In hydrology, the relationship between water storage and flow is still fundamental in characterizing and modeling hydrological systems. However, this simplification neglects important aspects of the variability of the hydrological system, such as stable or instable states, tipping points, connectivity, etc. and influences the predictability of hydrological systems, both for extreme events as well as long-term changes. We still lack appropriate data to develop theory linking internal pattern dynamics and integral responses and therefore to identify functionally similar hydrological areas and link this to structural features. We plan to investigate the similarities and differences of the dynamic patterns of state variables and the integral response in replicas of distinct landscape units. A strategic and systematic monitoring network is planned in this project, which contributes the essential dynamic datasets to the research group to characterize EFUs and DFUs and thus significantly improving the usual approach of subdividing the landscape into static entities such as the traditional HRUs. The planned monitoring network is unique and highly innovative in its linkage of surface and subsurface observations and its spatial and temporal resolution and the centerpiece of CAOS.
Although global pesticide use increases steadily, our field-data based knowledge regarding exposure of non-target ecosystems is very restricted. Consequently, this meta-analysis will for the first time evaluate the worldwide available peer-reviewed information on agricultural insecticide concentrations in surface water or sediment and test the following two hypotheses: I) Insecticide concentrations in the field largely exceed regulatory threshold levels and II) Additional factors important for threshold level exceedances can be quantified using retrospective meta-analysis. A feasibility study using a restricted dataset (n = 377) suggested the significance of the expected results, i.e. an threshold level exceedance rate of more than 50Prozent of the detected concentrations. Subsequent to a comprehensive database search in the peer-reviewed literature of the past 60 years, analysis of covariance with the relevant threshold level exceedance as the continuous dependent variable (about 10,000 cases) will be performed and the impact of significant predictor variables will be quantified. Parameters not yet considered in pesticide exposure assessment will be included as independent variables, such as compound class, environmental regulatory quality, and sampling design. The simultaneous presence of several insecticide compounds as a well as their metabolites will also be considered in the evaluation. The present approach may provide an innovative and integrated view on the potential environmental side effects of global high-intensity agriculture and in particular of pesticides use.
The formation of biogeochemical interfaces in soils is controlled, among other factors, by the type of particle surfaces present and the assemblage of organic matter and mineral particles. Therefore, the formation and maturation of interfaces is studied with artificial soils which are produced in long-term biogeochemical laboratory incubation experiments (3, 6, 12, 18 months. Clay minerals, iron oxides and charcoal are used as major model components controlling the formation of interfaces because they exhibit high surface area and microporosity. Soil interface characteristics have been analyzed by several groups involved in the priority program for formation of organo-mineral interfaces, sorptive and thermal interface properties, microbial community structure and function. Already after 6 months of incubation, the artificial soils exhibited different properties in relation to their composition. A unique dataset evolves on the development and the dynamics of interfaces in soil in the different projects contributing to this experiment. An integrated analysis based on a conceptual model and multivariate statistics will help to understand overall processes leading to the biogeochemical properties of interfaces in soil, that are the basis for their functions in ecosystems. Therefore, we propose to establish an integrative project for the evaluation of data obtained and for publication of synergistic work, which will bring the results to a higher level of understanding.
Without doubt the climate of the Alps has changed during the last decades, which result in a shift of vegetation zones, a new composition of species and most important the duration of the vegetation period. A trend analysis based on data of the Swiss phenological network showed an earlier flowering, bud burst and leaf unfolding in the year, whereas coloring of the leaves occurs later. This trend is not uniform throughout the Alps and exhibits strong regional distinction with a clear north-south difference and a contrast between lowlands and altitudes above 1000m. Although, some sites of the phenological network exist, their spatial distribution in the Alps is sparse. Furthermore, only a few measurement sites exist to monitor the actual vegetation dynamics in the Alps. In most investigations monitoring lasts only some years and only a few sites were observed for more than 10 years. Knowledge about the influence of climate on the spatial variations of vegetation dynamics is needed in order to assess future changes of vegetation due to climate change. Therefore, the proposed project focuses on the derivation of vegetation dynamics (start of season, maximum, end of season, duration of vegetation activity) and their variability in a changing climate and aims at addressing the following scientific questions: a) Does the sensitivity to warming differ across key components of land cover? b) Is there a clear difference between North-South and East-West Alps and elevation zones? c) How strong is the temperature signal in comparison to 'chilling duration' and 'photoperiod'? A homogenous and consistent data set with a high spatial (1.1km2) and temporal (1day) resolution based on data of the Advanced Very High Resolution Radiometer (AVHRR) on board of the NOAA-satellites will be generated. The Normalized Difference Vegetation Index (NDVI), a measure for the vegetation activity, will be derived for the years 1987 until 2006 using processing software developed to take into account the special conditions (topography, cloud coverage) of the Alps. The NDVI data set will be used to derive the annual vegetation dynamics with a spatial resolution of 1day (depending on the cloud coverage) and for each pixel. Thus, for the first time vegetated areas in all altitudinal zones and regions of the Alps will be analyzed on their variability of vegetation dynamics. These results are the starting point to identify the most important patterns of vegetation dynamic (start of season, maximum value, duration of maximum values, end of season, duration of season) and climate year-to-year variability. Temperature and precipitation will be taken into account to explain the dependence of vegetation variability on climate. The outcome of the vegetation variability will be compared with the variability of spring onset as obtained from phenological observation networks in order to find out whether phenological observations are representative for a region.
This project had two main goals: i) to test and further develop the novel method of scanning reflectance spectroscopy in the visible spectrum (VIS-RS) and ii) to gain improved insight into Holocene climate, especially into phases with rapid climate change by applying this method to sediments from lakes in Northern Europe. In a first study, we could confirm the high potential of VIS-RS for inferring for example organic content of lake sediments. We could as well demonstrate the high potential of multivariate calibration techniques for this purpose. In a next step it should be tested to which extend more time consuming and costly sediment parameters can be inferred by means of VIS-RS. In a second study, we analysed a comprehensive data set from a pro-glacial lake in Western Norway and extracted a signal of Holocene glacier variations from this data set. Focusing on the 8.2 ka event a period characterised by rapid cooling and subsequent warming in the North Atlantic realm, we find that the decomposition of the glacier happened even faster than the glacier advance. In this study, we applied a multitude of statistical methods to i) compare sediment parameters among each other, ii) to extract signals common to all sediment parameters and iii) to transform uncertainty of age-depth models into uncertainties of glacial activity. We therefore employed methods that are widely applied in palaeoecology but that have not found their way into the field of geochemistry and sedimentology yet.
Soil moisture - the water stored in soil within reach of the plants - is a crucial parameter for a large number of applications. Consequently, the field of microwave remote sensing of soil moisture has been an important research topic since the 1970s. But only in the last few years significant progress towards operational soil moisture services has been made. This progress became possible due to advances in sensor technology and new algorithmic approaches. With the improved algorithms it has been possible to derive soil moisture from existing operational microwave sensors. The first global soil moisture dataset derived from ERS-1/2 scatterometer measurements was released in 2002. The first near-real-time operational soil moisture service was started by EUMETSAT in May 2008 based on METOP ASCAT, which is the successor instrument of the ERS-1/2 scatterometer. Austria has made important contributions to these developments. The algorithms for retrieving soil moisture from the C-band scatterometers on board of ERS-1/2 and METOP have been developed by the Vienna University of Technology (TU Wien). Within EUMETSAT's Satellite Application Facility in Support to Operational Hydrology and Water Management (Hydrology SAF) the Austrian meteorological service (ZAMG) coordinates the soil moisture activities and is responsible for building up operational services for value-added METOP ASCAT soil moisture products. The overall goal of the proposed project is to advance the use of soil moisture services based on METOP ASCAT and complementary satellite systems, most importantly SMOS and ENVISAT ASAR, by extending the Hydrology SAF products to Africa and Australia, carrying out extensive calibration and validation (Cal/Val) activities and by developing novel water hazards applications. The considered applications are weather forecasting, drought and yield monitoring, hydrologic prediction, epidemiological modelling, climate change, desertification monitoring and societal risks assessment. A project of comparable thematic focus and breath has not been proposed before. It is expected that the interdisciplinary cooperation of specialists from different fields will lead to important scientific innovations that will promote a wide use of satellite technology in water hazards applications.
Satellite measurements strongly contribute to the understanding of the processes related to stratospheric ozone loss, e.g. by global and long term monitoring of ozone and its depleting substances. For instance, measurements performed in limb geometry by SCIAMACHY on ENVISAT largely improved the knowledge about the vertical distribution of species like BrO and OClO only recently. However, there are still important open questions, like e.g. the chlorine activation processes on different kinds of aerosols and polar stratospheric clouds. Also, the role of very short lived species in the stratospheric bromine budget or the effects of a possible enhancement of the Brewer-Dobson circulation are not fully understood.Globally, the vertical distribution of ozone depleting species varies significantly in space and time due to solar illumination, atmospheric chemistry and transport. Especially strong gradients occur near the twilight zone or across stratospheric transport barriers (polar vortex boundary, subtropical transport barriers). These regions are of particular importance for chemistry and transport of the lower stratosphere and upper troposphere, since they separate air masses on large scales but also enable exchange between them.Standard 1-D profile retrievals, which assume horizontal homogeneity, result in large systematic biases due to neglecting the effect of horizontal gradients on the measurement. We propose to develop, improve and apply a tomographic profile retrieval algorithm, which optimally combines the information provided by the SCIAMACHY limb and nadir measurements. An improved global dataset of 3D stratospheric profiles for NO2, BrO and OClO for the 10 years of the SCIAMACHY mission (2002-2012) will be developed, compared to atmospheric chemistry simulations and applied to selected questions of atmospheric science. The dataset developed in this project will be very useful for investigating the complex interplay of stratospheric chemistry and transport processes, and will help to reduce the uncertainties in the distribution of ozone depleting species, in particular for regions with large horizontal inhomogeneity.
The HGF Alliance 'Remote Sensing and Earth System Dynamics' aims at the development and evaluation of novel bio/geo-physical information products derived from data acquired by a new generation of remote sensing satellites; and their integration in Earth system models for improving understanding and modelling ability of global environmental processes and ecosystem change. The Earth system comprises a multitude of processes that are intimately meshed through complex interactions. In times of accelerated global change, the understanding and quantification of these processes is of primary importance. Spaceborne remote sensing sensors are predestined to produce bio-geo-information products on a global scale. The upcoming generation of spaceborne remote sensing configurations will be able to provide global data sets and products with unprecedented spatial and temporal resolution in the context of a consistent and systematic observation strategy. The integration of these data sets in existing environmental and climate science components will allow a new global view of the Earth system and its dynamics, initiating a performance leap in ecosystem and climate change modelling.
The investigation of high-silica rhyolitic rocks collected in the recent ICDP drilling from the Snake River Plain (SRP) volcanic province (western United States) as well as rocks from the adjacent rhyolitic complexes offers a unique opportunity to track the evolution of magma storage conditions in time and space in the 'Yellowstone hotspot' intracontinental volcanic province. The application of various geothermometers which can be used to determine pre-eruptive temperatures show a general trend indicating a general decrease of temperature over the last 16 Ma. However, the depth (or pressure) of the magma chambers is difficult to constrain and remains mainly unknown because the mineral assemblage in the rhyolitic systems is not suitable for geobarometry. As an alternative to mineral compositions, the silica content of rhyolitic melts can be used to constrain pressure, provided that the silicate melts have cotectic compositions (melts coexisting with quartz and feldspar), which is the case for most SRP rhyolites. From studies in synthetic systems, it is well known that the silica content of cotectic melts decreases with increasing pressure and that it may be used as barometer in pressure ranges of ca 1000 - 50 MPa. However, the evolution of silica content with pressure is not calibrated for natural systems containing up to 2 wtProzent Cao and 4 wtProzent FeO. In this study, we plan to determine the role of pressure on the silica content of cotectic melts compositions relevant for SRP compositions. The experimental data are crucial to interpret the natural glass compositions (matrix glass and glass inclusions) analyzed in the ICDP core samples and will be used to extract quantitative information on the depth of magma storage prior to eruption. The dataset obtained from various eruptive events (samples from ICDP drillings and other SRP rhyolites) will be used to check if there is an evolution of the depth of magma storage over the lifetime of the 'Yellowstone hotspot' in the last 16 Ma and if there is a correlation between the pre-eruptive pressure, the volume of erupted material, the temperature (or differentiation level) and the water activity of magmas. This study will be conducted in close cooperation with other U.S. groups who are in charge of the analysis of ICDP rhyolitic samples. It is emphasized that the experimental database obtained in this project can also be applied to other case studies (high silica rhyolites, A-type granites).
Objective: Integrated assessment and energy-economy models have become central tools for informing long-term global and regional climate mitigation strategies. There is a large demand for improved representations of complex system interactions and thorough validation of model behaviour in order to increase user confidence in climate policy assessments. ADVANCE aims to respond to this demand by facilitating the development of a new generation of integrated assessment models. This will be achieved by substantial progress in key areas where model improvements are greatly needed: end use and energy service demand; representation of heterogeneity, behaviour, innovation and consumer choices; technical change and uncertainty; system integration, path dependencies and resource constraints; and economic impacts of mitigation policies. In the past, methodological innovations and improvements were hindered by the unavailability of suitable input data. The ADVANCE project will make a large and coordinated effort to generate relevant datasets. These datasets, along with newly developed methodologies, will be made available to the broader scientific community as open-access resources. ADVANCE will also put a focus on improved model transparency, model validation, and data handling. A central objective of ADVANCE is to evaluate and to improve the suitability of models for climate policy impact assessments. The improved models will be applied to an assessment of long-term EU climate policy in a global context, and disseminated to the wider community. The ADVANCE consortium brings together long-standing expertise in integrated assessment and energy-economy modelling with a strong expertise in material flows, energy system integration, and energy service demand.
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