In hydrology, the relationship between water storage and flow is still fundamental in characterizing and modeling hydrological systems. However, this simplification neglects important aspects of the variability of the hydrological system, such as stable or instable states, tipping points, connectivity, etc. and influences the predictability of hydrological systems, both for extreme events as well as long-term changes. We still lack appropriate data to develop theory linking internal pattern dynamics and integral responses and therefore to identify functionally similar hydrological areas and link this to structural features. We plan to investigate the similarities and differences of the dynamic patterns of state variables and the integral response in replicas of distinct landscape units. A strategic and systematic monitoring network is planned in this project, which contributes the essential dynamic datasets to the research group to characterize EFUs and DFUs and thus significantly improving the usual approach of subdividing the landscape into static entities such as the traditional HRUs. The planned monitoring network is unique and highly innovative in its linkage of surface and subsurface observations and its spatial and temporal resolution and the centerpiece of CAOS.
Although global pesticide use increases steadily, our field-data based knowledge regarding exposure of non-target ecosystems is very restricted. Consequently, this meta-analysis will for the first time evaluate the worldwide available peer-reviewed information on agricultural insecticide concentrations in surface water or sediment and test the following two hypotheses: I) Insecticide concentrations in the field largely exceed regulatory threshold levels and II) Additional factors important for threshold level exceedances can be quantified using retrospective meta-analysis. A feasibility study using a restricted dataset (n = 377) suggested the significance of the expected results, i.e. an threshold level exceedance rate of more than 50Prozent of the detected concentrations. Subsequent to a comprehensive database search in the peer-reviewed literature of the past 60 years, analysis of covariance with the relevant threshold level exceedance as the continuous dependent variable (about 10,000 cases) will be performed and the impact of significant predictor variables will be quantified. Parameters not yet considered in pesticide exposure assessment will be included as independent variables, such as compound class, environmental regulatory quality, and sampling design. The simultaneous presence of several insecticide compounds as a well as their metabolites will also be considered in the evaluation. The present approach may provide an innovative and integrated view on the potential environmental side effects of global high-intensity agriculture and in particular of pesticides use.
The formation of biogeochemical interfaces in soils is controlled, among other factors, by the type of particle surfaces present and the assemblage of organic matter and mineral particles. Therefore, the formation and maturation of interfaces is studied with artificial soils which are produced in long-term biogeochemical laboratory incubation experiments (3, 6, 12, 18 months. Clay minerals, iron oxides and charcoal are used as major model components controlling the formation of interfaces because they exhibit high surface area and microporosity. Soil interface characteristics have been analyzed by several groups involved in the priority program for formation of organo-mineral interfaces, sorptive and thermal interface properties, microbial community structure and function. Already after 6 months of incubation, the artificial soils exhibited different properties in relation to their composition. A unique dataset evolves on the development and the dynamics of interfaces in soil in the different projects contributing to this experiment. An integrated analysis based on a conceptual model and multivariate statistics will help to understand overall processes leading to the biogeochemical properties of interfaces in soil, that are the basis for their functions in ecosystems. Therefore, we propose to establish an integrative project for the evaluation of data obtained and for publication of synergistic work, which will bring the results to a higher level of understanding.
Die Geosuche ist ein Webservice, welcher über die EGovernment-Basiskomponente Geodaten (GeoBAK) bereitgestellt wird. Die Geosuche ermöglicht eine multikriterielle Recherche nach ausgewählten Geobasisdaten und Geofachdaten, Geoinformationen (Metadaten) sowie Portalinhalten (Webseiten, Dokumente). Sie ist zentraler Bestandteil des Geoportals Sachsenatlas und als Freie Suche bzw. Volltextsuche ausgelegt. Die Umsetzung der Suche im Geoportal als singuläres Suchfeld (Omnibox, Einfeldsuche) analog zu bekannten Internetsuchmaschinen, ermöglicht einen schnellen Einstieg der Nutzer. Die Geosuche ermöglicht im Gegensatz zu standardisierten OGC-Geodatendiensten wie z.B. OGC-WFS-Gazetteer eine performanceoptimierte Recherche, welche nicht nur auf Geodaten beschränkt ist. Die Geosuche ermöglicht aufgrund der Filter- und Sortiermöglichkeiten die Umsetzung von über die Einfeldsuche hinausgehenden Recherchemöglichkeiten. Im Geoportal ist dies über die erweiterte Suche mit z.B. räumlicher und zeitlicher Auswahlmöglichkeit umgesetzt. Weiterhin sind einzelne Objekte untereinander verknüpft. Damit ist beispielsweise die Recherche nach allen Hausnummern einer Straße möglich (Drilldown). Die Umsetzung von Formularen mit Auswahllisten für eine Recherche, die die Geosuche aufrufen, ist möglich.
The accuracy of hydrology and weather predictions depends to a large extent on our understanding of small-scale flow phenomena at the land-atmosphere interface. The overall goal of this grant concerns improved understanding of the effects of complex alpine terrain on included field studies of air flow over steep slopes during morning and evening transition periods and thermal circulations that develop driven by differential heating on the earths surface from variations in solar heating and surface thermal properties. We have also developed improved turbulence simulations of the lower atmosphere using the immersed boundary method (IBM) and have tested our results against measurement studies in the open literature (laboratory and field). This grant has supported two PhD students (Daniel Nadeau & Marc Diebold). Nadeau was responsible for field studies and analysis of flows over steep slopes and successfully defended his PhD at the end of 2011 and is now Assistant Professor at Polytechnique in Montreal. Diebold is primarily focused on numerical simulation based upon the Large Eddy Simulation (LES) technique and is completing field campaigns (2011-2013) in the Val Ferret watershed on turbulent flow over snow covered terrain. His numerical work has focused on the implementation of new ideas in IBM and subgrid-scale (sgs) modeling. Simulation of local atmospheric flows around complex topography is of great importance for several applications in wind energy (e.g. short term wind forecasting and turbine siting and control), local weather predictions in mountainous regions and avalanche risk assessment. However atmospheric simulations around steep mountain topography remain difficult as the typical strategy used to introduce topographic elements, terrain following coordinates, becomes numerically unstable if the topography is too steep. The IBM provides a unique approach that is particularly well suited for efficient and numerically stable simulation of flows around steep terrain. To date the IBM has been used in conjunction with the EPFL-LES and tested against two unique data sets. In the first comparison, the LES was used to reproduce the experimental results from a wind tunnel study of a smooth three-dimensional hill. In the second study, we simulated the wind field around the Bolund Island, Denmark, and made direct comparisons with field measurements (this has been published recently in Boundary Layer Meteorology journal in 2013).
Quality standards to assess the chemical status of water bodies under the Water Framework Directive are often based on a few standardized laboratory tests and fixed assessment factors for extrapolation to the field situation. If larger data sets including tests with non-standard species are available, a statistical extrapolation approach, the Species Sensitivity Distribution approach (SSD) is applied. For assessing the remaining uncertainty on the SSD, the threshold concentration derived can be compared with data from field monitoring or model ecosystem studies. Taking the priority substance Ni as an example we present the use of microcosms to test the protectiveness of the quality standard derived from laboratory toxicity tests. The study was conducted in 14 microcosms including a natural sediment layer and an overlaying water volume of 750 L located in a greenhouse. After a pre-treatment period for establishing a diverse aquatic community of phytoplankton, zooplankton, periphyton and snails, Ni solution was added to reach concentrations of 6, 12, 24, 48 and 96 micro g Ni/L in two microcosms each. Four microcosms served as untreated controls. To achieve the intended constant exposure over the test period of four months, Ni concentrations were frequently determined in the microcosms and appropriate amounts of nickel solution were added mostly on a daily basis. Parameters known to affect Ni toxicity, i.e. water hardness, pH, and dissolved organic carbon, were also measured. Population abundance and community structure were analysed for difference to the dynamics in the controls. In the microcosms with 48 and 96 micro g Ni/L long-term effects on phytoplankton, rotifers, snails and, due to reduced grazing by snails, indirectly on the periphyton biomass were observed. Only minor, and/or temporary deviations from controls, i.e., for single sampling dates, were found for a few algae taxa at lower concentrations. Because these deviations showed no clear dose-response and were not found at the end of the study they were not seen as adverse effects. However, for the snail (Lymnaea stagnalis), effects on the trend of population development could not be excluded at 24 micro g/L. Thus, the overall No Observed Effect Concentration (NOEC) for a chronic exposure to nickel in this microcosm study was considered to be 12 micro g Ni/L. This NOEC confirms the protectiveness of the quality standard derived from the laboratory single species tests.
Accurate assessment of the aquatic impact of organic contaminants relies heavily on quantifying the principal degradation processes responsible for their removal. It is increasingly understood that oxidation processes play a significant and complicated role in the degradation of many contaminants in aquatic systems. The goals of the proposed project are threefold: 1. To assess three distinct computational approaches for their ability to accurate predict oxidation reaction barriers for a suite of organic compounds. These methods will be validated against existing databases of experimental measurements and high-level theoretical benchmarks. 2. To extend the existing database of measured rate constants describing organic contaminant oxidation by important oxidations in aquatic systems, for a limited number of test pollutants, using previously validated experimental protocols. 3. To further test the validity of the kinetic models for describing the rates of oxidations of organic contaminants in natural waters, using the combined data set of newly measured rate constants and both measured and newly computed oxidation barrier free energy data. In the proposed project, we will test both existing and newly developed quantum chemical models to predict the oxidation rates of several target contaminant families. The approaches developed here are expected to enable the future screening of other contaminants for their reactivity with oxidants in aquatic environments. This has important implications for the fate and impact of organic contaminants in natural surface waters, water and wastewater treatment facilities, and remediation efforts at highly contaminated sites.
A GC-MS/GC-IRMS for the molecular-level analyses of organic matter and the isotopic characterization of inorganic and organic compounds in aquatic and terrestrial ecosystems Stable isotopes represent a valuable means to constrain specific biogeochemical processes in natural environments. The main objective of the project is to develop an Environmental Laboratory for Aquatic and Terrestrial Biogeochemistry, which will support research that will make use of molecular-level characterization and (compound-specific) isotope ratio determination methods to assess a wide spectrum of biogeochemical transformations in the natural environment and in the laboratory, and to study sources and the fate of organic compounds in marine, freshwater, and soil systems. One of the major goals of the projects that make use of the new instrumental capacities is to understand the interactions of the bio- with the geo- and atmosphere with respect to the transport of organic materials and the transformation of inorganic and organic compounds by plants and microorganisms, which is of ultimate importance for the reduction of green house gases and the cycling of elements in aquatic and terrestrial ecosystems. A prime objective will be to use stable isotope measurements to constrain specific biogeochemical and metabolic processes, as well as sources, transport and degradation of organic matter in aquatic and terrestrial environments, and, in turn, to use these constraints to obtain improved estimates on global and regional C and N fluxes, in modern environments as well as in the past. Planned research themes include: I) using lipid biomarker approaches to study microbial communities in various marine and freshwater environments, II) characterizing organic matter components in lacustrine sediments as well as in soils, and identifying the mechanisms responsible for the longer-term sequestration and degradation of organic C and the emission of greenhouse gases, III) understanding the metabolic pathways of C and N during the symbiosis between microorganisms and plants, and IV) generating data sets for the isotopic composition of nitrate and other N species in various aquatic systems in order to characterize the controls on isotope fractionation of specific N cycle reactions. The spectrum of investigated ecosystems will range from Swiss soil and groundwater systems and small lakes to hydrothermal vent systems in the deep ocean, and the spatial scale of the planned research extends from enzyme biogeochemistry to ocean-scale circulation.
Within the INTERREG IIIB project MARS 'Monitoring the Alpine Region's Sustainability', an international team under the lead of BAK Basel Economics is developing an integrated set of indicators for measuring and evaluating sustainable development in the alpine space. The set of indicators integrates economic, social and ecological aspects of sustainable development and provides the basis for benchmarking of the regions. MARS is based on an extended geographical alpine space and includes important regional centres like Vienna, Milano, Munich, Lyon and Bern. In Germany, the alpine space comprises the administrative districts of Oberbayern, Schwaben, Freiburg im Breisgau and Tübingen (NUTS 2 regions). For these regions and for the total German alpine region, a dataset for the generation of environmental indicators will be established. This comprises: domestic extraction and harvest of raw materials, Domestic Processed Output (DPO = emissions, wastes and dissipative use of products), water consumption, energy consumption, land use, and a feasibility study for the Direct Material Input (DMI = domestic extraction and harvest of raw materials plus imports). In addition, regional project partners from public administration and policy will be involved in order to consider their needs for data and indicators for sustainable development of their regions. The results of MARS shall thus support local actors in evaluating and planning regional policies.
Satellite measurements strongly contribute to the understanding of the processes related to stratospheric ozone loss, e.g. by global and long term monitoring of ozone and its depleting substances. For instance, measurements performed in limb geometry by SCIAMACHY on ENVISAT largely improved the knowledge about the vertical distribution of species like BrO and OClO only recently. However, there are still important open questions, like e.g. the chlorine activation processes on different kinds of aerosols and polar stratospheric clouds. Also, the role of very short lived species in the stratospheric bromine budget or the effects of a possible enhancement of the Brewer-Dobson circulation are not fully understood.Globally, the vertical distribution of ozone depleting species varies significantly in space and time due to solar illumination, atmospheric chemistry and transport. Especially strong gradients occur near the twilight zone or across stratospheric transport barriers (polar vortex boundary, subtropical transport barriers). These regions are of particular importance for chemistry and transport of the lower stratosphere and upper troposphere, since they separate air masses on large scales but also enable exchange between them.Standard 1-D profile retrievals, which assume horizontal homogeneity, result in large systematic biases due to neglecting the effect of horizontal gradients on the measurement. We propose to develop, improve and apply a tomographic profile retrieval algorithm, which optimally combines the information provided by the SCIAMACHY limb and nadir measurements. An improved global dataset of 3D stratospheric profiles for NO2, BrO and OClO for the 10 years of the SCIAMACHY mission (2002-2012) will be developed, compared to atmospheric chemistry simulations and applied to selected questions of atmospheric science. The dataset developed in this project will be very useful for investigating the complex interplay of stratospheric chemistry and transport processes, and will help to reduce the uncertainties in the distribution of ozone depleting species, in particular for regions with large horizontal inhomogeneity.
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