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Trace element concentration of minerals in the Morro São João malignites (Serra do Mar, Brazil)

The Morro São João intrusion is located in the easternmost part of the Serra do Mar province, along the Cabo Frio lineament (Fig. 1) and has an area of approximately 10 km². It is a Late Cretaceous intrusion formed by clinopyroxenites, melagabbros, shonkinites, malignites, nepheline syenites, and phonolite dikes, without olivine, and is thought to have formed by closed system crystallization of a fairly evolved tephritic melt of potassic/ultrapotassic affinity (cf. Brotzu et al., 2007). We have analyzed two malignites, and specifically, their liquidus phases (clinopyroxene, titanite, garnet, amphibole). Analyzing the trace elements in these minerals helps us to better understand the different fractionation of the elements in these coexisting phases, and the implications for the evolution processes that occurred in the Morro São João magma reservoir. These analyses also provided important information about the concentration of rare earth elements (REEs) and high field strength elements (HFSEs), and their change with the magmatic evolution of the suite. This publication results from work conducted under the transnational access/national open access action at Mass spectrometry la-icp laboratory (IGG-CNR, Italy) supported by WP3 ILGE - MEET project, PNRR - EU Next Generation Europe program, MUR grant number D53C22001400005.

Trace element analysis of the main minerals in the Salitre lamprophyre (APIP, Brazil)

The Upper Cretaceous Salitre intrusion, subdivided into Salitre I and Salitre II and dated to ~86-82 Ma by Sonoki and Garda (1988), is part of the Alto Paranaíba Igneous Province (APIP, Fig. 1) in Brazil, which is one of the largest ultrapotassic / carbonatitic / kimberlitic provinces in the world. The intrusion is characterized by the presence of lamproites, carbonatites and one lamprophyre (analyzed here), as well as along with a variety of intrusive cumulitic rocks. Among the Salitre studied samples, this alkaline lamprophyre is characterized by low SiO2 (35.6 wt%), ultrapotassic (K2O/Na2O = 5; K2O = 4.4 wt%) and peralkaline (PI = 1.3). It exhibits variable MgO content (14 wt%) and is enriched in REEs (∑REE=~1,300 ppm) and other trace elements (Nb, Ta, Zr, Hf, Sr, Ba). This lamprophyre is characterized by olivine and phlogopite phenocrysts set in a fine-grained groundmass of clinopyroxene, apatite, phlogopite, magnetite, chromite, and perovskite, with rare titanite and garnet; kalsilite is absent. Analyzing the trace elements of the main minerals in this lamprophyre helped us learn more about the origin and evolution of these magmas, as well as their possible genetic link with the other Salitre rocks. This analysis also provided important information about their enrichment in rare earth elements (REEs) and high field strength elements (HFSEs). This publication results from work conducted under the transnational access/national open access action at Mass spectrometry la-icp laboratory (IGG-CNR, Italy) supported by WP3 ILGE - MEET project, PNRR - EU Next Generation Europe program, MUR grant number D53C22001400005.

Trace element data obtained from main minerals in Salitre clinopyroxenite and dunite rocks (APIP, Brazil)

The Salitre intrusion, which is subdivided into Salitre I and Salitre II. It was dated to ~86-82 Ma by Sonoki and Garda (1988). It is part of the Alto Paranaíba Igneous Province (APIP, Fig. 1) in Brazil. The APIP is one of the largest ultrapotassic/carbonatitic/kimberlitic provinces in the world. The intrusion consists of lamproites, carbonatites, and one lamprophyre, as well as various intrusive cumulitic rocks. These rocks include perovskite-phlogopite dunites, phlogopite-perovskite clinopyroxenites (salitrites, s.l.), phlogopitites, phoscorites, and perovskitites. These rocks are characterized by variable enrichment of olivine, clinopyroxene, phlogopite, perovskite, oxides, apatite, and carbonate, as well as several accessory phases, such as baddeleyite and calzirtite. Their geochemical and petrological features are related to the variable amounts of these minerals. For this part of the project, we have analyzed the concentrations of trace elements in the primary minerals (clinopyroxene, phlogopite, garnet, perovskite, apatite and olivine) identified in three phlogopite-perovskite clinopyroxenites and one perovskite-phlogopite dunite. Analyzing the trace elements in these minerals helped us to better understand the differential settling of minerals within the Salitre magma chamber, and their possible genetic relationship with carbonatitic and lamprophyric rocks. These analyses also provided important information about the minerals' enrichment in rare earth elements (REEs) and high field strength elements (HFSEs). This publication results from work conducted under the transnational access/national open access action at Mass spectrometry la-icp laboratory (IGG-CNR, Italy) supported by WP3 ILGE - MEET project, PNRR - EU Next Generation Europe program, MUR grant number D53C22001400005.

Mineral trace element analysis of xenocrysts and xenoliths hosted in the Limeira I kimberlite (APIP, Brazil)

The Limeira I kimberlite (91±6 Ma; Guarino et al., 2013) is part of the Alto Paranaíba Igneous Province (APIP) and was emplaced in the southern part of the São Francisco Craton in Brazil. This Kimberlite contains macrocrysts and phenocrysts of olivine, resorbed phlogopite/ tetraferriphlogopite, Al-free magnetite, chromite, magnesian ilmenite, rutile, perovskite, monticellite, apatite, serpentine and carbonate. It also contains a suite of xenocrysts and xenoliths (among which we recall wehrlite, phlogopite-ilmenite-websterite, olivine-ilmenite-glimmerite, clinopyroxenites bearing potassic-richterite, chromite-monticellite-kalsilite xenoliths, rutile with priderite or perovskite reaction rims, magnesian chromian ilmenite with perovskite rims). In this part of the project, we analyzed the xenocryst minerals and the main minerals found in the xenoliths entrapped in the Limeira I kimberlite. Analyzing the trace element concentrations in these minerals, helped us to better understand the processes that may occur in the subcontinental lithospheric mantle beneath the Alto Paranaíba Igneous Province. These analyses also provided important information about the minerals' enrichment in rare earth elements (REEs) and high field strength elements (HFSEs). This publication results from work conducted under the transnational access/national open access action at Mass spectrometry la-icp laboratory (IGG-CNR, Italy) supported by WP3 ILGE - MEET project, PNRR - EU Next Generation Europe program, MUR grant number D53C22001400005.

Noble Gas Isotopic Composition from Geothermal Springs of the North-Western Himalaya

This dataset contains noble gas (He, Ne, Ar) isotopic and elemental compositions of geothermal spring fluids collected across the North-Western Himalaya as part of the “Himalayan Geothermal Project: Investigating Geothermal Systems in the North Western Himalaya – Origin and Tectonic Influence”. The primary purpose of data collection was to determine the sources, mixing processes, and crust–mantle interactions governing geothermal fluid evolution in an active continental collision zone. Water samples were collected from major geothermal localities in Himachal Pradesh (India) using glass water. The entire analysis was carried out in the Laboratory of Noble Gas Isotopes at the INGV Section in Palermo following all standard procedures. The resultant dataset is provided as a single CSV file containing all processed noble gas concentrations, isotopic ratios and other realted data. This publication results from work conducted under the transnational access/national open access action at Laboratory of Noble Gas Isotopes at the INGV Section in Palermo (Italy) supported by WP3 ILGE - MEET project, PNRR - EU Next Generation Europe program, MUR grant number D53C22001400005.

Dataset of wehrlitization process: insights from X-ray Micro-CT of Mt. Vulture (southern Italy) mantle xenoliths

The study of textural and chemical characteristics of mafic minerals from mantle xenoliths is essential to investigate the nature of the upper mantle in a continental geodynamic context, melts generation and their effects related to mantle metasomatism. Particular textures in mantle minerals, inclusions or secondary veins of different nature (silicates vs carbonates), bubbles, represent petrographic tools to investigate these processes within the mantle. Petrographic 2D thin sections might overlook these mineralogical features, and 3D textural analysis through X-ray computed microtomography (micro-CT) are crucial to overcome these limitations. We focused on the Mt. Vulture volcano (southern Italy) rare mantle xenoliths, brought to the surface by a melilitite-carbonatite magma (141 ka), with particular emphasis to spinel-wehrlite xenoliths and wehrlitization processes that is located close to an area of intense CO2 degassing associated to catastrophic earthquakes. Preliminary results showed interesting 3D textural distributions within the studied xenoliths-forming mantle minerals. In particular, the micro-CT allowed to furnish new constrains on the relationship between fluids entrapment and migration, and structural discontinuities. Indeed, some minerals (especially those from the wehrlite xenoliths) showed a well-correlated distribution of fluid inclusions along the secondary fracturing planes. This publication results from work conducted under the transnational access/national open access action at Istituto Nazionale di Geofisica e Vulcanologia – Osservatorio Vesuviano (INGV-OV) and supported by WP3 ILGE - MEET project, PNRR - EU Next Generation Europe program, MUR grant number D53C22001400005. The author thanks also Gianmarco Buono and Lucia Pappalardo for their support during the analyses and the post processing process.

Carbon isotopes in OIB Mantle source

Other

Microstructure and mechanical properties of massive and porous of lavas from S. Miguel Island (Azores, Portugal)

The role of elongated pores and crystals of lavas influences their mechanical and physical behaviour, providing a first microstructural clue. In the context of a doctoral project, two samples – a trachyte and a basalt/andesite (s.l.) - representative of Fogo Volcano (S. Miguel Island, Azores, Portugal) were collected as part of an intact rock study. They were microstructurally assessed in the INGV-OV (Naples) using the ZEISS Xradia Versa 410 X-ray computed microtomography to obtain high-resolution 3D images, as well as to perform real-time in-situ mechanical tests (uniaxial – 7 mm diameter cylinders - and Brazilian – 13 mm diameter discs) to assess how elongated pores/crystals control strength. In addition to 3D images of the samples, which allow segmentation of the pore space and crystals, mechanical tests show that trachytes are more competent than vesicular basalts/andesites. Both pores and crystals control the development of the crack pattern.

CAMSIZER Particle Size Data from Explosive Paroxysms of Mt. Etna (2011–2025)

Mt. Etna in Catania, Italy, is an active volcano that has served as a natural laboratory for many volcanologists worldwide. Its paroxysms are unique eruptive events caused by a complex magmatic system that, despite being one of the most studied volcanoes, there is still an open field to contribute to the understanding of magma dynamics and degassing. This data set is a compilation of grain-size and shape measurements of 14 tephra samples of Mt. Etna. The tephra samples correspond to some of the most explosive cycles and events of the volcano from 2011 to 2025. The measurements were obtained using CAMSIZER through the ILGE TNA grant funding at INGV sezione di Catania. This dataset is the basis for a research project investigating the controls on the volume of gases and magma emitted during an eruption of Mt. Etna. This publication results from work conducted under the transnational access/national open access action at Sedimentology Laboratory – INGV sezione di Catania supported by WP3 ILGE - MEET project, PNRR - EU Next Generation Europe program, MUR grant number D53C22001400005.

Horizontal-to-Vertical Spectral Ratios (HVSR) of NW Italy seismic stations elaborated during the "FOCUS-HVNEA" NOA-ILGE project

This data set consists of Horizontal-to-Vertical Spectral Ratios (HVSR) resulting from the application of the software package HVNEA (HV Noise and Earthquake Automatic Analysis) with the aim of comparing them with those resulting from the application of another method, namely STATION (Seismic sTATion and sIte amplificatiON). The results, relative to more than 24,000 HVSR, derive from the processing of 700,000 seismograms recorded over different time periods by 8 stations of the networks IV (Italian Seismic Network), GU (Regional Seismic Network of North Western Italy) and GV (Mobile RSNI). To compare the results of the two methods as accurately as possible, the waveforms were subjected to the same preprocessing already used to elaborate the results stored in the STATION database. To this end, the methodological workflow applied with HVNEA for station IV.MURB involved the selection of segments from continuous recordings for each event reported in the INGV catalogue located within a radius of 120 kilometres from the station. Starting from the automatically picked S-wave onsets, 12-second windows were then extracted and used for the analysis of earthquake recordings. Regarding the noise analysis, it should be noted that STATION again considers 12-second windows selected before the P-wave onset, while HVNEA requires the use of a signal window of at least 60 seconds. A window of 3,600 seconds was used for the analysis. The comparison of the HVSR was performed in the frequency band 0.1–15 Hz. All analysed curves, for both earthquake and noise recordings, show generally similar shapes and identify significant peaks in correspondence of the same frequency ranges, although the amplitudes obtained with STATION are systematically higher than those obtained with HVNEA. To obtain a quantitative comparison, various statistical metrics commonly used to measure the discrepancy between data sets were applied, namely the Mean Squared Error, the Mean Absolute Error and the Pearson Correlation Coefficient. This publication results from work conducted under the transnational access/national open access action at the Site effects Laboratory – INGV L’Aquila supported by WP3 ILGE–MEET project, PNRR–EU Next Generation Europe program, MUR grant number D53C22001400005.

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