Magnetic resonance tomography (MRT) on microcosm soil cores (200 mm Ø) used for CeMiX, comprising naturally stacked subsoil down to 700 mm plus topsoil from CeFiT, will be implemented at a laterally partially open Split 1.5 T magnet, with intended final in-plane spatial resolution of 200 Micro m. Three-dimensional biopore distributions and dynamics of their formation within the cores will be determined non-invasively and compared to complementing CT analyses of SP 2. One major aim is a non-invasive differentiation of the biopores into earthworm- and root system-originating ones and currently air-, water-, root- and earthwormfilled ones, based on NMR relaxation parameters. Attempts will additionally be made to classify different wall coatings of the biopores with regard to their water affinity. Dynamics of water distribution within the microcosm core and its biopore structures, starting from initial values taken from CeFiT (SP 3), will be documented with an in-plane resolution of 5 mm, in parallel to measurements of root growth dynamics for calculation of biomass and root surface area. Special emphasis will be put on the role of the plant root system for a re-distribution of water/D2O (and solutes) between different soil layers. Finally we will attempt MRT-controlled sample collection from the microcosm cores, to get - together with our research unit partners of SPs 4-8 - repeated access to minimally invasively acquired data on nutrient and microorganism distributions in concert with non-invasively collected water and root distribution data as a basis for dynamic modelling of water and solute circuits in SP 10. Beside the microcosm cores, flat rhizotrons as used in SP 3 will be employed to enable measurements of root and shoot hydrostatic pressure profiles with pressure probes, in addition to MRT measurements. In this way water distributions and corresponding driving forces and growth dynamics will be measured altogether in a minimally invasive manner.
Diese Datenserie beschreibt das Sicherheitspotential der Staatsstraßen in der Baulast des Freistaats sowie der Bundesstraßen in sächsischer Verwaltung. Das Sicherheitspotential bewertet die Verkehrssicherheit von Straßennetzen und wird nach dem Verfahren der „Empfehlungen für die Sicherheitsanalyse von Straßennetzen - ESN“ (FGSV, 2003) berechnet. Zielstellung des Verfahrens ist es, Mängel der Straßenführung, der Straßengestaltung sowie des Straßenzustandes zu identifizieren. Die Bewertung erfolgt auf Grundlage der Differenz des tatsächlichen und des bei richtliniengerechtem Ausbau erwarteten Unfallgeschehens. Streckenabschnitte mit einem über dem akzeptierten Wert liegenden Unfallgeschehen weisen ein Potential zur Verbesserung der Verkehrssicherheit - ein Sicherheitspotential – auf (FGSV, 2003). Die ESN-Analyse wird in einem Turnus von drei Jahren durchgeführt. Die Datenserie umfasst die Betrachtungszeiträume 2014-2016, 2017-2019 sowie 2020-2022. Für Streckenabschnitte, die im Betrachtungszeitraum Änderungen unterlegen gewesen sind (bspw. Umwidmungen, Baumaßnahmen von mehr als sechs Monaten), konnte keine Bewertung durchgeführt werden. Eine Berechnung des Sicherheitspotential konnte ebenso nicht erfolgen, wenn für Streckenabschnitte keine Angabe der Verkehrsstärke (DTV) vorlag. Es erfolgt die Unterteilung des Sicherheitspotentials in fünf SIPO-Klassen (kein SIPO, 0-50, 50-110, 110-210, ≥ 210 [1000€/(km a)].
In the Earth, the dynamo action is strongly linked to core freezing. There is a solid inner core, the growth of which provides a buoyancy flux that drives the dynamo. The buoyancy in this case derives from a difference in composition between the solid inner core and the fluid outer core. In planetary bodies smaller than the Earth, however, this core differentiation process may differ - Fe may precipitate at the core-mantle boundary (CMB) rather than in the center and may fall as iron snow and initially remelt with greater depth. A chemical stable sedimentation zone develops that comprises with time the entire core - at that time a solid inner core starts to grow. The dynamics of this system is not well understood and also whether it can generate a magnetic field or not. The Jovian moon Ganymede, which shows a present-day magnetic dipole field, is a candidate for which such a scenario has been suggested. We plan to study this Fe-snow regime with both a numerical and experimental approach. In the numerical study, we use a 2D/3D thermo-chemical convection model that considers crystallization and sinking of iron crystals together with the dynamics of the liquid core phase (for the 3D case the influence of the rotation of the Fe snow process is further studied).The numerical calculations will be complemented by two series of experiments: (1) investigations in metal alloys by means of X-ray radioscopy, and (2) measurements in transparent analogues by optical techniques. The experiments will examine typical features of the iron snow regime. On the one hand they will serve as a tool to validate the numerical approach and on the other hand they will yield important insight into sub-processes of the iron snow regime, which cannot be accessed within the numerical approach due to their complexity.
Community forestry has not met the great public expectations on a significant contribution to sustainable forestry yet. Recent research in the management and policy of community forestry describes a complex process of multi level social choice which determines the outcomes. Our hypothesis is that the key factors determining the outcomes of community forestry are the interests and power of the external stake holders. This hypothesis will be tested in a comparative quantitative and qualitative analysis. In seven countries comprising developed and developing countries 84 cases will be used for comparison. The comparative analysis will be carried out by one PhD student financed by the project. He will do the field work in close cooperation with PhD students who are already conducting their PhD analysis the different countries. The comparative analysis is aimed to explore key drivers of community forestry which are not yet identified in literature.
Dissolved organic matter (DOM) is one major source of subsoil organic matter (OM). P5 aims at quantifying the impact of DOM input, transport, and transformation to the OC storage in the subsoil environment. The central hypotheses of this proposal are that in matric soil the increasing 14C age of organic carbon (OC) with soil depth is due to a cascade effect, thus, leading to old OC in young subsoil, whereas within preferential flowpaths sorptive stabilization is weak, and young and bioa-vailable DOM is translocated to the subsoil at high quantities. These hypotheses will be tested by a combination of DOC flux measurements with the comparative analysis of the composition and the turnover of DOM and mineral-associated OM. The work programme utilizes a DOM monitoring at the Grinderwald subsoil observatory, supplemented by defined experiments under field and labora-tory conditions, and laboratory DOM leaching experiments on soils of regional variability. A central aspect of the experiments is the link of a 13C-leaf litter labelling experiment to the 14C age of DOM and OM. With that P5 contributes to the grand goal of the research unit and addresses the general hypotheses that subsoil OM largely consists of displaced and old OM from overlying horizons, the sorption capacity of DOM and the pool size of mineral-associated OM are controlled by interaction with minerals, and that preferential flowpaths represent 'hot spots' of high substrate availability.
bifa wurde vom Bayerischen Staatsministerium für Umwelt und Gesundheit mit der Durchführung des Projekts IPP als Instrument des betrieblichen Klimaschutzes - eine Anleitung insbesondere für kleine und mittlere Unternehmen (KMU) beauftragt. Im Rahmen dieses Projekts werden u. a. acht Workshops mit Vertretern der Wirtschaft durchgeführt. Der erste Workshop fand bereits im Februar 2010 unter dem Motto Grüne Logistik: Visionen - Chancen - Risiken statt. Es nahmen 13 Unternehmer aus verschiedenen Bereichen der Logistik teil. Nach kurzen Impulsvorträgen zur Integrierten Produktpolitik und Grünen Logistik wurden in drei Arbeitsgruppen Möglichkeiten der Umsetzung von grüner Logistik im eigenen Unternehmen diskutiert und Ansatzpunkte gesucht, wie durch verstärkte Kooperation und Kommunikation die umweltbezogenen Vorteile der grünen gegenüber der normalen Logistik noch weiter ausgeschöpft werden können. Das äußerst heterogene Teilnehmerfeld wurde sehr positiv bewertet. So beschreibt ein Teilnehmer: Da waren ein Unternehmer mit eigenem Fuhrpark, ein kleiner mittelständischer Spediteur, ein großer mittelständischer Spediteur und ich aus der verladenden Wirtschaft. In der abschließenden Diskussion tauchte neben zahlreichen Ansatzpunkten zur Umsetzung immer wieder eine Frage auf: Was ist Green Logistics ? Wie können wir sie messen, was umfasst sie, wer nimmt daran teil und wer bezahlt sie? . Zur Abgrenzung der grünen gegenüber der normalen Logistik müssen Standards geschaffen werden, die den Unternehmen helfen, sich noch intensiver mit Möglichkeiten der Umweltentlastung im Bereich der Logistik auseinanderzusetzen. In einem weiterführenden Workshop im April 2010 setzten sich die Teilnehmer mit diesen Fragestellungen auseinander und erarbeiteten unter dem Titel Grüne Logistik: Standards generieren und umsetzen - aber wie? Vorschläge und Handlungsempfehlungen für die Praxis. Das IPP-Projekt ist für unterschiedliche Wirtschaftszweige von großem Interesse: So wurden weitere Workshops zu Themen wie Reach , Emissionen/ CDM , Bauwirtschaft und Recycling erfolgreich durchgeführt. Methoden: Analyse und Moderation sozialer Prozesse.
Sauropod dinosaurs represent one of the most important components of Mesozoic terrestrial vertebrate faunas, yet their early evolution and diversification in the Jurassic is still poorly understood. Furthermore, most of the pertinent data so far comes from Early and Middle Jurassic rocks in eastern Asia. The only abundant basal sauropod material reported from the Western Hemisphere so far comes from the Middle Jurassic Cañadón Asfalto Formation of Chubut province, Argentina, from where two species, Patagosaurus fariasi and Volkheimeria chubutensis, have been described. Especially the first of these taxa has figured prominently in basal sauropod phylogenies. However, recent research suggests that more sauropods are represented in the original material referred to this species, and intensive fieldwork in the rocks that have yielded these materials has resulted in the recovery of a wealth of new material. Thus, the objective of this project is a revision of the original materials of Patagosaurus as well as an incorporation of new materials. The alpha taxonomy of the sauropods from the Cañadón Asfalto Formation will be established, detailed osteological descriptions of the different taxa provided and their significance for our understanding of early sauropod evolution will be evaluated.
The development of sustainable and efficient energy conversion processes at interfaces is at the center of the rapidly growing field of basic energy science. How successful this challenge can be addressed will ultimately depend on the acquired degree of molecular-level understanding. In this respect, the severe knowledge gap in electro- or photocatalytic conversions compared to corresponding thermal processes in heterogeneous catalysis is staggering. This discrepancy is most blatant in the present status of predictive-quality, viz. first-principles based modelling in the two fields, which largely owes to multifactorial methodological issues connected with the treatment of the electrochemical environment and the description of the surface redox chemistry driven by the photo-excited charges or external potentials.Successfully tackling these complexities will advance modelling methodology in (photo)electrocatalysis to a similar level as already established in heterogeneous catalysis, with an impact that likely even supersedes the one seen there in the last decade. A corresponding method development is the core objective of the present proposal, with particular emphasis on numerically efficient approaches that will ultimately allow to reach comprehensive microkinetic formulations. Synergistically combining the methodological expertise of the two participating groups we specifically aim to implement and advance implicit and mixed implicit/explicit solvation models, as well as QM/MM approaches to describe energy-related processes at solid-liquid interfaces. With the clear objective to develop general-purpose methodology we will illustrate their use with applications to hydrogen generation through water splitting. Disentangling the electro- resp. photocatalytic effect with respect to the corresponding dark reaction, this concerns both the hydrogen evolution reaction at metal electrodes like Pt and direct water splitting at oxide photocatalysts like TiO2. Through this we expect to arrive at a detailed mechanistic understanding that will culminate in the formulation of comprehensive microkinetic models of the light- or potential-driven redox process. Evaluating these models with kinetic Monte Carlo simulations will unambiguously identify the rate-determining and overpotential-creating steps and therewith provide the basis for a rational optimization of the overall process. As such our study will provide a key example of how systematic method development in computational approaches to basic energy sciences leads to breakthrough progress and serves both fundamental understanding and cutting-edge application.
Der Geodätischer Postprocessing Positionierungs-Service (GPPS) ist einer von drei Servicebereichen des Satellitenpositionierungsdienstes (SAPOS®) der deutschen Landesvermessung. Angemeldete Nutzer können die Korrektur- und Beobachtungsdaten von den hessischen SAPOS®-Referenzstationen erwerben oder eine Onlineberechnung von amtlichen ETRS89-Positionen aus Roverbeobachtungen durchführen lassen.
Der Satellitenpositionierungsdienst SAPOS stellt das amtliche Lagebezugssystem für die Bundesrepublik Deutschland (Koordinatenreferenzsystem ETRS89_UTM32 (Bezugssystem ETRS89 mit Abbildungsvorschrift UTM, EPSG-Code 25832, frühere Bezeichnung: Lagestatus 310)) bereit. Er besteht aus den drei Servicebereichen EPS, HEPS und GPPS. Weitere Informationen finden Sie unter www.SAPOS.GeoNord.de
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