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Entwicklung neuer zeolithischer Redoxkatalysatoren für die selektive Reduktion von NO durch Ammoniak durch Aufklärung der Beziehungen zwischen Katalysatorstruktur und katalytischen Eigenschaften

Ziel des Vorhabens ist die Entwicklung hochaktiver, selektiver und stabiler zeolithischer Redoxkatalysatoren für die selektive Reduktion von Stickstoffoxiden mit Ammoniak. Zu diesem Zweck werden durch Kombination katalytischer Untersuchungen mit Studien zur physikochemischen Charakterisierung von Aktivkomponente und Matrix (Methoden: EPR, ferromagnetische Resonanz (FMR), Mößbauerspektroskopie, EXAFX, XPS, ISS, UV-Vis, IR, Raman, XRD) gesicherte Erkenntnisse über die erforderliche Struktur der Redoxkomponente und der zeolithischen Matrix erarbeitet, die in verbesserte Präparationsstrategien für eine neue Katalysatorgeneration umgesetzt werden. Bezüglich der Strukturierung der Übergangsmetallkomponente ist durch Kombination katalytischer mit spektroskopischen Techniken zwischen der Wirkung isolierter Ionen auf Kationenplätzen sowie intra- bzw. extra-zeolithischer Oxidaggregate zu differenzieren, wobei dem Beweis der katalytischen Relevanz von Spezies über spektroskopische in situ-Studien (EPR, UV-Vis, Raman, EXAFS) besondere Bedeutung zukommt (1.-3. Jahr).

INSPIRE RP Hydro - Physische Gewässer ALKIS

Wasserkörper aus ALKIS RP

INSPIRE RP Hydro - Netzwerk ATKIS-BasisDLM

Hydrografisches Netzwerk aus ATKIS-BasisDLM RP

INSPIRE RP Hydro - Physische Gewässer ATKIS-BasisDLM

Geografische Wasserkörper aus ATKIS-BasisDLM RP

Marine Seismic Survey Profiles (MSSP)

During the period from 1974 to 2023 various cruises from BGR acquired seismic lines worldwide. The aim of these marine expeditions were a detailed survey of the geological structure of seabed.

Marine Seismic Survey Profiles (MSSP) (WMS)

During the period from 1974 to 2018 various cruises from BGR acquired seismic lines worldwide. The aim of these marine expeditions was a detailed survey of the geological structure.

Processed seismic data of Cruise Nares 2001

The Scientific staff and crew onboard CCGS Louis S. St. Laurent (LSL) returned September the 10th, 2001 from a scientific expedition to the Nares Strait, the northernmost waterway connecting the Arctic and Atlantic oceans. The data format is Society of Exploration Geophysicists SEG Y. The ice conditions in the strait required the support of Canada's largest ice breaker. The ship was a versatile platform for 34 scientists to accomplish their marine investigation. The LSL has a history of supporting international scientific expeditions including an oceanographic transect of the Arctic Ocean in 1994 and a biological study of the Canadian Arctic Islands in 1999. Germany (Bundesanstalt für Geowissenschaften und Rohstoffe, BGR) and Canada (Geological Survey of Canada) undertook a 5-week scientific cruise to study and explore the geological structure and evolution of the Nares Strait. The primary objective was the study of structural features relating to the formation of the Arctic Ocean and, in particular, the study of the Wegener Fault. This fault is a linear boundary between Greenland and Ellesmere Island which was noted by the German scientist Alfred Wegener in 1915 and later became the subject of a major scientific controversy. The co-operative cruise, which was planned over a period of 2 years, provided the basis for a wide range of scientific investigations, from marine seismic work and climate change studies through airborne magnetic investigations to geodetic survey measurements and geological sampling onshore. Systematic geophysical offshore studies in this key area had not been undertaken before. Where towing of seismic equipment was not possible because of ice coverage, magnetic maps were made using a helicopter-borne magnetic sensor system. Sediment and water samples taken during the cruise provide information on changes in climate and sea ice cover from the last ice-age to the present. An 11 m-long sediment core from outer Jones Sound is the longest core ever taken in the Canadian Arctic channels and holds clues to the detailed climate history of northern Baffin Bay.

Processed seismic data of Cruise MSM9/3

The cruise leg MSM09/3 was conducted as a cooperative project between the Alfred Wegener Institute for Polar and Marine Research (AWI), the Federal Institute for Geosciences and Resources (BGR), the Geological Survey of Denmark and Greenland (GEUS) and Dalhousie University. The data format is Society of Exploration Geophysicists SEG Y. A geophysical survey covered areas of Baffin Bay and Davis Strait between Greenland and the Canadian Baffin Island. A component of the IPY 2007/08 Lead Project Plate Tectonics and Polar Gateways in the Earth System (PLATES & GATES), this project DAVIS GATE is aimed to develop a tectonic and sedimentary reconstruction of the opening process of this oceanic gateway. Baffin Bay and Davis Strait play an important role in the shallow water exchange from the Arctic to the Atlantic Ocean. The plate-tectonic evolution as well as the magmatic history of this region has been sparsely known and required a careful geophysical investigation in order to construct a set of gridded detailed paleotopographic maps for a complete geodynamic reconstruction of this gateway. With a set of three seismic refraction/wide-angle reflection profiles, using ocean-bottom seismometers on 62 stations, as well as multi-channel reflection seismic recordings with a 3000-m long streamer, data were acquired from the sedimentary cover to the deep crust and even from parts of the uppermost mantle. Additional seismic data supplement these profiles and provide insights into the structures of the basement and dominant fault zones such as the Ungava fault system. A parallel running magnetic survey aimed to resolve the temporal evolution of the oceanic crust of Baffin Bay. The extension and subsidence of the continental and transitional crust in the Davis Strait and the evolution of oceanic crust in the Labrador Sea and Baffin Bay could be investigated with dataset to which continuously recorded gravity anomaly data and sub-bottom profiler data also contribute. This dataset provides the basis of geometrical and physical properties of the crust required for a realistic geodynamic model which will describe the break-up and the ocean basin evolution between Greenland and Canada in terms of detailed paleo-topography.

Processed seismic data of Cruise BGR 2007

The previous BGR-cruises with RV AURELIA in 2003 and 2004 and RV HEINCKE in 2005 and RV ALKOR in 2006 were designed to collect a grid of seismic MCS-data which should enable us to get a high-resolution overview over the upper 1-2 s TWT of the sediments of the German North Sea sector. The data format is Society of Exploration Geophysicists SEG Y. The aim of this cruise was a detailed survey in the north westernmost area of the German EEZ (exclusive economic zone), the so-called ‘Entenschnabel’ and additionally a mapping of special glacial structures off Sylt Island. The cruise was subdivided into two Legs. One outreaching additional aim was to extend the results from the previous cruises for the Late Tertiary and Quaternary sedimentary evolution into the ‘Entenschnabel’-area which was virtually unexplored by systematic shallow high-resolution seismics. During Leg 1 the BGR high-resolution multichannel seismic reflection system consisting of a GI-Gun (0.8 l) and a 500 m streamer with 36 channels and a shallow swath bathymetric system, type SIMRAD EM1200 by Kongsberg, Bergen, Norway were used. While the BGR-seismic system was used to observe the shallow subsurface down to 2 s TWT penetration depth, the swath bathymetric system was used to identify possible pockmark locations as well as sampling positions for the deployment of the BGR vibration corer during the succeeding Leg 2. All seismic records were processed onboard for the quality control and for a first interpretation loaded into GEOQUEST.

Processed seismic data of Cruise BGR97

The 3rd cooperative BGR/SMNG Arctic cruise was designed to acquire new scietific data for a better understanding of temporal and spatial lithospheric variations during rifting and its influence on the tectonic and structural evolution of the continental crust of the Laptev Sea undergoing extension since at least the Early Tertiary, and for tackling open questions regarding the evolution of the submarine permafrost zone. Although conditions for seismic measurements were worse in 1997 than in 1993 and 1994, along 4,622 km of seismic traverses reflection seismic data and wide angle reflection/refraction data from 23 OBH-(ocean bottom hydrophone) stations were collected in the Laptev and East Siberian Sea. The most prominent rift basin is the Ust' Lena Rift, which is at least 300 km wide at latitude 75°N. The Cenozoic sedimentary cover exceeds 3 km everywhere, increasing up to 14 km at two locations. In the northern part of the shelf, the complex mainly N–S-trending Anisin Basin has a basin fill of up to 10 km thickness. The New Siberian Basin which is located in the northwestern part of the study area shows an up to 9 km thick graben fill. The Laptev Horst crust is locally subdivided into several tilted blocks by deep-reaching faults and there are several half grabens of smaller extent which divide the Laptev Horst into three parts: the North, the South and the East Laptev Horst. A major west dipping listric fault of at least 250 km length separates the Laptev Horst from the Ust' Lena Rift. Results from the seismological investigation indicate that recent extension is concentrated within the narrow rift basins of the eastern Laptev Sea. From wide-angle reflection/refraction seismic measurements the seismic velocities of the crustal layers were estimated along five profiles. The layers with velocities of up to 3.5 km/s apparently consist of predominantly Cenozoic sediments. The sedimentary section showing relatively high seismic velocities of 4.5 to 5.2 km/s might be interpreted as Late Paleozoic to Mesozoic deposits or overcompacted/cemented syn-rift deposits. In the eastern shelf area a layer beneath the acoustic basement was interpreted to represent Ordovician to Early Mesozoic carbonates. The lower crust in the area under study shows relatively uniform seismic velocities of about 6.0-6.8 km/s and the velocities estimated for the crust-mantle transition are in the range of 8.0 to 8.2 km/s. The origin of a several 100 m thick layer with a relative high velocity of 3 to 3.5 km/s directly beneath the seafloor was inferred as sub-sea permafrost.

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