In freshwater sediments, iron oxidation is dominated by phototrophic and chemotrophic (aerobic and nitrate-reducing) Fe(ll)-oxidizing microorganisms. Although these biogeochemical processes have been investigated in detail in laboratory studies, not much is known about their spatial distribution, interactions (e.g. competition) amongst each other, as well as their response towards environmental perturbations (i.e. temperature, geochemical variations (nutrient, organic matter input)). This research proposal aims to investigate the activity, abundance and resource competition between different chemotrophic (aerobic and (autotrophic/mixotrophic) anaerobic nitrate-reducing) and phototrophic ironoxidizing microorganisms. In order to better understand the spatial distribution of nitrate-reducing iron oxidizing bacteria, microbial nitrate-producing and competing, nitrate-depletion processes will also be studied throughout the sedimentary redox gradient. In addition, the activity and abundance of the ironoxidizing processes will be quantified with (geo)microbiological, molecular and novel spectral imaging techniques. Using high resolution geochemical measurements (microsensors) we will characterize the environmental conditions these bacteria experience in order to determine the role of spatial and functional niche competition in microbial iron oxidation and the interconnection to the N-cycle. Iron mineral formation will be investigated as a function of the microbial spatial and temporal activity, depending on environmental perturbations. The proposed research study will strongly improve the understanding of iron cycling, the interconnection to the N-cycle, as well as interactions and competition between phototrophic and chemotrophic metabolisms in aquatic environments.
Das Projekt ÖkoKauf der Stadt Wien hat es sich zum Ziel gesetzt, durch die Erstellung von ökologischen Kriterien, Pilotprojekte und durch Bewusstseinsarbeit das Beschaffungswesen im Magistrat Wien weiter zu ökologisieren. In diesem Rahmen widmete sich der Arbeitskreis 'Desinfektionsmittel unter der Leitung der Wiener Umweltanwaltschaft (WUA) der Aufgabe, für Hygienefachleute ein Instrument zur Beurteilung der Auswirkungen von Desinfektionsmitteln auf Gesundheit und Umwelt zu erstellen. Das Österreichische Ökologie-Institut führte eine Daten- und Literaturrecherche durch, das Umweltbundesamt nahm ergän-zende ökotoxikologische Tests an Wirkstoffen und -produkten vor und 'die umweltberatung ermittelte stationsbezogene Desinfektionsmittelverbräuche in Wiener Krankenanstalten. Die Recherche- und Testergebnisse zu Desinfektionsmittelwirkstoffen und -produkten wurden in einer vom IFZ konzipierten und von der Magistratsabteilung 14 realisierten Datenbank zusammengefasst. Um die ökotoxikologischen Produkteigenschaften vergleichbar zu machen, wurde vom IFZ ein Bewertungsraster entwickelt und in die Datenbank integriert. Dabei werden nachteilige Wirkungen auf die Gesundheit anhand von vier Wirkungskategorien erfasst: Akute Giftigkeit; Reizwirkung auf die Haut; Sensibilisierung, allergenes Potenzial sowie Erbgutschädigende, krebserzeugende und fruchtschädigende Eigenschaften. Zusammen mit der Berücksichtigung des Verhaltens in Oberflächengewässern (Abbauverhalten, Bioakkumulationspotenzial, Toxizität für Wasserorganismen) sowie dem Verhalten in Kläranlagen werden insgesamt sechs Bewertungszahlen generiert, die auf einer Skala von 1 (vernachlässigbar) bis 5 (sehr hoch) das gesamte Gefährdungsprofil des Stoffes beschreiben sollen. Das Gefährdungsprofil eines Handelsproduktes errechnet sich aus den Gefährdungsprofilen der darin enthaltenen Wirkstoffe anhand eines Algorithmus: Dabei wird die Annahme getroffen, dass die Produkteigenschaften von der Konzentration der darin enthaltenen Wirkstoffe abhängen. Bei der Bewertung ist außerdem zu gewährleisten, dass ein Wirkstoff mit einem hohen Gefährdungspotenzial angemessen berücksichtigt wird, auch und gerade wenn seine Konzentration im Produkt gering ist. In der Literatur wird dazu eine logarithmische Skalierung vorgeschlagen. Die Bewertung berücksichtigt derzeit die Wirkstoffe sowie Anwendungsverdünnungen. Die Zusammenfassung der Produkte in Verwendungs- bzw. Expositionskategorien ermöglicht letztlich eine vergleichende Bewertung. Da das Bewertungsraster gerade auf eine vergleichende Bewertung von Produkten abzielt, unterliegt er einer ständigen kritischen Diskussion, die auch häufig von den Herstellern geführt wird. Dieser Umstand sowie das Faktum von Produktlebenszyklen erfordern ein ständiges Update der in der Datenbank enthaltenen Informationen und eine Anpassung des Bewertungsmodells an den aktuellen Stand von Forschung sowie Standards der Stoff- und Produktpolitik.
Seit Juni 2014 ist der aktuelle Erlass zur 'Energetischen Vorbildfunktion von Bundesbauten' in Kraft. Darin werden Vorgaben für den Bundesbau zur Unterschreitung der Anforderungen aus der Energieeinsparverordnung 2013 gemacht. Mit Inkrafttreten der novellierten EnEV-Anforderungen am 1. Januar 2016 erhöhen sich die Anforderungen für neu zu errichtende Nichtwohngebäude. Will der Bund weiterhin seine Vorbildfunktion wahrnehmen, muss der EnEV-Erlass sinnvoll fortgeschrieben werden. Im Forschungsprojekt sollen dazu die Grundlagen erarbeitet werden. Ausgangslage: Seit Juni 2014 ist der aktuelle Erlass zur 'Energetischen Vorbildfunktion von Bundesbauten' (BI3-8133.2/3) in Kraft. Darin werden Vorgaben für den Bundesbau zur Unterschreitung der Anforderungen aus der Energieeinsparverordnung 2013 (EnEV 2013) gemacht. Mit dem Inkrafttreten der novellierten EnEV-Anforderungen am 1. Januar 2016 erhöhen sich die Anforderungen für neu zu errichtende Nichtwohngebäude. Will der Bund weiterhin seine Vorbildfunktion wahrnehmen, muss der EnEV-Erlass sinnvoll fortgeschrieben werden. Ziel: Bei der Fortschreibung des EnEV-Erlasses sind Anforderungen an die energetische Qualität von neu zu errichtenden Bundesbauten zu formulieren, die über die Anforderungen der EnEV 2016 hinausgehen. Auch im Zusammenhang mit der Anpassung und Weiterentwicklung des Bewertungssystems Nachhaltiges Bauen (BNB) ergeben sich Erfordernisse. Es muss auch hier überprüft werden, welche energetischen Ziele einerseits formuliert und andererseits mit angemessenem Aufwand realisiert werden können. Im Forschungsprojekt sollen dazu die Grundlagen erarbeitet werden, indem Wirtschaftlichkeitsuntersuchungen an geeigneten Referenzgebäuden durchgeführt werden.
Previous studies indicated that the development and biogeochemistry of paddy soils relates to the parent material, thus the original soil paddies derive from. The proposed research focuses on redox-mediated changes in mineral composition and mineral-associated organic matter (OM) during paddy transformation of different soils. We plan to subject soil samples to a series of redox cycles, in order to mimic paddy soil formation and development. Soils with strongly different properties and mineral composition as well as at different states of paddy transformation; ranging from unchanged soils to fully developed paddy soils, are to be included. We hypothesize that dissolved organic matter is one key driver in redox-mediated transformations, serving as an electron donator as well as interacting with dissolved metals and minerals. The extent of effects shall depend on the parent soil's original mineral assemblage and organic matter and their mutual interactions. The experimental paddy soil transformation will tracked by analyses of soil solutions, of the (re-)distribution of carbon (by addition of 13C-labelled rice straw), of indicative biomolecules (sugars, amino sugars, fatty acids, lignin) and of minerals (including the redox state of Fe). For analyses of organic matter as well as of mineral characteristics we plan to utilize EXAFS and XPS, for Fe-bearing minerals also Mößbauer spectroscopy. This approach of experimental pedology seems appropriate to give insight into the major factors during paddy soil formation and development.
The geomagnetic field shields our habitat against solar wind and radiation from space. Due to the geometry of the field, the shielding in general is weakest at high latitudes. It is also anomalously weak in a region around the south Atlantic known as South Atlantic Anomaly (SAA), and the global dipole moment has been decreasing by nearly 10 percent since direct measurements of field intensity became possible in 1832. Due to our limited understanding of the geodynamo processes in Earths core, it is impossible to reliably predict the future evolution of both dipole moment and SAA over the coming decades. However, lack of magnetic field shielding as would be a consequence of further weakening of dipole moment and SAA region field intensity would cause increasing problems for modern technology, in particular satellites, which are vulnerable to radiation damage. A better understanding of the underlying processes is required to estimate the future development of magnetic field characteristics. The study of the past evolution of such characteristics based on historical, archeo- and paleomagnetic data, on time-scales of centuries to millennia, is essential to detect any recurrences and periodicities and provide new insights in dynamo processes in comparison to or in combination with numerical dynamo simulations. We propose to develop two new global spherical harmonic geomagnetic field models, spanning 1 and 10 kyrs, respectively, and designed in particular to study how long the uninterrupted decay of the dipole moment has been going on prior to 1832, and if the SAA is a recurring structure of the field.We will combine for the first time all available historical and archeomagnetic data, both directions and intensities, in a spherical harmonic model spanning the past 1000 years. Existing modelling methods will be adapted accordingly, and existing data bases will be complemented with newly published data. We will further acquire some new archeomagnetic data from the Cape Verde islands from historical times to better constrain the early evolution of the present-day SAA. In order to study the long-term field evolution and possible recurrences of similar weak field structures in this region, we will produce new paleomagnetic records from available marine sediment cores off the coasts of West Africa, Brazil and Chile. This region is weakly constrained in previous millennial scale models. Apart from our main aim to gain better insights into the previous evolution of dipole moment and SAA, the models will be used to study relations between dipole and non-dipole field contributions, hemispheric symmetries and large-scale flux patterns at the core-mantle boundary. These observational findings will provide new insights into geodynamo processes when compared with numerical dynamo simulation results.Moreover, the models can be used to estimate past geomagnetic shielding above Earths surface against solar wind and for nuclide production from galactic cosmic rays.
Rain-cracking limits the production of many soft and fleshy fruit including sweet cherries world wide. Cracking is thought to result from increased water uptake through surface and pedicel. Water uptake increases fruit volume, and hence, turgor of cells (Pcell) and the pressure inside the fruit (Pfruit) and subjects the skin to tangential stress and hence, strain. When the strain exceeds the limits of extensibility the fruit cracks. This hypothesis is referred to as the Pfruit driven strain cracking. Based on this hypothesis cracking is related to two independent groups of factors: (1) water transport characteristics and (2) the intrinsic cracking susceptibility of the fruit defined as the amount of cracking per unit water uptake. The intrinsic cracking susceptibility thus reflects the mechanical constitution of the fruit. Most studies focussed on water transport through the fruit surface (factors 1), but only little information is available on the mechanical constitution (i.e., Pfruit and Pcell, tensile properties such as fracture strain, fracture pressure and modulus of elasticity of the exocarp; factors 2). The few published estimates of Pfruit in sweet cherry are all obtained indirectly (calculated from fruit water potential and osmotic potentials of juice extracts) and unrealistically high. They exceed those measured by pressure probe techniques in mature grape berry by several orders of magnitude. The objective of the proposed project is to test the hypothesis of the Pfruit driven strain cracking. Initially we will focus on establishing systems of widely differing intrinsic cracking susceptibility by varying species (sweet and sour cherry, Ribes and Vaccinium berries, plum, tomato), genotype (within sweet cherry), stage of development and temperature. These systems will then be used for testing the hypothesis of Pfruit driven strain cracking. We will quantify Pfruit und Pcell by pressure probe techniques and compression tests and the mechanical properties of the exocarp using biaxial tensile tests. When the presence of high Pfruit and Pcell is confirmed by direct measurements, subsequent studies will focus on the mode of failure of the exocarp (fracture along vs. across cell walls) and the relationship between failure thresholds and morphometric characteristics of the exocarp. However, when Pfruit und Pcell are low, the hypothesis of Pfruit driven strain cracking must be rejected and the mechanistic basis for low pressures (presence of apoplastic solutes) clarified on a temporal (in the course of development) and a spatial scale (exocarp vs. mesocarp). We focus on sweet cherry, because detailed information on this species and experience in extending the short harvest period is available. Where appropriate, other cracking susceptible species (sour cherry, plum, Vaccinium, Ribes, tomato) will be included to further extend the experimental period and to maximize the range in intrinsic cracking susceptibility.
Whether primordial bodies in the solar system possessed internally-generated dynamos is a fundamental constraint to understand the dynamics and timing of early planetary formation. Paleointensity studies on several meteorites reveal that their host planets possessed magnetic fields within an order-of magnitude of the present Earths field. Interpretation of paleointensity data relies heavily on fundamental knowledge of the magnetic properties of the magnetic carriers, such as the single to multidomain size threshold or how the saturation magnetization varies as a function of grain size, yet very little knowledge exists about these key parameters for some of the main magnetic recorders in meteorites: the iron-nickel alloys. Moreover, most meteorites have experienced some amount of shock during their histories, yet the consequence of even very small stresses on paleointensity data is poorly known.We wish to fill these gaps by magnetically characterizing Fe-Ni alloys as a function of grain size and by determining how absolute and relative paleointensity data are biased by strain levels lower than those petrologically observable (less than 4-5 GPa). For example, our preliminary work shows that an imposed stress of 0.6 GPa will reduce absolute paleointensity estimates by 46Prozent for single domain magnetite-bearing rocks. In general, paleointensity determinations possess inherent disadvantages regarding measurement precision and the inordinate amount of human time investment. We intend to overcome these limitations by extending and improving our fully automated magnetic workstation known as the SushiBar.
Irrigation in the Yanqi Basin, Sinkiang, China has led to water table rise and soil salination. A model is used to assess management options. These include more irrigation with groundwater, water saving irrigation techniques and others. The model relies on input data from remote sensing.The Yanqi Basin is located in the north-western Chinese province of Xinjiang.This agriculturally highly productive region is heavily irrigated with water drawn from the Kaidu River. The Kaidu River itself is mainly fed by snow and glacier melt from the Tian Mountain surrounding the basin. A very poor drainage system and an overexploitation of surface water have lead to a series of environmental problems: 1. Seepage water under irrigated fields has raised the groundwater table during the last years, causing strongly increased groundwater evaporation. The salt dissolved in the groundwater accumulates at the soil surface as the groundwater evaporates. This soil salinization leads to degradation of vegetation as well as to a loss of arable farmland. 2. The runoff from the Bostan Lake to the downstream Corridor is limited since large amount of water is used for irrigation in the Yanqi Basin. Nowadays, the runoff is maintained by pumping water from the lake to the river. The environmental and ecological system is facing a serious threat.In order to improve the situation in the Yanqi Basin, a jointly funded cooperation has been set up by the Institute of Environmental Engineering, Swiss Federal Institute of Technology (ETH) , China Institute of Geological and Environmental Monitoring (CIGEM) and Xinjiang Agricultural University. The situation could in principle be improved by using groundwater for irrigation, thus lowering the groundwater table and saving unproductive evaporation. However, this is associated with higher cost as groundwater has to be pumped. The major decision variable to steer the system into a desirable state is thus the ratio of irrigation water pumped from the aquifer and irrigation water drawn from the river. The basis to evaluate the ideal ratio between river and groundwater - applied to irrigation - will be a groundwater model combined with models describing the processes of the unsaturated zone. The project will focus on the following aspects of research: (...)
Zukünftige Explorationen für metallische Ressourcen werden auf größere Tiefen und untermeerische Bereiche abzielen, was kostspielig und technisch herausfordernd ist. Für diese Entwicklung benötigen wir belastbare Vorhersagemodelle, welche die entscheidenden Prozesse innerhalb ganzer lagerstättenbildender Systeme abbilden können. Magmatisch-hydrothermale Lagerstätten bilden unsere größten Ressourcen für Cu, Mo, Sn und W und entstehen durch Fluidentmischung aus magmatischen Intrusionen in ein Hydrothermalsystem im Umgebungsgestein. Das Potential, riesige ('world-class') Lagerstätten bilden zu können, hängt wesentlich von Fluidflüssen über diese magmatisch-hydrothermale Grenzschicht hinweg ab, welche jedoch die größte Unbekannte in unserem derzeitigen Verständnis dieser Lagerstätten darstellten und bislang in numerischen Simulationen lediglich parameterisiert werden können. Um diese Grenzprozesse abbilden zu können, benötigt es einen fundamental neuen Modellieransatz mit einem Kontinuum, das über die Tiefenbereiche von Hydrothermalsystemen hinaus reicht und die Lücke zwischen Fluidfluss und Magmadynamik überbrückt. Das Projekt CROWN wird neue Wege beschreiten, indem es eine konsistente Formulierung für Fluidgenese und -transport in einem gekoppelten Modell für viskoses Fliessen gemäß der Navier-Stokes-Gleichungen und poröses Fliessen nach dem Darcy Gesetz entwickelt. Außerdem, und sehr wichtig für die geologische Realitätsnähe, simuliert das Modell dynamische Permeabitätsänderungen und fokussiertes Fliessen entlang von Störungsbahnen. Die Simulationen richten sich an konzeptuellen Modellen aus der Literatur aus - darunter auch neue eigene Arbeit. Der Projektantrag hebt auch angedachte direkte Zusammenarbeiten mit anderen Projekten, die sich mit magmatisch-hydrothermalen Lagerstätten beschäftigen und für das DOME SPP beantragt wurden, hervor. Das Thema hat auch Verbindungen zu anderen SPP-Anträgen, welche sich mit Laborexperimenten beschäftigen, was noch weitere Möglichkeiten zur Zusammenarbeit eröffnet.
The agricultural sector has experienced substantial structural changes in the past and faces continuing adjustments in the future. The implications of structural change are not only relevant for the sector itself but have broader social, economic and environmental consequences for a region. An understanding of this process is required in order to assess how (agricultural-) policy affects or, if a specific social outcome is desired, can influence this development. A common approach to gain understanding of the process is to model structural change as a Markov process. One problem in the analysis of structural change in the EU is that farm level (micro) data is rarely available such that inference about behaviour of individual farms has to be derived from aggregated (macro) data. Recently, the generalized cross entropy estimator gained popularity in this context since it allows considering prior information such that the often underdetermined 'macro data' Markov models can be estimated. However, the way prior information is considered is also the greatest drawback of the approach. Therefore, the project aims to develop a Bayesian framework as an alternative estimator that allows to consider prior information in a more efficient and transparent way. The project will further provide an evaluation of the statistical properties of the estimator as well as an exemplifying application analyzing the effects of single farm payments on agricultural structural change in the EU.
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