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GTS Bulletin: SIVX81 EDZW - Surface data (details are described in the abstract)

The SIVX81 TTAAii Data Designators decode as: T1 (S): Surface data T1T2 (SI): Intermediate synoptic hour (Remarks from Volume-C: SHIP)

GTS Bulletin: ISNI01 EDZW - Observational data (Binary coded) - BUFR (details are described in the abstract)

The ISNI01 TTAAii Data Designators decode as: T1 (I): Observational data (Binary coded) - BUFR T1T2 (IS): Surface/sea level T1T2A1 (ISN): Synoptic observations from fixed land stations at non-standard time (i.e. 01, 02, 04, 05, ... UTC) A2 (I): 0° - 90°W southern hemisphere(The bulletin collects reports from stations: 89011;89047;) (Remarks from Volume-C: SYNOP)

GTS Bulletin: ISND39 AMDS - Observational data (Binary coded) - BUFR (details are described in the abstract)

The ISND39 TTAAii Data Designators decode as: T1 (I): Observational data (Binary coded) - BUFR T1T2 (IS): Surface/sea level T1T2A1 (ISN): Synoptic observations from fixed land stations at non-standard time (i.e. 01, 02, 04, 05, ... UTC) A2 (D): 90°E - 0° northern hemisphere (Remarks from Volume-C: NATIONAL AUTOMATIC SYNOP)

GTS Bulletin: ISND81 AMDN - Observational data (Binary coded) - BUFR (details are described in the abstract)

The ISND81 TTAAii Data Designators decode as: T1 (I): Observational data (Binary coded) - BUFR T1T2 (IS): Surface/sea level T1T2A1 (ISN): Synoptic observations from fixed land stations at non-standard time (i.e. 01, 02, 04, 05, ... UTC) A2 (D): 90°E - 0° northern hemisphere (Remarks from Volume-C: NATIONAL AUTOMATIC SYNOP)

GTS Bulletin: ISID05 EDZW - Observational data (Binary coded) - BUFR (details are described in the abstract)

The ISID05 TTAAii Data Designators decode as: T1 (I): Observational data (Binary coded) - BUFR T1T2 (IS): Surface/sea level T1T2A1 (ISI): Intermediate synoptic observations from fixed land stations A2 (D): 90°E - 0° northern hemisphere(The bulletin collects reports from stations: 10161;Boltenhagen;10168;Goldberg;10180;Barth;10193;Ueckermünde;10210;Friesoythe-Altenoythe;10235;Soltau;10249;Boizenburg;10261;Seehausen;10267;Kyritz;10281;Trollenhagen;10282;Feldberg/Mecklenburg;10289;Grünow;10305;Lingen;10309;Ahaus;10312;Belm;) (Remarks from Volume-C: SYNOP)

Multibeam bathymetry raw data (Kongsberg EM712 entire dataset) of RV HEINCKE during cruise HE642

Raw multibeam bathymetry data from the Kongsberg EM712 were acquired during the RV Heincke cruise HE642 in the German Bight in June 2024. The data was generally acquired during calm seas, although bad weather periods occurred mainly during the later stages of the cruise. Water depths range between 20 and 50 m. Primarily, two different regions were surveyed (Borkumer Reef Ground and Sylt Outer Reef). Generally, the data is comprehensive and overlapping swaths creating a continuous bathymetry were archived. In some areas, the data was acquired complementary to sidescan sonar surveys, where individual tracks do not overlap. Data are unprocessed and therefore may contain some incorrect depth measurements (artifacts) without further processing. No tide variations are applied. Sound velocity profiles were acquired regularly. Overall, it appears that the data quality is good but compromised by a slightly tilted centre swath sector. The gridded data shows relatively few artefacts.

First-principles kinetic modeling for solar hydrogen production

The development of sustainable and efficient energy conversion processes at interfaces is at the center of the rapidly growing field of basic energy science. How successful this challenge can be addressed will ultimately depend on the acquired degree of molecular-level understanding. In this respect, the severe knowledge gap in electro- or photocatalytic conversions compared to corresponding thermal processes in heterogeneous catalysis is staggering. This discrepancy is most blatant in the present status of predictive-quality, viz. first-principles based modelling in the two fields, which largely owes to multifactorial methodological issues connected with the treatment of the electrochemical environment and the description of the surface redox chemistry driven by the photo-excited charges or external potentials.Successfully tackling these complexities will advance modelling methodology in (photo)electrocatalysis to a similar level as already established in heterogeneous catalysis, with an impact that likely even supersedes the one seen there in the last decade. A corresponding method development is the core objective of the present proposal, with particular emphasis on numerically efficient approaches that will ultimately allow to reach comprehensive microkinetic formulations. Synergistically combining the methodological expertise of the two participating groups we specifically aim to implement and advance implicit and mixed implicit/explicit solvation models, as well as QM/MM approaches to describe energy-related processes at solid-liquid interfaces. With the clear objective to develop general-purpose methodology we will illustrate their use with applications to hydrogen generation through water splitting. Disentangling the electro- resp. photocatalytic effect with respect to the corresponding dark reaction, this concerns both the hydrogen evolution reaction at metal electrodes like Pt and direct water splitting at oxide photocatalysts like TiO2. Through this we expect to arrive at a detailed mechanistic understanding that will culminate in the formulation of comprehensive microkinetic models of the light- or potential-driven redox process. Evaluating these models with kinetic Monte Carlo simulations will unambiguously identify the rate-determining and overpotential-creating steps and therewith provide the basis for a rational optimization of the overall process. As such our study will provide a key example of how systematic method development in computational approaches to basic energy sciences leads to breakthrough progress and serves both fundamental understanding and cutting-edge application.

Multibeam bathymetry processed data (Kongsberg EM2040 working area dataset) of RV ALKOR during cruise AL644, Baltic Sea

Swath sonar bathymetry data recorded during AL644 on RV ALKOR using the hull-mounted Kongsberg EM2040 multibeam echosounder. The cruise took place between 17.11.2025 - 28.11.2025 in the German Baltic Sea. The approximate depth range of the mapped areas is between 10-30m. To improve MBES data quality, sound velocity profile (SVP) casts were conducted in the vicinity of the mapped area prior to and after each survey using a CTD. The data set includes data from the 'Adlergrund' (ADG), located within the Pommeranian Bay/Rønne Bank Nature Conservation Area (NCA), from the 'Kadet Trench ('KDR') NCA and the Fehmarn Belt ('FB') NCA. The mapping has been conducted for baseline habitat studies in the area. Data were manually edited for false measurements using Qimera (https://qps.nl/qimera/#). A raster was calculated and stored in GeoTIFF format with a 0.5 m resolution (negative values), WGS84 as vertical datum and UTM as a projection. The mapping has been conducted for baseline habitat studies in the area.

Multibeam bathymetry processed data (Kongsberg EM2040 working area dataset) of RV ALKOR during cruise AL652/2, MPA Fehmarnbelt, Baltic Sea

Swath sonar bathymetry data were acquired during cruise AL652-2 with the research vessel RV ALKOR using a hull-mounted Kongsberg EM2040 multibeam echosounder (MBES). The cruise took place between 25.05.2026 - 02.06.2026 in the German Baltic Sea. The approximate depth range of the mapped area is between 15-30m. To improve MBES data quality, sound velocity profile (SVP) casts were conducted in the vicinity of the mapped area prior to and after each survey using a Sound Velocity Probe. The data set includes data from an area called 'Oejet', which is a part of the Nature Conservation Area (NCA) 'Fehmarnbelt', located in the western Baltic Sea. The survey was carried out to support baseline habitat studies in this region. Data processing involved the application of a weak spline filter and manual cleaning to remove erroneous soundings, performed using Qimera (https://qps.nl/qimera/#). A bathymetric raster was generated and exported in GeoTIFF format with a spatial resolution of 0.25 m (negative depth values), referenced to WGS84 as the vertical datum and projected in UTM coordinates. The dataset consists of two surveys (Stations AL652-2_65, AL652-2_77) that were combined into a single final grid.

Multibeam bathymetry raw data (Kongsberg EM2040 entire dataset) of RV ALKOR during cruise AL644

Swath sonar bathymetry data recorded during AL644 on RV ALKOR using the hull-mounted Kongsberg EM2040 multibeam echosounder. The cruise took place between 17.11.2025 - 28.11.2025 in the German Baltic Sea. The approximate depth range of the mapped areas is between 10-30m. To improve MBES data quality, sound velocity profile (SVP) casts were conducted in the vicinity of the mapped area prior to and after each survey using a CTD. The data set includes data from the 'Adlergrund' (ADG), located within the Pommeranian Bay/Rønne Bank Nature Conservation Area (NCA), from the 'Kadet Trench ('KDR') NCA and the Fehmarn Belt ('FB') NCA. The mapping has been conducted for baseline habitat studies in the area.

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