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KOSMOS 2023 Helgoland mesocosm study on ocean alkalinity enhancement: sediment trap particle flux data and water column biogeochemistry

The data presented herein originates from a mesocosm study conducted as part of the BMBF CDRmare, Retake project (grant agreement no. 03F0895A), aimed at investigating the ecological ramifications of ocean alkalinity enhancement (OAE). Twelve mesocosms were deployed in Helgoland South Harbor, Germany, and systematically sampled using integrated water samplers over the period spanning from March 12th to April 20th, 2023. Six alkalinity levels under two dilution scenarios were established to differentiate between localized and uniform OAE additions. Alkalinity was increased stepwise to ΔTAmax = 1250 μmol kg-1 (250 μmol TA kg-1 increments) using sodium hydroxide (NaOH) with calcium chloride (CaCl2) to simulate cation release during calcium-based mineral dissolution, causing strong carbonate chemistry perturbations (e.g., pHT > 9.25). The dataset encompasses a spectrum of sediment trap particle flux data, water column biogeochemistry including pigment variables, inorganic nutrients, carbonate chemistry parameters. The study and data set offer insights into impacts of alkalinity enhancement on marine ecosystems and their associated biogeochemistry.

Erfassung der Planktonbiomasse des Bodensee-Obersees mit Hilfe von Summenparametern

Erfassung der Planktonbiomasse des Bodensee-Obersees mit rasch, z.T. kontiunierlich messbaren Summenparametern (Protein, Algenpigmente, in-vivo-Fluoreszenz des Phytoplanktons, Coulter-Counter-Volumen, ATP) als Grundlage fuer genauere Biomassenbilanzierungen. Die Messungen werden in woechentlichem Abstand in je 12 bis 42 Seewasserproben durchgefuehrt.

Wirkungen von SO2 bzw. Schwermetallen auf pflanzenphysiologische Vorgaenge und auf die Zelle

Bearbeitete Teilfragen innerhalb des Gesamtprojektes: Physiologische Erklaerung des 'Truebungstests' nach Haertel als Diagnosemethode fuer Abgasschaeden an Koniferen. Das Verhalten der Borke in verunreinigter Luft (inkl. Stadtluftguete). Veraenderung der Enzymausstattung unter dem Einfluss von SO2 und Einfluss auf Schwefelstoffwechsel. Pigmentanalysen an immissionsgeschaedigten Pflanzen. Holzanatomische Veraenderungen in SO2-haltiger Luft (in Industriegebieten). Permeabilitaetsuntersuchungen an Pflanzenzellen nach SO2- bzw. Vitalfaerbungen an geschaedigten Pflanzenzellen.

Coastal Atmosphere & Sea Time Series (CoASTS) and Bio-Optical mapping of Marine optical Properties (BiOMaP): the near- surface marine bio-optical data

The CoASTS-BiOMaP data set comprises in situ near-surface inherent (e.g., absorption, scattering and backscattering coefficient s) and apparent (e.g., normalized-water leaving radiance and the corresponding remote sensing reflectance) optical properties of relevance for satellite ocean colour applications. The data were produced through the Coastal Atmosphere & Sea Time Series (CoASTS) and the Bio-Optical mapping of Marine optical Properties (BiOMaP) measurement programs implemented by the Marine Optical Laboratory of the Joint Research Center (JRC) in collaboration with a number of European institutions. Common to both CoASTS and BiOMaP is the standardization of instruments, measurement methods, quality control schemes and processing codes to enforce temporal and spatial consistency to data products. CoASTS measurements comprise 125 field campaigns and 637 stations performed from December 1998 up to March 2016 benefitting of the Acqua Alta Oceanographic Tower (AAOT) in the northern Adriatic Sea to generate time series data at a fixed coastal site. CoASTS data exhibit occurrence of waters with optical properties largely determined by phytoplankton, as well as diverse concentrations of suspended particulate matter (SPM) and of coloured organic matter (CDOM). BiOMaP measurements comprise 36 bio-optical oceanographic campaigns and 1915 stations performed between July 2000 and May 2022 using a variety of oceanographic vessels to produce spatially distributed data across various European Seas. BiOMaP measurement regions include: the Baltic Sea exhibiting waters dominated by a high concentration of CDOM; the Adriatic Sea, Black Sea, North Sea (comprising the English Channel), Ligurian Sea, Iberian Shelf and the Greenland Sea, characterized by a variety of optically complex waters determined by diverse concentrations of CDOM and SPM; the Eastern and Western Mediterranean oligotrophic and mesotrophic Seas.

Chlorophyll a, extracellular polymeric substance concentration and 16S rRNA gene copy numbers in saltmarsh sediments in response to a storm surge

Samples were taken to study the effect of storm surges on ecosystem functioning of salt marsh microbial communities. Sediment samples were collected from experimental salt marsh islands located in the back-barrier tidal flats of Spiekeroog Island, German North Sea (53°45′N, 7°43′E). The islands consist of three elevation zones (0.7 m, 1.0 m, and 1.3 m above mean sea level), corresponding to pioneer zone, lower salt marsh, and upper salt marsh. Six islands were sampled (three initially bare; three transplanted with lower salt marsh sediment and vegetation). Sampling was conducted in September 2022 (pre-disturbance), March 2023 (post-winter storm surges), and August 2023 (recovery phase). Surface sediments (upper 2 cm) were collected using syringe cores. Pooled samples were analyzed for chlorophyll a as a proxy for microphytobenthos biomass using ethanol extraction and spectrophotometric pigment analysis. Extracellular polymeric substances (EPS) were quantified using EDTA extraction followed by phenol–sulfuric acid carbohydrate analysis. DNA was extracted from sediment subsamples using a Qiagen PowerSoil kit. Prokaryotic abundance was estimated by quantitative PCR targeting the 16S rRNA gene (primers 519F/907R), using an Escherichia coli 16S rRNA gene standard curve. The dataset includes chlorophyll a concentrations (µg g⁻¹ dry sediment), EPS carbohydrate concentrations, and prokaryotic 16S rRNA gene copy numbers for all sampling times, elevations, and treatments.

Coastal Atmosphere & Sea Time Series (CoASTS) and Bio-Optical mapping of Marine optical Properties (BiOMaP): the water hyperspectral absorption coefficients

The CoASTS-BiOMaP data set of hyperspectral absorption coefficients, complementary to the bio-optical data set accessible at https://doi.org/10.1594/PANGAEA.971945, were determined from laboratory analysis of discrete water samples collected at approximately 1 m depth during the Coastal Atmosphere & Sea Time Series (CoASTS) and the Bio-Optical mapping of Marine optical Properties (BiOMaP) measurement programs. The dataset, resulting from the collaboration between the Marine Optical Laboratory of the Joint Research Center (JRC) and a number of European national institutions, comprises absorption coefficients of pigmented and non-pigmented particles in the 400-750 nm interval, and those by colored dissolved organic matter in the 350-680 nm interval, provided with 3 nm spectral resolution at 2 nm increment. All coefficients were determined applying identical sampling, laboratory, processing and quality control methods, regardless of the measurement program or geographic areas. A few spectra of absorption coefficients for pigmented particles exhibit some unrealistic negative values beyond approximately 500 nm explained by limits of the measurement methodology in the presence of a low concentration of particles largely associated with sampling in oligotrophic waters. These spectra were not excluded from the data set expecting their application can be still relevant once the absorption coefficients are corrected for their background in the near-infrared. Overall, the data set comprises absorption spectra from 2549 stations. Of these, 634 stations refer to 125 CoASTS field campaigns performed from October 1998 up to March 2016 on-board the Acqua Alta Oceanographic Tower (AAOT) in the northern Adriatic Sea representing moderate optically complex waters with properties largely determined by phytoplankton, as well as diverse concentrations of suspended particulate matter (SPM) and of coloured dissolved organic matter (CDOM). The remaining 1915 stations are from 36 BiOMaP oceanographic campaigns performed between July 2000 and May 2022 in various European marine regions: the Baltic Sea with waters dominated by a high concentration of CDOM; the Adriatic Sea, Black Sea, North Sea (comprising the English Channel), Ligurian Sea, Iberian Shelf and the Greenland Sea, exhibiting a variety of optically complex waters determined by diverse concentrations of CDOM and SPM; the Eastern and Western Mediterranean oligotrophic and mesotrophic Seas.

Remondis Production GmbH in Lünen (2021 - 2024)

Bei der Haupttätigkeit der Remondis Production GmbH , Inspire-ID: https://registry.gdi-de.org/id/de.nw.inspire.pf.bube-eureg/anl-2017-978024-900-9103516-0010) handelt es sich um Herstellung von Nichtmetallen und Metalloxiden (NACE-Code: 20.14 - Herstellung von sonstigen organischen Grundstoffen und Chemikalien). Weitere Nebentätigkeiten beinhalten: Beseitigung oder Verwertung v. gefährlichen Abfällen > 10 t/d Herstellung von Farbstoffen und Pigmenten. Es wurden keine Freisetzungen oder Verbringungen nach PRTR berichtet zu: Freisetzung in die Luft, Freisetzung in das Wasser, Freisetzung in den Boden, Verbringung von Schadstoffen mit dem Abwasser, Verbringung gefährlicher Abfälle im Ausland.

Biogeochemical variables from a Multidisciplinary BASS Mesocosm Study at Wilhelmshaven, 2023

This dataset contains biogeochemical variables measured during the same mesocosm experiment at Sea Surface Facility (SURF) in Wilhelmshaven, Germany (53.5148° N, 8.1461° E) in 2023. Variables include surfactants and nutrient concentrations, chlorophyll a, pigments, particulate and dissolved organic carbon and nitrogen, and several other biogeochemical parameters. These data complement the daily averaged physical parameters (PANGAEA DOI: https://doi.pangaea.de/10.1594/PANGAEA.983975) and together support the assessment of ecosystem and biogeochemical dynamics associated with the experiment, as described in the related publication Bibi et al., 2025.

A validation data set of phytoplankton pigment concentrations and phytoplankton groups measured on water samples collected from various expeditions

This data set composes quality controlled in situ measurements of eight major pigments based on HPLC collected from various expeditions from 2016 to 2023. There are two subsets: subset 1 is the test dataset (99 matchups) extracted from and takes up 30 % of a global in situ PFT matchup data set, while the other 70 % was used for the retuning of the PFT algorithm for Sentinel 3 OLCI sensors. Subset 1 spans from 2016 to 2021 and is part of the global data set described in Xi et al. (2023): https://doi.pangaea.de/10.1594/PANGAEA.954738. Subset 2 containing 134 matchups is a newly compiled dataset that composites in situ PFT data collected from four recent mostly polar expeditions with the research vessel Polarstern (Alfred-Wegener-Institut Helmholtz-Zentrum für Polar- und Meeresforschung, 2017), that are PS126 (May–June 2021), PS131/1 (June–Aug 2022) and PS136 (May–June 2023) in the north Atlantic to the Arctic Ocean, and PS133 (Oct–Nov 2022) in the Southern Ocean. The in situ PFT data were derived from quality-controlled HPLC pigment concentrations using diagnostic pigment analysis (DPA) with updated pigment-specific weighting coefficients following Xi et al. (2023). This published data set has been used to validate satellite PFT products generated for the EU funded Copernicus Marine Service (CMEMS, https://marine.copernicus.eu/), which are derived from multi-sensor ocean color reflectance data and sea surface temperature using an empirical orthogonal function based approach (Xi et al. 2020; 2021).

Phytoplankton pigment concentrations during POLARSTERN cruise PS121 from North Sea to Fram in August to September 2019

Phytoplankton pigments were determined in the water column of a transect from the North Sea to Fram Strait during RV Polarstern expedition PS121 from 11 Aug to 10 Sep 2019. Water samples were collected from CTD Niskin bottles at five to six different depths from the upper 100 m at CTD stations and from underway sampling. This were the same water samples as in Bracher et al. (https://doi.pangaea.de/10.1594/PANGAEA.938260). Between 0.2 to 3.5 L of each seawater sample was filtered through Whatman GF/Ffilters. The sample filters were then shock‐frozen in liquid N2 and kept at−80 °C until analysis. High Pressure Liquid Chromatography (HPLC) was performed to quantify various phytoplankton pigments (see Table 1 in Taylor et al. 2011) following the method of Barlow et al. (1997) that was adjusted to our temperature‐controlled instruments as detailed in Alvarez et al. (2022).

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