing ponds. Adding zinc dust to the zinc sulfate solution facilitates purification. The purification of leachate leads to precipitation of cadmium, copper, and cobalt as metals. In electrolysis, the purified solution is electrolyzed between lead alloy anodes and aluminum cathodes. The high-purity zinc deposited on aluminum cathodes is stripped off, dried, melted, and cast into SHG zinc ingots (99.99 % zinc). Pyro-metallurgical Smelting The pyro-metallurgical smelting process is based on the reduction of zinc and lead oxides into metal with carbon in an imperial smelting furnace. The sinter, along with pre-heated coke, is charged from the top of the furnace and injected from below with pre-heated air. This ensures that temperature in the center of the furnace remains in the range of 1000-1500 °C. The coke is converted to carbon monoxide, and zinc and lead oxides are reduced to metallic zinc and lead. The liquid lead bullion is collected at the bottom of the furnace along with other metal impurities (copper, silver, and gold). Zinc in vapor form is collected from the top of the furnace along with other gases. Zinc vapor is then condensed into liquid zinc. The lead and cadmium impurities in zinc bullion are removed through a distillation process. The imperial smelting process is an energy-intensive process and produces zinc of lower purity than the electrometallurgical process. technologyComment of processing of anode slime from electrorefining of copper, anode (GLO): Based on typical current technology. Anode slime treatment by pressure leaching and top blown rotary converter. Production of Silver by Möbius Electrolysis, Gold by Wohlwill electrolysis, copper telluride cement and crude selenium to further processing. technologyComment of silver-gold mine operation with refinery (CL): OPEN PIT MINING: The ore is mined in four steps: drilling, blasting, loading and hauling. In the case of a surface mine, a pattern of holes is drilled in the pit and filled with explosives. The explosives are detonated in order to break up the ground so large shovels or front-end loaders can load it into haul trucks. BENEFICIATION: The processing plant consists of primary crushing, a pre-crushing circuit, (semi autogenous ball mill crushing) grinding, leaching, filtering and washing, Merrill-Crowe plant and doré refinery. The Merrill-Crowe metal recovery circuit is better than a carbon-in-pulp system for the high-grade silver material. Tailings are filtered to recover excess water as well as residual cyanide and metals. A dry tailings disposal system was preferred to a conventional wet tailings impoundment because of site-specific environmental considerations. technologyComment of silver-gold mine operation with refinery (RoW): Refinement is estimated with electrolysis-data. technologyComment of treatment of precious metal from electronics scrap, in anode slime, precious metal extraction (SE, RoW): Anode slime treatment by pressure leaching and top blown rotary converter. Production of Silver by Möbius Electrolysis, Gold by Wohlwill electrolysis, Palladium to further processing

CASE Outcrop Data (WMS)

The web service of the dataset comprises the locations of outcrops with respective information on the lithology, stratigraphy, rock age and tectonic data collected during the CASE expeditions. The data attributes include stereographic projections and sketches of tectonic structures derived from the outcrop data. At the end of the 1980s, BGR initiated the research program Circum-Arctic Structural Events (CASE) to reconstruct the plate tectonic processes during the evolution of the Arctic Ocean using terrestrial data from the surrounding continental margins. One of the scientific questions of the CASE programme is as simple as it is complex: How did the Arctic Ocean, this large basin between the Eurasian and North American continental plates, develop? There are still no conclusive answers to this question in terms of plate tectonics. In contrast to the marine expeditions of geophysicists in the Arctic Ocean, geologists on land along the various coastal areas of the Arctic Ocean can directly touch, examine and map rocks, structures, folds and fault zones and determine the respective ages of the movements. This makes it possible to directly compare rock units and deformation zones on different continental plates and thus also to reconstruct when these plates collided, how long they remained next to each other and when and how they separated again. Since the inception of BGR’s Arctic research, the primary focus and research areas have been along the continental margins between Spitsbergen and the Canadian Arctic Archipelago via Greenland, to the Yukon North Slope on the border with Alaska. On the opposite side of the Arctic Ocean, there have been expeditions to Yakutia, the mainland areas near the Laptev Sea, the New Siberian Islands and to the Polar Ural with Russian partners. An important method for the interpretation of the geological evolution of the Arctic is the examination of tectonic structures (faults, folds, cleavage etc.), the determination of the kinematics and the age of the tectonic movements.

Grundwassermessstelle Plate F1 des NLWKN

Art der Messstelle: Brunnen. Die Messstelle Befindet sich im tiefer Grundwasserleiter. Sie gehört zum Koordinierungsraum Mittlere Elbe/Elde (5700). Der Grundwasserleiter heißt: Jeetzel Lockergestein links.

Processed seismic data of Cruise SO186 SeaCause II 2006

SeaCause cruise SO186-2, aboard the RV Sonne, was carried out off northern Sumatra between 21st January and 24th February 2006, with mobilisation and demobilisation in Singapore and Penang, Malaysia, respectively. The geophysical survey acquired multichannel seismic data (MCS) using a 240 channel, 3 km Sercel streamer, and a tuned airgun array comprising 16 airguns with a total capacity of 50.8 litres. Bathymetry data, using the 12 kHz Simrad swath system, subseabed data using the hull mounted high resolution Parasound profiler together with gravity and magnetic data were also acquired. The main scientific objective of the survey was to investigate the southern part of the rupture zone of the 26th December 2004 9.3 magnitude earthquake, that caused the catastrophic tsunami of that date, and the rupture zone of the 8.7 magnitude earthquake of March 28th 2005. Specifically, to identify the segment boundary between the two earthquakes, as recognised by the distribution of their aftershocks. This was to be achieved by mapping the structure of the subduction zone including the dip angle of the subducted plate, the architecture of the accretionary prism and the structure of the forearc basins, particularly their strike-slip fault systems. Also to be investigated was whether there was a contribution to the 2004 tsunami from major submarine failures. During the survey a total of 5358 line kilometres of MCS data were acquired, mainly on lines oriented orthogonal to the subduction zone and extending from the ocean basin across the trench and accretionary prism to the forearc basins offshore Sumatra. The orthogonal survey lines were located on average approximately 40 km apart. The survey was planned using the bathymetry from the HMS Scott, RV Natsushima and RV Sonne cruises carried out in 2004. The morphology of the trench and sediment thickness varies from north to south. In the north the trench is poorly defined with shallow seabed dip but with sediment thickness of ~3.5 secs (TWT). The seafloor dips increase southwards, but sediment thickness decreases to ~2.5 secs (TWT) off Nias. Both the ocean basin and trench sediments are dissected by numerous normal faults, oriented subparallel to the plate boundary, with many that penetrate the oceanic crust. In the south Fracture Zones were identified. The structure of the deformation front on the seaward margin of the accretionary prism is highly variable. While the younges main thrust are predominantly landward vergent there are examples for seaward verging thrusts. The frontal fold develops in some cases already in the french while in most cases the frontal fold is at the beginning of the accretionary wedge. At some locations there are large sediment slumps on the frontal thrusts, the slope angle of the prism varies between 6 to 15 degrees, an angle that explains the large scale slumping. The width of the accretionary prism is widest in the north of the area at 140 km and narrows southwards until in the vicinity of the islands it is 40 km. In the north and central parts of the survey area the passage from the deformation front landwards into the older prism is rapid and the seabed gradients steep. The dip of the oceanic crust remains low and there is an obvious twofold increase (6-7 seconds TWT) in the sediment thickness. The basal decollement of the thrusts at the deformation front is in the lower sediment layer overlying oceanic basement. This is traced northeastward. A possible explanation for the increase in thickness of the prism is therefore considered to be the formation of a thrust duplex. Perhaps this is due to the subducted sediment thickness. In this region the prism forms a plateau and the internal pattern of the uppermost sediments shows striking similarities to the trench fill. Offshore of Simeulue Island the prism structure changes and it forms the more usually seen taper. The offscraped sediment forms a thinner section, the thrusts are more steeply dipping. The dip of the subducted plate here is greater than in the north. Three forearc basins were surveyed. In the north the western margin of the Aceh Basin lies along the West Andaman Fault. Within the main basin the sediments are internally undeformed. Farther south in the Simeulue Basin the northern and central parts there are numerous, active steeply dipping faults. In southern part of the basin there is a transpressional fault similarly to the Mentawi Fault off southern Sumatra. There are notable ‘bright spots’ in the upper section that may indicate the presence of hydrocarbon gas. There are also widespread Bottom Simulating Reflectors indication the presence of gashydrates and there may be also one double BSR. At the southern end of the surveyed area the Nias Basin may be subdivided along its length into two parts by a northnorthwest to southsoutheast trending carbonate platform development. The basin has had a varying subsidence history, in the south the subsidence was completed before the northern part started.

Processed seismic data of Cruise SO104 CINCA 1995

The CINCA marine geoscience investigations on the convergent continental margin of Chile between 19°S and 33°30'S were accomplished during three legs of RV SONNE cruise SO-104, from 22. July to 15. October 1995. The objectives of the first leg are to contribute to an understanding of the geological architecture and of the tectonic mechanism in the area of the Chile convergent zone through a geophysical assessment of the tectonic structures of the Chile continental margin and the adjacent oceanic Nazca plate. During the first leg from 22. July to 24. August 1995 multichannel seismic reflection data with BGR's new digital streamer were collected along a systematic grid with a total traverse length of 4,494 km simultaneously with the acquisition of magnetic, gravimetric, Hydrosweep and Parasound data over a total traverse length of 7,012 km. GFZ's mobile land array of 12 seismic stations recorded the air gun shots fired by RV SONNE within the CINCA area. Three seismic lines were surveyed between 32°30'S and 33°30'S in the area of the CONDOR project. Here, the surface of the downbending oceanic crust is smooth. The 5,000 m to 6,000 m deep trench floor is underlain by sediments, in excess 2,500 m thick. The inner trench slope consists of a landward thickening accretionary wedge which terminates against a body forming the base of a fore arc basin near Valparaiso. The principal area of the CINCA project extends between 19°S and 26°S and comprises the convergent continental margin, the Peru-Chile trench and the seaward adjacent part of the Nazca plate up to approximately 75°W longitude. The tectonic regime of these units of the CINCA area is very different from the tectonic system of the respective units of the CONDOR area. The Eocene-aged and sediment-starved oceanic crust of the Nazca plate becomes blockfaulted when approaching the outer trench slope break. The 50 km to 70 km wide outer trench slope is characterized by a complex system of horst and graben structures in the CINCA area probably resulting from the strong downbending. Steep fault scarps forming the flanks of the horsts reach vertical offsets varying between few hundreds of metres to 1,000 m, and locally even more. The 7,000 m to 8,l00 m deep trench is very narrow and mostly sediment-starved in the CINCA area. Morphology and architecture of the continental margin of the CINCA area are controlled by planar and listric faulting and tilted blocks of inferred continental nature, which apparently slid down into the trench. The inferred continental blocks, overlying a reflective mass, are covered by sediments of presumably turbiditic nature. An accretionary wedge is difficult to define on the seismic single channel records from the CINCA area. However, processed seismic data show a deep reflective mass underlying the downfaulted blocks of inferred continental nature. This deep reflective mass is interpreted to consist of a tectonically eroded and underplated continental crust-basalt melange forming the transition between the downfaulted continental upper plate and the subducting oceanic lower plate. Complex structural highs of still unknown origin and nature have been observed on the upper continental slope at 20°S, 24°S and 25°S. The northernmost structural high represents the seaward termination of the Iquique fore arc basin. The accuracy of the acquired gravity and bathymetric data is very good, i.e. better than 1 mGal and less than 10 m. The Chile trench is associated with strong negative gravity anomalies, and the continental margin is characterized by several positive and negative gravity anomalies of varying size and amount. The first results of magnetic modeling show, that the intensive blockfaulting of the oceanic crust across the outer trench slope causes no loss of the magnetization of the oceanic crust. The air gun shots fired by RV SONNE in 50 m intervals along 17 seismic traverses were recorded by GFZ's mobile land array in the coastal area of Chile. Good quality data were obtained out to about 100 km distance and in some cases even out to about 150 km.

Processed seismic data of Cruise SO161 SPOC 2001

Within the frame of the comprehensive SPOC project (Subduction Processes off Chile) the SONNE cruises SO161 Leg 2 and 3 have been conducted between October 16th and November 29th, 2001, off central Chile between 28° and 44° S. In that period some 5,300 km were surveyed with multichannel seismic (MCS) reflection, magnetic, gravity, high-resolution bathymetric and echographic methods. In addition, approximately 3,900 km were surveyed with the same spectrum of methods but without MCS. The total number of 2D profiles was 48. Target was the variation of the subduction properties between the convergent oceanic Nazca and continental Southamerica plates and the different conditions that might influence the subduction process as there are: (1) age of the oceanic crust, (2) its structure and composition, (3) its sedimentary cover, (4) its thermal state, (5) the subduction angle and obliquity, and (6) the terrigenous sediment afflux from the continent. Furthermore, special focus was given to the subduction front, the subduction interface, the structure of the slope as well as to the forearc basin structure and history, and the general distribution of gas hydrate indicating bottom simulating reflectors (BSR's). The results are to be compared with previous studies of the Chilean active margin, e.g. CONDOR (SO 101 and 103) and CINCA (SO 104). The SPOC target area was subdivided into three sub-areas A,B and C. One area was chosen for a detailed survey by aid of a narrowly spaced grid and for a close link with a lot of partners. This area is characterized by a distinctly different margin type south of it is assumed. Moreover, the subducting portion of the aseismic Juan Fernandez Ridge is located in that area representing another important target of the survey. Advantageous conditions enabled the survey of an east-west profile south of Chiloé Island, providing a section through the submerged coastal Cordillera into the flooded longitudinal valley. Some results of Leg 2 and 3 are: In all areas A, B and C no subduction bulge (outer high) in the oceanic crust was visible perhaps due to the shortness of the profiles. The sedimentary cover of the oceanic crust is exceptionally thin, and the crustal thickness is generally quite "normal" with around 7 km derived from relatively weak Moho reflections. In area B a so far magnetically unmapped region was filled providing reliable ages of the oceanic crust, and suggesting that the Challenger Fracture Zone abruptly terminates west of the area of investigation. The survey in area C yielded valuable information on the trench morphology. The so far unique MCS profile south of Chiloé island shows a very wide trench and allows to extrapolate the general conditions encountered an area A southward to approximately 44° S. It can be stated that the situation is in sharp contrast to the basin structures detected by industry profiles further north in the Golfo de Corcovado.

Processed seismic data of Cruise SO98 GIGICS 1994

Main target of the project GIGICS (Cooperative German-Indonesian Geoscientific Investigations in the Celebes Sea) is the investigation of the internal crustal structure and the plate tectonic evolution of the Celebes Sea and its active continental margins off Mindanao and Northern Sulawesi. These investigations were carried out during the cruise SO98 of RV SONNE by the Federal Institute for Geosciences and Natural Resources (BGR), Hannover; the German Research Centre for Geosciences (GFZ), Potsdam; the GEOMAR, Kiel; the Institute of Oceanography (IfM), Hamburg; the Mines and Geoscience Bureau, Manila; the Agency for the Assessment and Application of Technology, Jakarta, and the Institute of Oceanography, Wormley. The cruise SO98 consisted of three legs of two weeks duration and one leg of four weeks duration. The total amount of data acquired during the cruise were: - 3,300 km of multichannel reflection seismics, - over 6,800 km of gravimetric and magnetic data and approximately 10.000 km of swath bathymetric and sediment echosounder data, - 3 wideangle-/refractionseismic profiles, each of 120 - 150 km length, - geological, geochemical sampling and oceanographical measurements at a total of 37 stations. During the cruise SO98 a widespaced but regular grid of magnetic and gravimetric profiles were acquired in the eastern part of the Celebes Sea from which up to then reliable data were very sparse. WEISSEL (1980) recognized in the western Celebes Sea WSW-ENE striking magnetic lineations, which he interpreted as chrons 18 - 20 (39 - 43 Ma according to the timescale of HARLAND et al. (1990)). The data from cruise SO98 show that there is no continuation of these anomalies to the east. In the eastern part the magnetic field of the Celebes Sea is less clear and much more disturbed. Nevertheless, E-W-striking anomalies are recognizable. Because amplitudes of local magnetic anomalies are higher than the lineations, the correlation of these lineations with the magnetic reversal scale is still somewhat ambiguous. The gravity map compiled from the measured gravimetric data shows elongated positive anomalies in the eastern part of the Celebes Sea. Exceptions occur at the deep sea trenches off North Sulawesi (North Sulawesi Trench) and Mindanao (Cotabatu Trench) and at the Sulu Archipelago where strong negative gravity anomalies were found. A remarkable NW-striking gravity high of up to 60 mgal was found in the central eastern part of the Celebes Sea. Gravimetric modelling suggests that this high can be correlated with the gravimetric effect of the Molucca Sea Plate subducting from the east under the Sangihe Arc. The reflection seismic data from the northern part of the Celebes Sea show indications for a juvenile subduction of oceanic Celebes Sea crust under the Sulu Archipelago. The oceanic crust bends down towards the Sulu Arc with angles between 2° and 5° and the sedimentary sequence above is deformed indicating a compressional stress regime. With the exception of two linear arranged seamount-like basement highs the Celebes Sea is dominated by two different oceanic crustal types showing distinct differences in the topography. The first one is showing a very similar reflection seismic pattern as it is found for oceanic crust of the Atlantic (HINZ et al., 1994). This type is characterized by a small-scale block-faulted relief of the top basement and a low reflectivity in lower crustal levels typically related as to be accreted at slow to intermediate spreading ridges. This type is found in the western, northern and southern part of the investigated area. In the eastern and especially in the southeastern part the igneous crust shows a very different image. The reflection of the top of the basement is less distinct and of lower frequency. The relief is very much smoother than in the previous type. This reflection seismic image indicates a volcanic/magmatic overprinting of the oceanic crust in this part of the Celebes Sea. Another target of cruise SO98 was the area of the active continental margin off North Sulawesi and its accretionary complex. The internal structure of the accretionary complex should be investigated to decide whether this active margin is also of the 'splinter-type' or not. During former geophysical cruises with RV SONNE oceanic crustal splinters were discovered in the accretionary wedges of the Sulu Sea and off Costa Rica (e.g. HINZ et al., 1991). From our reflection seismic measurements this active continental margin is morphologically subdivided into three units and consists of two accretionary complexes of different internal structural style: the lower and middle continental slope is underlain by an intensively thrusted, sedimentary accretionary wedge. This wedge was most probably formed during the last 5 Ma. Landward of this wedge an older and seismically very complex accretionary unit is present which is overlain at its landward termination by a sedimentary fore-arc basin. Within this older accretionary complex, units with a strong, low frequency reflection pattern were found which are interpreted to represent crustal splinters of igneous oceanic or ophiolitic nature. This interpretation is supported by our gravity and magnetic data. The magnetic profiles show an increase of the magnetic field towards the north arm of Sulawesi across the continental margin. This increase of the magnetic field suggests an increase of magnetized material within the older accretionary wedge towards the northern arm of Sulawesi where ophiolites are emplaced. During the interpretation of the reflection seismic data of the project GIGICS BSR's (bottom simulating reflectors) were discovered for the first time along the active continental margin of North-Sulawesi. BSR's are the seismic expression of a velocity decrease at the bottom of a gas hydrate zone. The distribution and depth of the BSR's correlates with the geochemical and geothermal results. Radiometric age dating and geochemical analyses from pillow basalts of a seamount from the southeastern Celebes Sea indicate hot-spot activity in this part of the Celebes Sea during or shortly after the formation of the oceanic crust approximately at 43 Ma ago. Three NW-striking ridges or seamount-chains in the northeastern Celebes Sea were mapped and investigated in detail. They are thought to represent a wrench fault system extending through the northeastern Celebes Sea. At the flank of one of these ridges a strongly alterated plagioclase-olivine basalt sample was dredged which was overlain by non-fossiliferous clay stone. A similar lithostratigraphic sequence was drilled during ODP leg 124 (RANGIN et al., 1990). The geochemical composition of these basalts is different from typical MORB. The existence of a large crustal splinter within the accretionary wedge off southwestern Mindanao obviously is responsible for a high thermal conductivity which in turn could have enhanced heat flow (108.1 mW/m2) and methanogenesis (405 ppb). The heat flow of 103.0 mW/m2 at the deformation front of the Mindanao wedge and the high methane concentration of 5.555 ppb suggests tectonically induced fluid transport within the wedge. High methane concentrations between 8.044 and 49.006 ppb at the lower slope off Sulawesi and in the North Sulawesi Trench are accompanied by high heat flow values of up to 100.5 mW/m2. Heat flow is significantly lower upslope (31.3 mW/m2). This general heat flow distribution pattern is seen over a large portion of the accretionary wedge. The elevated heat flow values and high methane concentrations near the deformation front most likely result from heat transport by fluids squeezed out from vertically and laterally compacting sediments. The reduced heat flow towards the coast is compatible either with a cooling effect of slow subduction of the oceanic crust, or stacking of cool slabs of compacted sediments. A subduction of oceanic crust with a heat flow around 60 mW/m2 over a period of more than 3 million years would have produced the low heat flow values of the upper slope if the wedge consists of claystone with a low thermal conductivity (1.2 - 1.7 W/mK). Even in the low-heat flow area isolated fluid venting is possible. Lateral variations in the heat flow pattern (e.g. broadening of the anomalies in the west) may be due to different thermal regimes within the subducted crust.

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