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Data supplement to: Chemistry and Microbiology of the Critical Zone along a steep climate and vegetation gradient in the Chilean Coastal Cordillera

The Chilean Coastal Cordillera features a spectacular climate and vegetation gradient, ranging from arid and unvegetated areas in the north to humid and forested areas in the south. The DFG Priority Program "EarthShape" (Earth Surface Shaping by Biota) uses this natural gradient to investigate how climate and biological processes shape the Earth's surface. We explored the critical zone, the Earth's uppermost layer, in four key sites located in desert, semidesert, mediterranean, and temperate climate zones of the Coastal Cordillera, with the focus on weathering of granitic rock. Here, we present first results from four ~2m-deep regolith profiles to document: (1) architecture of weathering zone; (2) degree and rate of rock weathering, thus the release of mineral-derived nutrients to the terrestrial ecosystems; (3) denudation rates; and (4) microbial abundances of bacteria and archaea in the saprolite. From north to south, denudation rates from cosmogenic nuclides are ~10 t km-2 yr-1 at the arid Pan de Azúcar site, ~20 t km-2 yr-1 at the semi-arid site of Santa Gracia, ~60 t km-2 yr-1 at the mediterranean climate site of La Campana, and ~30 t km-2 yr-1 at the humid site of Nahuelbuta. A and B horizons increase in thickness and elemental depletion or enrichment increases from north (~26 °S) to south (~38 °S) in these horizons. Differences in the degree of chemical weathering, quantified by the chemical depletion fraction (CDF), are significant only between the arid and sparsely vegetated site and the other three sites. Differences in the CDF between the sites, and elemental depletion within the sites are sometimes smaller than the variations induced by the bedrock heterogeneity. Microbial abundances (bacteria and archaea) in saprolite substantially increase from the arid to the semi-arid sites. With this study, we provide a comprehensive dataset characterizing the Critical Zone geochemistry in the Chilean Coastal Cordillera. This dataset confirms climatic controls on weathering and denudation rates and provides prerequisites to quantify the role of biota in future studies. The data are supplementary material to Oeser et al. (2018). All samples are assigned with International Geo Sample Numbers (IGSN), a globally unique and persistent Identifier for physical samples. The IGSNs are provided in the data tables and link to a comprehensive sample description in the internet. The content of the eight data tables is: Table S1: Catena properties of the four primary EarthShape study areas. Table S2: Major and selected trace element concentration for bedrock samples. Table S3 Normative modal abundance of rock-forming minerals. Table S4: Major and selected trace element concentration for regolith samples and dithionite and oxalate soluble pedogenic oxides. Table S5: Weathering indices CDF and CIA, and the mass transfer coefficients (τ) for major and trace elements along with volumetric strain (ɛ). Table S6: Chemical weathering and physical erosion rates Table S7: Relative microbial abundances in saprolite of the four study areas. Table S8: Uncorrected major and trace element concentration. The data tables are provided as one Excel file with eight spreadsheets, as individual tables in .csv format in a zipped archive and as printable PDF versions in a zipped archive.

Chemical and isotope data on the deep regolith’s source of mineral nutrients in mountainous temperate forest ecosystems

The data herein were used to trace the source and depth of nutrient uptake in two mountainous temperate forest ecosystems in southern Germany (Conventwald/Black Forest and Mitterfels/Bavarian Forest). Presented are phosphorus (P) concentrations from various P fractions of soil, saprolite, weathered bedrock and unweathered bedrock samples from drilling cores (depth: 20 m, site Conventwald (CON), and 30 m, site Mitterfels (MIT)) obtained by sequential extractions following the Hedley fractionation method. Further, the dataset contains strontium (Sr) and beryllium (Be) isotope data from drilling cores mentioned above. 87Sr/86Sr data are provided for bulk samples of forest floor, soil, saprolite, weathered bedrock, and unweathered bedrock. For soil and saprolite samples, additional Sr isotope ratios of the water-soluble and the exchangeable Sr fractions are provided. 87Sr/86Sr, beryllium concentrations (measured by Quadrupole-ICP-MS) and 10Be(meteoric)/9Be data from living leaves, needles, and stem wood (heartwood and sapwood of Fagus sylvatica and Picea abies) from both study sites are reported. Beryllium concentrations (measured by ICP-OES) and isotope ratios of amorphous oxides sequentially extracted from soil and saprolite at CON and MIT are provided. Soil pH at CON and MIT is also provided. Compiled concentrations of K, Ca, Mg and P and total deposition rates of atmospheric dust deposition are also included in the dataset. The data presented here stem from sampling campaigns and analyses described in Uhlig et al. (2020) to which they are supplementary material to. Samples were mainly processed in the Helmholtz Laboratory for the Geochemistry of the Earth Surface (HELGES), the University of Bonn (P Hedley fractionation) and the University of Cologne - Centre for Accelerator Mass Spectrometry (AMS) (10Be measurements). Tables supplementary to the article, including data quality control, are provided in pdf and xls formats. In addition, data measured in the course of the study are also provided as machine readable ASCII files. All samples are indexed with an International Geo Sample Number (IGSN). Sample metadata can be viewed by adding the IGSN to the “http://igsn.org/” URL (e.g. igsn.org/GFDUH00LT).

Laboratory and field data used to determine the controls of drainage density differences in two granitoid plutons in semi-arid Central Chile

Here we provide in situ 10Be data, meteoric 10Be data, X-Ray fluorescence data, infiltration rate field date, chemical extraction data, a summary of grain size data, all grain size data (Table S7), mineral point counting data, XRD data, soil grain size data, and data from laboratory measurements of hydrological parameters. Field work in Santa Gracia was conducted in February of the years 2019 and 2020 and laboratory work was conducted between 2019 and 2023. This data publication accompanies our study (Lodes et al., 2024), in which we investigate whether lithology controls drainage density in Santa Gracia, a semi-arid field site in Central Chile. In the study, we compare the density of drainages in two distinct, neighbouring landscapes underlain by a monzogranite and two diorite plutons (which we refer to as the “inner diorite” and the “outer diorite”). We collected multiple datasets to understand the underlying mechanisms behind the drainage density differences. The data was collected as part of the German Science Foundation (DFG) priority research program SPP-1803 “EarthShape: Earth Surface Shaping by Biota” (grant SCHE 1676/4-1 and -2 to D. S.; funding of P. G. through grant BE 1780/53-1 and -2).

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