Other language confidence: 0.9991979087176527
The dataset contain full 40Ar/39Ar geochronological data completed by multi collector noble gas mass spectrometry on plagioclase and glass separates from a tuff sample interbedded in Pleistocene marine claystone (Argille di Spadafora) of northeastern Sicily (Italy). Tuff unit VU7 was identified in the field using the published base map and stratigraphic nomenclature of Di Bella et al. (2016), which correlates to bathyal marine marl (Argille di Vito Superiore) in southern Calabria. The tuff contains stratified white lapilli with abundant fresh volcanic glass shards and was deposited by a submarine turbidity current from a single volcanic eruption. The Ar laserprobe facility was realized with the financial support of CNR. The CO2 laser system was acquired within the PNRR – Mission 4, “Education and Research” - Component 2, “From research to business” - Investment line 3.1, “Fund for the creation of an integrated system of research and innovation infrastructures” - Project IR0000025 MEET. EPOS JRU Italia is acknowledged for support in the Laboratory maintenance.
Carbonate minerals of the dolomite-ankerite and magnesite-siderite series are often found in sedimentary basins associated with economically viable ore deposits and as alteration product of Ca-Mg-Fe-silicates in igneous and metamorphic rocks. Analysis of oxygen and carbon isotopes in such carbonates gives important information, among others, on their evolution and spatial distribution during sediment burial and diagenesis, crystallization temperature during sedimentation, diagenesis and hydrothermal alteration, fluid and carbon sources, mechanisms of CO2 sequestration (e.g., (Śliwiński et al., 2016, 2018 and references therein). Because of their common chemical zoning at the microscale, in-situ techniques such as Secondary Ion Mass Spectrometry (SIMS) are fundamental to unravel intragrain and intergrain isotopic heterogeneities at scales < 50 µm. Due to instrumental artifacts, SIMS analyses need to be calibrated with matrix-matched reference materials to be accurate. This dataset describes a newly compiled set of Ca-Mg-Fe carbonates that were characterized for their mineralogical (XRD), major and minor element chemical composition (EPMA), oxygen and carbon isotopic composition by acid digestion gas-source isotope ratio mass spectrometry (GS-IRMS), and oxygen and carbon isotopic homogeneity at the microscale (SIMS). Three dolomites and one ankerite with Fe# (molar Fe/(Fe+Mg)) ranging from 0.0004 to 0.3429, one magnesite (Fe# = 0.0099) and one siderite (Fe# = 0.6152) are now available for the global SIMS community.
We report the results of high throughput, robust, and sensitive method for the precise analysis of 56Fe/54Fe and 57Fe/54Fe, performed using Multi-Collector-Inductively Coupled Plasma-Mass Spectrometer (MC-ICP-MS), Thermo Scientific Neptune PlusTM. We measured the Fe isotope compositions of widely used standard reference materials ranging from basaltic to rhyolitic compositions (JB-2, BHVO-2, BE-N, AGV-1, and RGM-1). We also propose a new iron isotope reference material, IAEA-B5, a basalt from Mount Etna already commonly used as a reference for B and Li isotopes. Funding information: EU-Next Generation EU Mission 4 ‘Education and Research’-Component 2: ‘From research to business’-Investment 3.1: ‘Fund for the realization of an integrated system of research and innovation infrastructures’-Project IR0000032-ITINERIS-Italian Integrated Environmental Research Infrastructures System-CUP B53C22002150006. EPOS European Plate Observing System
Tables that include information and calculations associated with water samples collected from rivers in Central Italy. The goal of the project was to determine the carbon budget for the Central Apennine Mountains of Italy, by accounting for weathering reactions that are responsible for either CO2 drawdown or release into the atmosphere. The carbon budget was created by: 1) analysing samples from different water bodies and sources in the Central Apennines (rivers, lakes, and groundwater) for ion and isotope signatures, and 2) by incorporating the ion and isotope signatures from the waters into an inversion model that partitions these signatures into different sources (e.g. minerals, vegetation, atmospheric sources) around the landscape. All data associated with this publication are provided in a single excel spreadsheet that contains a separate tab for each of the 18 Tables. The supplementary data include: 1) Information on the locations of the water samples and associated water bodies, described in the “Sampling Methods” section, 2) ion and isotope measurements from the water samples, described in the “Analytical Procedure” section, 3) the setup and output from the inversion model, and 4) the CO2 calculations that form the basis for the carbon budget, described in the “Data Processing” section. Water samples were collected over two seasons, in winter and summer; data in the tables are divided by sampling season, where indicated in the content description. For a full description of the sampling strategy, data, and methods, please refer to: Erlanger et al. (2024) “Deep CO2 release and the carbon budget of the central Apennines modulated by geodynamics” Nature Geoscience.
This database contains a compilation of published zircon geochronology, chemistry and isotope data. The database was created through automated web scraping of the Figshare data repository. Data included U-Pb and Pb-Pb dating, Lu-Hf isotopes, trace element and rare earth element chemistry and isotopes. Where available, metadata on the analytical method, lithology, sample description and sampling coordinates are included. All analyses include a citation and doi link to the original data hosted on Figshare. See metadata table for descriptions of table headers. See associated manuscript for web scraping code.
A compilation of 29,574 published radiometric dates for metamorphic rocks from the South American Andes and adjacent parts of South America have been tabulated for access by researchers via GEOROC Expert Datasets. The compilation exists as a spreadsheet for access via MS Excel, Google Sheets, and other spreadsheet applications. Initial igneous compilations were utilized in two publications by the author, Pilger (1981, 1984). The compilations have been added to in subsequent years with the metamorphic and sedimentary compilations separated in the last few years. Locations in latitude and longitude are largely taken from the original source, if provided, with UTM locations maintained and converted; in some cases, sample locations were digitized from electronic maps if coordinates were otherwise not available. Analytical results are not included to prevent the files from becoming too large. The existing compilation incorporates compilations by other workers in smaller regions of the Andes. References to original and compilation sources are included. While I am updating reconstructions of the South American and Nazca/Farallon plates, incorporating recent studies in the three oceans, for comparison with the igneous dates for the past 80 m. y., it is hoped that the spreadsheets will be of value to other workers. Reliability: In most cases the data have been copy/pasted from published or appendix tables. In a few cases, the location has been digitized from published maps; the (equatorial equidistant) maps were copied into Google Earth and positioned according to indicated coordinates, with locations digitized and copied/pasted into the spreadsheet. (It is possible that published maps are conventional Mercator-based, even if not so identified, rather than either equatorial equidistant or Universal Transverse Mercator; this can be a source of error in location. For UTMs, the errors should be minor.) Duplicates are largely recognized by equivalent IDs, dates, and uncertainties. Where primary sources have been accessed, duplicate data points in compilations are deleted. (Analytic data are NOT included.) This compilation is part of a series. Companion compilations of radiometric dates from igneous and sedimentary rocks are available at https://doi.org/10.5880/digis.e.2023.005 and https://doi.org/10.5880/digis.e.2023.006, respectively.
In the Western Tauern Window, Zillertal Alps (Austria/Italy), metasediments of a Mesozoic intra-montane basin ("Pfitsch-Mörchner basin"; Veselá and Lammerer, 2008) are exposed. The (me-ta)sediments were deposited on a Variscan basement, which comprises different types of meta-granitoids and their (Pre)-Variscan metamorphic country rocks. The chemical composition (major and trace elements) of these rocks is presented for 205 samples. In the metasediments (103 samples), we distinguish the following units (from base to top): metaconglomerate (14 samples) – mica schist (19) – carbonate-mica schist (9) – tourmaline gneiss (35) – lazulite quartzite (25) – marble (1). In the basement to the NW of the basin, we distinguish two different types of orthogneiss (both Zentralgneis of the Tux unit, in the local nomenclature two varieties Augenflasergneis and Schrammacher gneiss; 32 samples) and the roof pendant of these gneisses with serpentinite (10 samples), amphibolite, and paragneiss (no analyses presented). In the SE of the basin we distinguish orthogneiss from the Zillertal branch of the Zentralgneis (7 samples), biotite-chlorite-plagioclase gneiss (9 samples), amphibolite, and (Pre-)Variscan graphitic micaschist with the local name Furtschagl schist (no analyses presented), and at the base of the basin sediments a schistose pyrite quartzite (31) with lenses of magnetite-chloritoide-staurolite-chlorite rich rocks (13 samples MCSC-lenses, interpreted as paleosol, Barrientos and Selverstone, 1987). From a subset of these samples (23 samples), rare earth elements were determined, and from another subset of 25 samples 11B/10B boron isotope ratios and whole rock B-contents. This extends a previously published data set of B isotope ratios in tourmaline from the metasedimen-tary unit (Berryman et al. 2017). For a test of stratigraphic correlation, typical rocks from the meta-conglomerate, the carbonate-mica schist, lazulite quartzite, and marble (one sample each) were analyzed for 87Sr/86Sr isotope ratios.
This dataset was used to analyse the link between chemical weathering and erosion rates across the southern tip of Taiwan. The weathering of silicate minerals is a key component of Earth’s long-term carbon cycle, and it stabilises Earth’s climate by sequestering carbon dioxide (CO2) from the atmosphere – thereby balancing CO2-emissions from the mantle. Conversely, the weathering of accessory carbonate and sulphides acts as a CO2 source. Chemical weathering is fundamentally dependent on the exposure of fresh minerals by erosion. With these data we investigated the link between the exposure of rocks by erosion and the chemical weathering of silicates, carbonates, and sulphides across a landscape with a significant erosion-rate gradient and comparatively little variation in runoff and lithology. This dataset includes new major element chemistry and water isotopes of river waters collected from across the southern tip of Taiwan as well as associated topographic and lithologic data (tab 1 in the excel table). Moreover, the data include a compilation of published 10Be-derived erosion rates from a subset of the sampled rivers (tab 2 in the excel file) and available major element chemistry from hotsprings in the region (tab 3 in the excel file). Using a mixing model, we derived the cation contributions from silicate and carbonate weathering as well as from hotspring and cyclic sources. Further, we estimated the erosion rates for each sample from the compiled 10Be data and the steepness of river channels, and we estimated saturation and pH in the weathering zone. For more information please refer to the associated data description file and especially to Bufe et al. (2021).
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