Other language confidence: 0.7157221410051707
The development of sustainable and efficient energy conversion processes at interfaces is at the center of the rapidly growing field of basic energy science. How successful this challenge can be addressed will ultimately depend on the acquired degree of molecular-level understanding. In this respect, the severe knowledge gap in electro- or photocatalytic conversions compared to corresponding thermal processes in heterogeneous catalysis is staggering. This discrepancy is most blatant in the present status of predictive-quality, viz. first-principles based modelling in the two fields, which largely owes to multifactorial methodological issues connected with the treatment of the electrochemical environment and the description of the surface redox chemistry driven by the photo-excited charges or external potentials.Successfully tackling these complexities will advance modelling methodology in (photo)electrocatalysis to a similar level as already established in heterogeneous catalysis, with an impact that likely even supersedes the one seen there in the last decade. A corresponding method development is the core objective of the present proposal, with particular emphasis on numerically efficient approaches that will ultimately allow to reach comprehensive microkinetic formulations. Synergistically combining the methodological expertise of the two participating groups we specifically aim to implement and advance implicit and mixed implicit/explicit solvation models, as well as QM/MM approaches to describe energy-related processes at solid-liquid interfaces. With the clear objective to develop general-purpose methodology we will illustrate their use with applications to hydrogen generation through water splitting. Disentangling the electro- resp. photocatalytic effect with respect to the corresponding dark reaction, this concerns both the hydrogen evolution reaction at metal electrodes like Pt and direct water splitting at oxide photocatalysts like TiO2. Through this we expect to arrive at a detailed mechanistic understanding that will culminate in the formulation of comprehensive microkinetic models of the light- or potential-driven redox process. Evaluating these models with kinetic Monte Carlo simulations will unambiguously identify the rate-determining and overpotential-creating steps and therewith provide the basis for a rational optimization of the overall process. As such our study will provide a key example of how systematic method development in computational approaches to basic energy sciences leads to breakthrough progress and serves both fundamental understanding and cutting-edge application.
The EU Climate Policy Tracker (EU CPT) presents up-to-date developments in climate and energy policies in the EU-27. Although government policy is the single most influential driver behind the fight against climate change, there is limited information about the status of the policies that influence increases or decreases in emissions. The EU Climate Policy Tracker (EU CPT) is intended to bridge this gap. The project holds two references in focus at the same time: a 2050 goal of near total decarbonisation, and our current policy trajectory. A uniquely developed scoring method, modelled on appliance efficiency labels (A-G), gives an indication of how Member States are doing compared to a low-carbon policy package. This results in aggregated scores, supported with a rich background of information, for all Member States, at EU level, and for different economic sectors. The project is intended to be a resource for those seeking information, a means of sharing best practice, and a way of holding policymakers to account. In 2011 we updated our initial rating from November 2010. The findings of 2010 showed that the average score across the EU was an E, indicating that the level of effort needed to treble to be on track to reach the 2050 vision. Looking at the developments in 2011, we can see that there has been considerable activity in many countries, though the overall scoring has generally remained constant: positive actions are counteracted by negative developments or budget cuts. The EU CPT is a joint project by Ecofys and WWF. The project is funded by the European Climate Foundation. Visit the EU Climate Policy Tracker on: www.climatepolicytracker.eu.
Konkretes Management von Substanzen von hoher Besorgnis im Rahmen von REACH; Exemplarische Beschreibung an Fallbeispielen.
Previous Sternfahrten were mainly conducted in spring and summer. To cover the seasonal aspects more thoroughly, including a winter situation, Sternfahrt 13 was conducted in February 2025 (10–12 February). We used the RV Heincke (cruise HE653/2) instead of the RV Uthörn. The Heincke's draught is greater, so we could not reach all of our previous stations. Surface and bottom water samples were taken with a rosette; in the event of stratification in the water column, an additional sample was taken from the middle.
Bebauungspläne und Umringe der Kreisstadt Saarlouis (Saarland) Stadtteil Beaumarais:Bebauungsplan "Am Rech Nr.64_0" der Kreisstadt Saarlouis, Stadtteil Beaumarais
Für die sehr persistente und sehr mobile Verbindung Trifluoracetat (TFA) werden die potentiell TFA-emittierenden Industriebetriebe dargestellt, die im Rahmen des Gutachtens „Trifluoracetat (TFA): Grundlagen für eine effektive Minimierung schaffen - Räumliche Analyse der Eintragspfade in den Wasserkreislauf“ (Laufzeit: August 2021-November 2022) ermittelt wurden. Wichtiger Hinweis: Informationen zu Industriebetrieben in Deutschland, die TFA direkt in die aquatische Umwelt emittieren, lagen nicht vor. Daher können keine Aussagen zur Relevanz des Eintragspfads Industrie für die TFA-Fracht in Fließgewässern in Deutschland und zum Standort TFA-emittierender Betriebe getroffen werden. Ob und in welchem Umfang die aufgezeigten Betriebe tatsächlich TFA in die aquatische Umwelt emittieren, kann an dieser Stelle nicht beantwortet werden. Hier wird daher lediglich die Lage der Betriebe in Deutschland dargestellt, welche laut der Angaben im E-PRTR-Register Betriebe sind, die Fluor oder Fluor-haltige Verbindungen emittieren oder nach Artikel 10 der REACH-Verordnung registriert sind. Die Daten lassen jedoch keine Rückschlüsse auf die tatsächlich im Betrieb produzierten und/oder verarbeiteten fluorierten Chemikalien zu. Genauere Hinweise befinden sich im Abschnitt Herkunft des Datenkatalogs.
Bebauungspläne und Umringe der Gemeinde Gersheim (Saarland), Ortsteil Bliesdalheim:Bebauungsplan "Zum Rech 1. Änderung (OT Bliesdalheim)" der Gemeinde Gersheim, Ortsteil Bliesdalheim
Bebauungspläne und Umringe der Gemeinde Gersheim (Saarland), Ortsteil Bliesdalheim:Bebauungsplan "Zum Rech" der Gemeinde Gersheim, Ortsteil Bliesdalheim
The dataset contains sedimentation velocity measurements for 22 morphologically diverse macroalgae species (n = 49), the seagrass Zostera marina (n = 3), and plastic particles of four distinct shapes (n = 16). Each sample was measured at least five times, with some measured up to seven times. Detailed morphological descriptions and images are available in the corresponding paper. Samples with a SampleID starting with "K" were collected in January 2023 from the Kiel Fjord, Germany (between Strande and Bülk light house, 54°26'57.4N 10°11'37.6E). U. gigantea was collected in June 2024 in Yerseke, Netherlands (51°30'09.0N, 4°02'39.7E). All other samples were collected in June 2024 at the same site from the Kiel Fjord as in 2023, as well as two additional locations (Schilksee, 54°25'16.3N 10°10'43.1E and Mönkeberg, 54°21'20.92N 10°10'41.97E). Sedimentation velocity measurements were conducted in plastic cylinders, allowing particles to sink 15 cm to reach their terminal sinking velocity before starting the measurements. The sinking time was recorded using a stopwatch, and sedimentation velocity was calculated by dividing the sinking distance by the elapsed time. Test with varying cylinder heights showed no significant differences in results. Macrophyte species measured: Fucus vesiculosus, Fucus serratus, Saccharina latissima, Gracilaria vermiculophylla, Ceramium virgatum, Vertebrata fucoides, Polysiphonia stricta, Spermothamnion repens, Ahnfeltia plicata, Furcellaria lumbricalis, Coccotylus truncatus, Delesseria sanguinea, Cladophora flexuosa, Cladophora sp., Rhodomela confervoides, Pyropia leucosticta, Ulva clathrata, Ulva linza, Kornmannia leptoderma, Bryopsis hypnoides, Acrosiphonia centralis, Ulva gigantea, and Zostera marina. The plastic particles include eight circular pieces of foil (disks), three table tennis balls, two plastic nets, and three rubber bands. The foil disks were cut to different diameters and some were punched with different numbers of small holes. The name of the foil circles indicates both their diameter and perforation level. For example, "Disk 40-1" had a diameter of 40 mm and was unpunched, where "1" denotes unpunched, "2" partially punched, and "3" heavily punched, "4" extremely heavily punched. The three tennis balls shared identical dimensions but had different mass densities due to the different level of replacement of air with seawater and glass beads in the tennis ball.
This metadata overs the dataset containing information on how EU Member States spend the revenues from auctioning EU ETS emission allowances in one calendar year. More information on the EU Emissions Trading System (EU ETS) can be found here. The revenues from the auctioning of these allowances represent an increasing income source for Member States. This data is being collected under Article 19 of the Governance Regulation. The Regulation’s aim is to help the EU reach its 2030 climate and energy targets by setting common rules for planning, reporting and monitoring. The Regulation also ensures that EU planning and reporting are synchronised with the ambition cycles under the Paris Agreement. Reporting is mandatory for EU Member States. Some information is only mandatory to report if the data is available.
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