In forest ecosystems ectomycorrhizal fungi are responsible for the mobilization of mineral nutrients from soil organic matter (SOM) resulting in a marked increase in productivity of their symbiotic host plants. In return the fungi obtain a significant amount of photosynthetic products from these plants, allowing the formation of an extensive hyphal system. These hyphae constitute a major part of soil biomass and, ultimately, a major source for SOM formation. While plant-fungal nutrient exchange has been analyzed extensively, this proposal is focused on the fungal contribution to SOM formation and on the processes leading to the acquisition of nutrients by the fungi. These two processes will be studied separately and in a quantitative way using isotopic labeling in soil bioreactors. Analysis of the fate of 13C labeled fungal material (Laccaria bicolor) in soil bioreactors will tell how fast and to what extent the various fractions of hyphal biomass are transformed into non-living SOM. As potential molecular or structural markers for SOM formation from fungal hyphae we will analyze characteristic remnants of fungal hyphae in SOM using scanning electron microscopy, DNAfragments using a PCR approach for the fungal rRNA internal transcribed spacerregions and biochemical markers like fatty acids and ergosterol. The impact of ectomycorrhizal mycelia supported by Pinus sylvestris plantlets on 13C- and 15N-labeled SOM and on microbial biomass will be analyzed in separate soil bioreactor experiments.
The sorption of anions in geotechnical multibarrier systems of planned high level waste repositories (HLWR) and of non-ionic and organic pollutants in conventional waste disposals are in the center of recent research. In aquatic systems, persistent radionuclides such as 79Se, 99Tc, 129I exist in a form of anions. There is strongly increasing need to find materials with high sorption capacities for such pollutants. Specific requirements on barrier materials are long-term stability of adsorbent under various conditions such as T > 100 C, varying hydrostatic pressure, and the presence of competing ions. Organo-clays are capable to sorb high amounts of cations, anions and non-polar molecules simultaneously having selectivity for certain ions. This project is proposed to improve the understanding of sorption and desorption processes in organo-clays. Additionally, the modification of material properties under varying chemical and thermal conditions will be determined by performing diffusion and advection experiments. Changes by sorption and diffusion will be analyzed by determining surface charge and contact angles. Molecular simulations on models of organo-clays will be conducted in an accord with experiments with aim to understand and analyze experimental results. The computational part of the project will profit from the collaboration of German partner with the group in Vienna, which has a long standing experience in a modeling of clay minerals.
During the first project period we developed a general approach to quantify soil pore structure based on X-ray micro-tomography Vogel et al. (2010) which is applicable at various scales to cover soil pores larger that 0.05 mm in a representative way. Based on this method we generated equivalent network models to numerically simulate flow and transport of dissolved chemicals. The existing network model was extended to handle reactive transport and infiltration processes which are especially critical for matter flux in soil. The results were compared to experimental findings. The original research question 'what does a particle see on its way through soil' could be answered quantitatively for various boundary conditions including steady state flux and infiltration. However, we identified various critical aspects of the proposed modeling concept which will be in the focus of the second period. This includes 1) the spatial arrangement of interfaces having different quality which is crucial for chemical interactions and pore scale water dynamics, 2) the realistic multiphase dynamics at the pore scale which need to reflect the dynamic pressure and movement of trapped non-wetting phase and 3) the parametrization of structural complexity which need to be developed beyond the measurement of continuous Minkowski functions to allow the development of quantitative relations between structure and function. These aspects will be explored in a joint experiments in cooperation with partners within the SPP.
Chromium (Cr) is introduced into the environment by several anthropogenic activities. A striking ex-ample is the area around Kanpur in the Indian state of Uttar Pradesh, where large amounts of Cr-containing wastes have been recently illegally deposited. Hexavalent Cr, a highly toxic and mobile contaminant, is present in significant amounts in these wastes, severely affecting the quality of sur-roundings soils, sediments, and ground waters. The first major goal of this study is to clarify the solid phase speciation of Cr in these wastes and to examine its leaching behavior. X-ray diffraction and synchrotron-based X-ray absorption spectroscopy techniques will be employed for quantitative solid phase speciation of Cr. Its leaching behavior will be studied in column experiments performed at un-saturated moisture conditions with flow interruptions simulating monsoon rain events. Combined with geochemical modeling, the results will allow the evaluation of the leaching potential and release kinetics of Cr from the waste materials. The second major goal is to investigate the spatial distribution, speciation, and solubility of Cr in the rooting zone of chromate-contaminated soils surrounding the landfills, and to study the suitability of biochar as novel soil amendment for mitigating the deleterious effects of chromate pollution. Detailed field samplings and laboratory soil incubation studies will be carried out with two agricultural soils and biochar from the Kanpur region.
Soil microorganisms can mobilize and immobilize phosphorus (P), and therefore strongly affect the availability of P to plants. In this project we hypothesize that the ratio of labile P to microbial P increases during the transition from acquiring to recycling ecosystems. Microbial and plant P uptake will be studied with 33P that will be quantified in microbial and plant biomass as well as in lipids. To what extent microorganisms immobilize and mobilize P during decomposition of soil organic matter will be explored with a 14C/33P labeled monoester. Seasonal dynamics of actual and potential P mineralization (33P dilution and phosphatase activity), and microbial P immobilization will be studied with soils of the transition from acquiring to recycling ecosystems. The contribution of litter-derived P will be explored in a litter exclusion experiment in the field. Spatial patterns of microbial and plant P mineralization in the rhizosphere will be explored by analyses of areas of high acid and alkaline (=microbial-derived) phosphatase activity by soil zymography, and their relations with areas of high rhizodeposition (14C imaging). In conclusion, we will analyse mechanisms of actual and potential microbial P mineralization and immobilization, localization, and consequences for P uptake by plants.
Die Nukleation von Eispartikeln spielt eine wichtige Rolle bei der Wolken- und Niederschlagsbildung, mit Konsequenten für die atmosphärische Chemie, die Wolkenphysik und das Erdklima. Für eine Quantifizierung und Vorhersage des Einflusses von Wolken in Wettervorhersage- und Klimamodellen muss die Bildung von Eispartikeln daher in einer realistischen Art und Weise beschrieben werden. Einer der wichtigen Bildungsmechanismen ist dabei die heterogene Eisnukleation im Immersionsmodus, bei dem Eis an der Oberfläche eines in einem wässrigen Tröpfchen suspendierten Eiskeims - zum Beispiel eines Mineralstaub- Partikels - gebildet wird. Wir werden im Rahmen dieses Forschungsprojekts zahlreiche Gefrierexperimente im Immersionsmodus durchführen. So werden eine Reihe verschiedener, als Aerosolpartikel in der Atmosphäre vorkommende Materialien auf ihre Eisnukleationseigenschaften hin untersucht werden. Insbesondere sollen hier die Temperatur- und Zeitabhängigkeit der von diesen Materialien ausgelösten Eisnukleation quantifiziert werden. Dabei werden wir spezielles Augenmerk auf die systematische Untersuchung der von porösen Materialien ausgelösten Eisnukleation legen. Es sollen sowohl synthetische Materialien wie beispielsweise mesoporöse Silikate untersucht werden, als auch natürlich vorkommende Materialien wie etwa mikroporöse Zeolithe.
In subsoils, organic matter (SOM) concentrations and microbial densities are much lower than in topsoils and most likely highly heterogeneously distributed. We therefore hypothesize, that the spatial separation between consumers (microorganisms) and their substrates (SOM) is an important limiting factor for carbon turnover in subsoils. Further, we expect microbial activity to occur mainly in few hot spots, such as the rhizosphere or flow paths where fresh substrate inputs are rapidly mineralized. In a first step, the spatial distribution of enzyme and microbial activities in top- and subsoils will be determined in order to identify hot spots and relate this to apparent 14C age, SOM composition, microbial community composition and soil properties, as determined by the other projects within the research unit. In a further step it will be determined, if microbial activity and SOM turnover is limited by substrate availability in spatially distinct soil microsites. By relating this data to root distribution and preferential flow paths we will contribute to the understanding of stabilizing and destabilizing processes of subsoil organic matter. As it is unclear, at which spatial scale these differentiating processes are effective, the analysis of spatial variability will cover the dm to the mm scale. As spatial segregation between consumers and substrates will depend on the pore and aggregate architecture of the soil, the role of the physical integrity of these structures on SOM turnover will also be investigated in laboratory experiments.
Soil organic matter (SOM) controls large part of the processes occurring at biogeochemical interfaces in soil and may contribute to sequestration of organic chemicals. Our central hypothesis is that sequestration of organic chemicals is driven by physicochemical SOM matrix aging. The underlying processes are the formation and disruption of intermolecular bridges of water molecules (WAMB) and of multivalent cations (CAB) between individual SOM segments or between SOM and minerals in close interaction with hydration and dehydration mechanisms. Understanding the role of these mediated interactions will shed new light on the processes controlling functioning and dynamics of biogeochemical interfaces (BGI). We will assess mobility of SOM structural elements and sorbed organic chemicals via advanced solid state NMR techniques and desorption kinetics and combine these with 1H-NMR-Relaxometry and advanced methods of thermal analysis including DSC, TGADSC- MS and AFM-nanothermal analysis. Via controlled heating/cooling cycles, moistening/drying cycles and targeted modification of SOM, reconstruction of our model hypotheses by computational chemistry (collaboration Gerzabek) and participation at two larger joint experiments within the SPP, we will establish the relation between SOM sequestration potential, SOM structural characteristics, hydration-dehydration mechanisms, biological activity and biogechemical functioning. This will link processes operative on the molecular scale to phenomena on higher scales.
Due to the often practised uncontrolled disposal into the environment, olive oil production wastewater (OPWW) is presently a serious environmental problem in Palestine and Israel. The objectives of this interdisciplinary trilateral research project are (i) to understand the mechanisms of influence of the olive oil production wastewater on soil wettability, water storage, interaction with organic agrochemicals and pollutants; (ii) monitor short-term and long-term effects of OPWW land application in model laboratory and field experiments; (iii) identify the components responsible for unwanted changes in soil properties and (iv) analyse the mechanisms of association of OPWW OM with soil, the interplay between climatic conditions, pH, presence of multivalent cations and the resulting effects of land application. Laboratory incubation experiments, field experiments and new experiments to study heat-induced water repellency will be conducted to identify responsible OPWW compounds and mechanisms of interaction. Samples from field experiments and laboratory experiments are investigated using 3D excitation-emission fluorescence spectroscopy, thermogravimetry-differential thermal analysis-mass spectrometry (TGA-DSC-MS), LC-MS and GC-MS analyses. We will combine thermal decomposition profiles from OPWW and OPWW-treated soils in dependence of the incubation status using TGA-DSC-MS, contact angle measurements, sorption isotherms and the newly developed time dependent sessile drop method (TISED). The resulting process understanding will open a perspective for OPWW wastewater reuse in small-scale and family-scale olive oil production busi-nesses in the Mediterranean area and will further help to comprehend the until now not fully un-ravelled effects of wastewater irrigation on soil water repellency.
We are currently facing the urgent need to improve our understanding of carbon cycling in subsoils, because the organic carbon pool below 30 cm depth is considerably larger than that in the topsoil and a substantial part of the subsoil C pool appears to be much less recalcitrant than expected over the last decades. Therefore, small changes in environmental conditions could change not only carbon cycling in topsoils, but also in subsoils. While organic matter stabilization mechanisms and factors controlling its turnover are well understood in topsoils, the underlying mechanisms are not valid in subsoils due to depth dependent differences regarding (1) amounts and composition of C-pools and C-inputs, (2) aeration, moisture and temperature regimes, (3) relevance of specific soil organic carbon (SOC) stabilisation mechanisms and (4) spatial heterogeneity of physico-chemical and biological parameters. Due to very low C concentrations and high spatio-temporal variability of properties and processes, the investigation of subsoil phenomena and processes poses major methodological, instrumental and analytical challenges. This project will face these challenges with a transdisciplinary team of soil scientists applying innovative approaches and considering the magnitude, chemical and isotopic composition and 14C-content of all relevant C-flux components and C-fractions. Taking also the spatial and temporal variability into account, will allow us to understand the four-dimensional changes of C-cycling in this environment. The nine closely interlinked subprojects coordinated by the central project will combine field C-flux measurements with detailed analyses of subsoil properties and in-situ experiments at a central field site on a sandy soil near Hannover. The field measurements are supplemented by laboratory studies for the determination of factors controlling C stabilization and C turnover. Ultimately, the results generated by the subprojects and the data synthesized in the coordinating project will greatly enhance our knowledge and conceptual understanding of the processes and controlling factors of subsoil carbon turnover as a prerequisite for numerical modelling of C-dynamics in subsoils.
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