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Stammdaten und Analysedaten zu den Grundwassermessstellen im EUA-Messnetz: Messtelle DEGM_DEMV_25360014 (Möderitz)
The Nussloch Drilling Campaign (NUSS) involved drilling three loess sediment cores (85 mm in diameter) on April 21-25, 2019, on top of a loess hill at 49.31°N, 8.73°E, at an altitude of 215 m, close to the most recently described outcrop at the Nussloch reference site in Germany. Downhole logging was performed in the three drilling holes. Core S2, which has the most complete stratigraphy compared to previously published profiles, was analyzed using XRF core scanning. The name of the samples is given as NUSS for Nussloch, S2 for core S2, and C1-C11 for the subcore numbers. Depth is expressed in meters from the topsoil to the lowest level reached during drilling. The XRF data consists of the following elements: Na, Mg, Al, Si, P, S, Cl, K, Ca, Ti, Cr, Mn, Fe, Cu, Zn, Ni, Br, Rb, Sr, Zr, and Pb, in counts. These raw data counts are followed by the following ratios: Ca/Sr, Rb/Sr, Rb/K, Fe/Al, Fe/Mn, Si/Al, Ti/Al, Ti/Zr, Zr/Rb, and Ca/Al. Measurements were conducted every 1 cm from the top of the sub-cores. The measurements were performed with a resolution of 5mm on the AVAATECH Core Scanner at the EDYTEM laboratory in Chambéry in June 2015. This investigation aimed to conduct a comprehensive coring to acquire a sedimentary archive to ensure the preservation of this distinctive Nussloch record for future research projects.
The hydrochemical and stable isotope composition of fresh surface water in rivers (Sieber and Oder) of a karst area in the southwestern foreland of the Harz Mountains, Germany, was investigated at several occasions between years 1986 and 1992. The campaigns covered different seasonal and hydrological (discharge) conditions, including a snow-melt induced high water at the rivers. Aim of the study was the investigation of the impact of discharge conditions at the river water loosing water to underground passage in the Basin of Pöhlde, dissolving carbonate and sulfate minerals in the karst aquifers, and reappearing in the karst springs of the Rhume river. Besides physical characterization, hydrochemical major and minor elements were measaured, as weill as the carbon isotope composition of DIC, the sulfur and oxygen isotope composition of sulfate, and the oxygen isotope composition of water. Results reflect the impact of hydrological conditions on the subterrestrial carbon and sulfur cycles.
The dataset contains major and trace element concentrations measured by inductively coupled plasma optical emission spectrometry (ICP-OES) from water samples collected during a 16-day in-situ incubation experiment in the Baltic Sea (2025-07-12 to 2025-07-29). Samples were collected using an automated glass-syringe sampler deployed within two benthic chambers of a Biogeochemical Observatory (BIGO, Sommer et al., 2009) at 54° 34.432' N, 10° 10.776' E, at 22 m water depth. In one chamber, 29 g of fine calcite powder were added to the bottom water to assess the potential of enhanced benthic calcite weathering as an ocean alkalinity enhancement (OAE) strategy. Seven samples per chamber and from the ambient bottom water were analyzed to trace elemental changes associated with calcite dissolution.
The geochemical composition of surface sediments and pore waters from the Fehmarn Belt area, southern Baltic Sea, was analyzed in the context of the establishment of exclusion areas for bottom trawling activity. Samples were taken on cruise EMB238 in May/June 2020 using a multi corer or benthic lander device. Besides on-site measurements, further dissolved major and trace elements, dissolved inorganic carbon, nutrients were analyzed in home laboratory. Results are complemented by the analysis of potential microbial gross sulfate reduction rates and the geochemical composition of CNS and extractable sulfur (AVS, CrS(II), and acid-extractable Fe, Zn, Pb, Fe, Mn contents.
This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).
This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).
This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).
The data set contains the results for the porewater composition of samples, collected from different (up to 11) depths (down to 4.5 mbsf) at two sites in front of the Hütelmoor, southern Baltic Sea. Porewater was under impact by submarine groundwater discharge and collected during 6 field campaigns in years 2020 and 2021 using permanent multi-port samplers. Stable isotope signatures (H, C, O, S), major, and trace element data are presented to characterize the mixture between the endmembers freshwater and the brackish surface water component, superimposed by benthic diagenesis.
Oxbow lakes are continuous archives of flood events. On 28th June 2022 a 7.5 m long bottom sediment core (S1: 53.24758°N and 14.46271°E, 2.4 m b.s.l.) was collected from an oxbow lake in the Lower Odra Valley, NW Poland. Drilling was conducted using an Instorf sampler (Russian type; chamber dimension: 10 x 50 cm), onboard a "Manat" catamaran motorboat. After core recovery, each half-metre section was packed into a PVC tube and kept in cool rooms with a constant temperature. Samples were collected every 4 cm. For the first 2 m of the core grain-size, geochemical and Chironomidae analyses as well as radiocarbon dating were performed, which allow to identify flood events in the last 3200 years.
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