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Experimental investigations into the influence of organic complexing agents and inorganic anions (Cl-, NO3-, SO42- und PO43-) on the transformation behaviour and the mobility of metallic palladium (Pd) and PdO

The projects goal is to examine the Mobility and transformation behaviour of emitted palladium from automobile exhaust catalysts into the environment. To achieve this, I will examine the influence of commonly present organic complexing agents like citric acid, amino acid (L-Methionin) and ethylenediamine tetra acetic acid (EDTA), as well as inorganic anion species (Cl-, NO3-, SO42- und PO43-), on the chemical behaviour and transformation of metallic palladium (Pd-Mohr) and PdO into more soluble species. The analytical experiments will be conducted over different time periods (1, 10, 20, 30, 40, 50 and 60 days), involving different concentrations of the various complexing agents under examination (0.001, 0.01 and 0.1 M). The results will help clarify the extent to which Pd Mobility is influenced by time and the presence of various complexing agents at different concentrations. In addition, surface analyses of isolated particles using X-ray photoelectron spectroscopy (XPS) will be used to examine the influence of organic compounds and inorganic anion species, on the transformation of metallic palladium and PdO. The proposed study will significantly help to shed light on questions related to the environmental transformation of Pd into more toxic species following emission in car exhausts, a poorly understood process to date.

GTS Bulletin: FCDL34 EDZO - Forecast (details are described in the abstract)

The FCDL34 TTAAii Data Designators decode as: T1 (F): Forecast T1T2 (FC): Aerodrome (VT < 12 hours) A1A2 (DL): Germany (The bulletin collects reports from stations: EDAC;ALTENBURG-NOBITZ ;COCHSTEDT ;EDGS;SIEGERLAND ;EDHL;LUEBECK BLANKENSEE ;EDLN;MOENCHENGLADBACH ;EDMA;AUGSBURG ;EDQM;HOF-PLAUEN ;EDNY;FRIEDRICHSHAFEN;EDZO;)

GTS Bulletin: FCDL35 EDZO - Forecast (details are described in the abstract)

The FCDL35 TTAAii Data Designators decode as: T1 (F): Forecast T1T2 (FC): Aerodrome (VT < 12 hours) A1A2 (DL): Germany (The bulletin collects reports from stations: EDHA;EDHI;HAMBURG-FINKENWERDER ;EDHK;KIEL-HOLTENAU ;EDJA;MEMMINGEN ALLGAU ;EDMO;OBERPFAFFENHOFEN ;EDTD;DONAUESCHINGEN-VILLINGEN ;EDTL;LAHR ;EDTY;SCHWAEBISCH HALL ;EDVE;BRAUNSCHWEIG WOLFSBURG ;EDXW;WESTERLAND SYLT ;EDZO;)

GTS Bulletin: SADL35 EDZO - Surface data (details are described in the abstract)

The SADL35 TTAAii Data Designators decode as: T1 (S): Surface data T1T2 (SA): Aviation routine reports A1A2 (DL): Germany (The bulletin collects reports from stations: EDHA;EDHI;HAMBURG-FINKENWERDER ;EDHK;KIEL-HOLTENAU ;EDJA;MEMMINGEN ALLGAU ;EDMO;OBERPFAFFENHOFEN ;EDOP;SCHWERIN PARCHIM ;EDTD;DONAUESCHINGEN-VILLINGEN ;EDTL;LAHR ;EDTY;SCHWAEBISCH HALL ;EDVE;BRAUNSCHWEIG WOLFSBURG ;EDXW;WESTERLAND SYLT ;EDZO;)

GTS Bulletin: SADL34 EDZO - Surface data (details are described in the abstract)

The SADL34 TTAAii Data Designators decode as: T1 (S): Surface data T1T2 (SA): Aviation routine reports A1A2 (DL): Germany (The bulletin collects reports from stations: EDAC;ALTENBURG-NOBITZ;EDBC;MAGDEBURG-COCHSTEDT;EDGS;SIEGERLAND;EDHL;LUEBECK BLANKENSEE;EDLN;MOENCHENGLADBACH;EDLP;PADERBORN LIPPSTADT;EDLW;DORTMUND;EDMA;AUGSBURG;EDNY;FRIEDRICHSHAFEN;EDQM;HOF-PLAUEN;EDRZ;ZWEIBRUECKEN;EDSB;KARLSRUHE BADEN-BADEN;EDZO;)

GTS Bulletin: LCDL34 EDZO - Aviation Information in XML (details are described in the abstract)

The LCDL34 TTAAii Data Designators decode as: T1 (L): Aviation Information in XML A1A2 (DL): Germany T1T2 (LC): Aerodrome Forecast ("TAF") (VT<12 hours)"(The bulletin collects reports from stations: EDAC;ALTENBURG-NOBITZ;EDBC;COCHSTEDT;EDGS;SIEGERLAND;EDHL;LUEBECK BLANKENSEE;EDLN;MOENCHENGLADBACH;EDMA;AUGSBURG;EDQM;HOF-PLAUEN;EDNY;FRIEDRICHSHAFEN;EDZO;)

GTS Bulletin: SADL40 EDZW - Surface data (details are described in the abstract)

The SADL40 TTAAii Data Designators decode as: T1 (S): Surface data T1T2 (SA): Aviation routine reports A1A2 (DL): Germany (The bulletin collects reports from stations: EDOP;SCHWERIN PARCHIM ;EDVK;KASSEL-CALDEN ;EDMO;OBERPFAFFENHOFEN ;EDXW;WESTERLAND SYLT ;EDTL;LAHR ;EDDV;HANNOVER ;EDDW;BREMEN ;EDFH;FRANKFURT-HAHN ;EDDR;SAARBRUECKEN ;EDDS;STUTTGART ;EDDT;BERLIN-TEGEL INT ;EDDM;MUNICH INT ;EDTD;DONAUESCHINGEN-VILLINGEN ;EDDN;NUERNBERG;EDHI;HAMBURG-FINKENWERDER ;EDHL;LUEBECK BLANKENSEE ;EDDP;LEIPZIG HALLE ;EDFM;MANNHEIM-CITY ;EDHK;KIEL-HOLTENAU ;EDBC;COCHSTEDT ;EDVE;BRAUNSCHWEIG WOLFSBURG ;EDDK;COLOGNE BONN ;EDJA;MEMMINGEN ALLGAU ;EDDL;DUESSELDORF INT ;EDDE;ERFURT ;EDDF;FRANKFURT AM MAIN INT ;EDDG;MUENSTER OSNABRUECK ;EDDH;HAMBURG ;EDLW;DORTMUND ;EDDC;DRESDEN ;EDDB;BERLIN-Brandenburg INT ;EDLV;NIEDERRHEIN ;EDLP;PADERBORN LIPPSTADT ;EDLN;MOENCHENGLADBACH ;EDNY;FRIEDRICHSHAFEN ;EDSB;KARLSRUHE BADEN-BADEN ;EDMA;AUGSBURG ;EDQM;HOF-PLAUEN ;EDRZ;ZWEIBRUECKEN ;EDAC;ALTENBURG-NOBITZ ;EDTY;SCHWAEBISCH HALL ;EDAH;HERINGSDORF ;EDGS;SIEGERLAND ;) (Remarks from Volume-C: COMPILATION FOR REGIONAL EXCHANGE)

GTS Bulletin: LCDL35 EDZO - Aviation Information in XML (details are described in the abstract)

The LCDL35 TTAAii Data Designators decode as: T1 (L): Aviation Information in XML A1A2 (DL): Germany T1T2 (LC): Aerodrome Forecast ("TAF") (VT<12 hours)"(The bulletin collects reports from stations: EDHA;EDHI;HAMBURG-FINKENWERDER;EDHK;KIEL-HOLTENAU;EDJA;MEMMINGEN ALLGAU;EDMO;OBERPFAFFENHOFEN;EDTD;DONAUESCHINGEN-VILLINGEN;EDTL;LAHR;EDTY;EDVE;BRAUNSCHWEIG WOLFSBURG;EDXW;WESTERLAND SYLT;EDZO;)

GTS Bulletin: LADL34 EDZO - Aviation Information in XML (details are described in the abstract)

The LADL34 TTAAii Data Designators decode as: T1 (L): Aviation Information in XML A1A2 (DL): Germany T1T2 (LA): Aviation routine reports ("METAR")(The bulletin collects reports from stations: EDAC;ALTENBURG-NOBITZ;EDBC;MAGDEBURG-COCHSTEDT;EDGS;SIEGERLAND;EDHL;LUEBECK BLANKENSEE;EDLN;MOENCHENGLADBACH;EDLP;PADERBORN LIPPSTADT;EDLW;DORTMUND;EDMA;AUGSBURG;EDNY;FRIEDRICHSHAFEN;EDQM;HOF-PLAUEN;EDRZ;ZWEIBRUECKEN;EDSB;KARLSRUHE BADEN-BADEN;EDZO;)

GTS Bulletin: LADL35 EDZO - Aviation Information in XML (details are described in the abstract)

The LADL35 TTAAii Data Designators decode as: T1 (L): Aviation Information in XML A1A2 (DL): Germany T1T2 (LA): Aviation routine reports ("METAR")(The bulletin collects reports from stations: EDHA;EDHI;HAMBURG-FINKENWERDER;EDHK;KIEL-HOLTENAU;EDJA;MEMMINGEN ALLGAU;EDMO;OBERPFAFFENHOFEN;EDOP;SCHWERIN PARCHIM;EDTD;DONAUESCHINGEN-VILLINGEN;EDTL;LAHR;EDTY;EDVE;BRAUNSCHWEIG WOLFSBURG;EDXW;WESTERLAND SYLT;EDZO;)

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