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Entwicklung neuer zeolithischer Redoxkatalysatoren für die selektive Reduktion von NO durch Ammoniak durch Aufklärung der Beziehungen zwischen Katalysatorstruktur und katalytischen Eigenschaften

Ziel des Vorhabens ist die Entwicklung hochaktiver, selektiver und stabiler zeolithischer Redoxkatalysatoren für die selektive Reduktion von Stickstoffoxiden mit Ammoniak. Zu diesem Zweck werden durch Kombination katalytischer Untersuchungen mit Studien zur physikochemischen Charakterisierung von Aktivkomponente und Matrix (Methoden: EPR, ferromagnetische Resonanz (FMR), Mößbauerspektroskopie, EXAFX, XPS, ISS, UV-Vis, IR, Raman, XRD) gesicherte Erkenntnisse über die erforderliche Struktur der Redoxkomponente und der zeolithischen Matrix erarbeitet, die in verbesserte Präparationsstrategien für eine neue Katalysatorgeneration umgesetzt werden. Bezüglich der Strukturierung der Übergangsmetallkomponente ist durch Kombination katalytischer mit spektroskopischen Techniken zwischen der Wirkung isolierter Ionen auf Kationenplätzen sowie intra- bzw. extra-zeolithischer Oxidaggregate zu differenzieren, wobei dem Beweis der katalytischen Relevanz von Spezies über spektroskopische in situ-Studien (EPR, UV-Vis, Raman, EXAFS) besondere Bedeutung zukommt (1.-3. Jahr).

Processed seismic data of Cruise BGR 1976

On the MS Explora (1st September, 1976 - 29th September, 1976) multichannel seismic measurements were carried out on 44 lines The area covered was the Barentssea. The data format is Society of Exploration Geophysicists SEG Y.

Marine Seismic Survey Profiles (MSSP) (WMS)

During the period from 1974 to 2018 various cruises from BGR acquired seismic lines worldwide. The aim of these marine expeditions was a detailed survey of the geological structure.

Processed seismic data of Cruise Nares 2001

The Scientific staff and crew onboard CCGS Louis S. St. Laurent (LSL) returned September the 10th, 2001 from a scientific expedition to the Nares Strait, the northernmost waterway connecting the Arctic and Atlantic oceans. The data format is Society of Exploration Geophysicists SEG Y. The ice conditions in the strait required the support of Canada's largest ice breaker. The ship was a versatile platform for 34 scientists to accomplish their marine investigation. The LSL has a history of supporting international scientific expeditions including an oceanographic transect of the Arctic Ocean in 1994 and a biological study of the Canadian Arctic Islands in 1999. Germany (Bundesanstalt für Geowissenschaften und Rohstoffe, BGR) and Canada (Geological Survey of Canada) undertook a 5-week scientific cruise to study and explore the geological structure and evolution of the Nares Strait. The primary objective was the study of structural features relating to the formation of the Arctic Ocean and, in particular, the study of the Wegener Fault. This fault is a linear boundary between Greenland and Ellesmere Island which was noted by the German scientist Alfred Wegener in 1915 and later became the subject of a major scientific controversy. The co-operative cruise, which was planned over a period of 2 years, provided the basis for a wide range of scientific investigations, from marine seismic work and climate change studies through airborne magnetic investigations to geodetic survey measurements and geological sampling onshore. Systematic geophysical offshore studies in this key area had not been undertaken before. Where towing of seismic equipment was not possible because of ice coverage, magnetic maps were made using a helicopter-borne magnetic sensor system. Sediment and water samples taken during the cruise provide information on changes in climate and sea ice cover from the last ice-age to the present. An 11 m-long sediment core from outer Jones Sound is the longest core ever taken in the Canadian Arctic channels and holds clues to the detailed climate history of northern Baffin Bay.

Processed seismic data of Cruise BGR 1974

Reconnaissance surveys were carried out in 1974 within the framework of the BGR program "Geoscientific studies in the North Atlantic". The areas covered were the continental margin of Spitsbergen, the Barents Sea and the Norwegian continental margin. On the R/V LONGVA (10th August, 1974 - 10th September, 1974) multichannel seismic measurements were carried out on 40 lines with a total length of 8,091 km. The data format is Society of Exploration Geophysicists SEG Y.

Processed seismic data of Cruise BGR 1977

A geophysical reconnaissance survey was carried out in the Labrador Sea and Davis Strait between July and September 1977 by BGR. The data format is Society of Exploration Geophysicists SEG Y. The survey was executed on the research vessel MS Explora. The seismic, magnetic and gravity data from 5931 line-kilometers on 21 lines were recorded on magnetic tape. A 24-fold coverage technique was used with 48 seismic channels (traces), with a 2400m streamer cable, and 23.45 l airgun array. A full integrated computerized satellite navigation system (INDAS III) served as positioning system. Based on a preliminary interpretation of the seismograms, the Labrador Sea was devided into an eastern (Greenland) and western (Canadian) area, seperated by the Mid Labrador Ridge. Within the eastern part of the Labrador Sea the Pre-Cenozoic sediments show three distinct layers, traceable over the entire Greenland area of the sea. In the Cenozoic layer olisthostromes occur. The highest apparent velocity determined from sonobuoy data was 9.26 km/sec. The calculated refractor lies at a depth of approximately 13 km. The seismic section from the sediments on the Canadian side of the Labrador Sea show a uniform series of thick sediments below the Cenozoic cover. The highly disturbed basement is often masked by the multiple reflections from the seafloor. Statements about the nature and structure of the basement can only be made after processing data.

Processed seismic data of Cruise BGR 1975

Reconnaissance surveys were carried out in 1975 within the framework of the BGR program "Geoscientific studies in the North Atlantic". The data format is Society of Exploration Geophysicists SEG Y. The areas covered were the continental margin of Spitsbergen, the Barents Sea and the Norwegion continental margin. On the vessel LONGVA (30th August, 1975 - 29th September, 1975) multichannel seismic measurements were carried out on 37 lines with a total length of 2,815 km.

Processed seismic data of Cruise ARK5/3 1988

In July/August 1988 a seismic reconnaisance survey was carried out with F.S. Polarstern on the perennially ice covered East Greenland shelf between latitudes 73°N and 81°N. The data format is Society of Exploration Geophysicists SEG Y. 14 reflection seismic lines with a total length of 2.016 km and 12 sonobuoy refraction profiles were recorded. The following results were obtained: •On the wide Holm Land shelf province north of 79°N three possible Cretaceous rift basins were observed. •A buildup of layered extrusive basaltic rocks forming a wedge of seaward dipping reflectors underlies the Holm Land continental slope. •On the Northeastern Greenland shelf province the existence of a wide sedimentary basin was demonstrated north of 76°N. •South of 76°N four volcanic structures from the continent to ocean were observed: The zone of Early Tertiary plateau basalts (zone I) that occur landward of an escarpment, a flat lying basaltic flow unit immediately seaward of the escarpment (zone II), an elongate wedge of seaward dipping reflectors (zone IIIa), a basaltic flow unit which in places shows seaward dipping beds of short length (zone IIIb), and the oceanic crust. •Dyke swarms and intrusions of inferred Neogene age were recognized at several locations.

Processed seismic data of Cruise BGR 1994

On the M/V Akademic Nemchinow multichannel seismic measurements were carried out on 34 lines with a total length of 4,000 km. The area covered was the Laptev Sea. The data format is Society of Exploration Geophysicists SEG Y.

Processed seismic data of Cruise AUR 2004

Continuing the systematic work which was started during a previous BGR expedition with RV AURELIA in Sept./Oct. 2003 the late Tertiary and Quaternary development of the German EEZ was further investigated by seismic profiling. The data format is Society of Exploration Geophysicists SEG Y. Again the research vessel AURELIA was chartered for a period of 21 days from 31st of May to 19th of June 2004. During the cruise the grid of seismic profiles which was aquired in 2003 was completed and data gaps were closed. A total of 2618km of high quality MCS lines were surveyed.

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