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UNESCO-Welterbe Römischer Limes (Kernzone)

Kernzone des UNESCO-Welterbes Römischer Limes in Hessen

UNESCO-Welterbe Römischer Limes (Pufferzone)

Umgebungsschutz für den Limes als landschaftsprägendes Element

UNESCO-Weltnaturerbe Fossillagerstätte Grube Messel (Kernzone)

Kernzone des UNESCO-Weltnaturerbes Fossillagerstätte Grube Messel

Baudenkmal

Kulturdenkmal nach § 2 Abs. 1 Hessisches Denkmalschutzgesetz (HDSchG), Grün- und Wasserflächen als Kulturdenkmal nach § 2 Abs. 1 HDSchG oder Bestandteil einer Gesamtanlage nach § 2 Abs. 3 HDSchG

Flächendenkmal

Gesamtanlage nach § 2 Abs. 3 Hessisches Denkmalschutzgesetz (HDSchG)

Bodendenkmal

Bodendenkmäler (Kulturdenkmäler nach § 2 Abs. 2 HDSchG), dargestellt als Mittelpunktkoordinate mit 300 m Wirkumkreis

Denkmalschutz Hessen (INSPIRE)

Der Datensatz Denkmalschutz Hessen (INSPIRE) des Landesamt für Denkmalschutz Hessen (LfDH) umfasst aus der Bau- und Kunstdenkmalpflege die Themen "Baudenkmal" und "Flächendenkmal", aus der hessenARCHÄOLOGIE die Themen "Bodendenkmal", "UNESCO-Welterbe Römischer Limes (Kernzone)" sowie "UNESCO-Welterbe Römischer Limes (Pufferzone)" und UNESCO-Weltnaturerbe Fossillagerstätte Grube Messel (Kernzone). Hinweis: Die Themen "Baudenkmal" und "Flächendenkmal" decken nicht die gesamte Landesfläche ab. Der aktuelle Bearbeitungsstand kann in einer Übersichtskarte in der Anwendung DenkXweb (https://denkxweb.denkmalpflege-hessen.de/bearbeitungsstand/) eingesehen werden. Die Themen "Bodendenkmal" sowie "UNESCO-Welterbe Römischer Limes (Kernzone)", "UNESCO-Welterbe Römischer Limes (Pufferzone)" und UNESCO-Weltnaturerbe Fossillagerstätte Grube Messel (Kernzone) decken die gesamte Landesfläche ab. Das Thema „Bodendenkmal“ (Kulturdenkmäler nach § 2 Abs. 2 HDSchG) wird als Mittelpunktkoordinate mit 300 m Wirkumkreis dargestellt.

Structural insight into conifer forest topsoil and blackwater dissolved organic matter by Orbitrap tandem MS mass difference matching

Ultrahigh-resolution Fourier transform tandem mass spectrometry was employed to reveal novel structural detail of the natural complex mixture dissolved organic matter (DOM) that is found ubiquitously in soils and rivers. We developed and evaluated a novel approach to decipher the structural detail that is encrypted in DOM. One DOM sample from a spruce forest (Wetzstein, Germany, 50° 27' 13" N; 11° 27' 27" E; 785 meter above sea level) and Suwannee River Natural Organic Matter (SRNOM, purchased from International Humic Substances Society as isolate 2R101N; details given in Green et al. 2015, Environm Eng Sci 32, 1) were used as representative biodegraded DOM mixtures of high complexity and measured by direct-injection tandem mass spectrometry (DI-ESI-Orbitrap-MS/MS). The unknowns in DOM were then compared with indicative tandem MS features (mass differences, "dm" features, written with greek letter delta instead of d) from known standard compounds (14 phenolic standard substances measured in parallel, and 11477 library mass spectra available from the java-based software framework SIRIUS which included nearly 18000 unique molecular structures) and natural product and in-silico structure suggestions. The dataset consists of seven subsets (Data Set S1 - S7), all of which are xlsx files. "Data Set S1", contains the standard compound data and fragmentation sensitivities (14 phenolic standards) and general information on the analyzed parts of the DOM mass spectrum (molecular indices, number of precursors, number of product ions). Data Sets S2 through S5 contain the aligned DOM molecular composition data obtained at different collision energies for four mass windows ("Data Set S2", m/z 241; "Data Set S3", m/z 301; "Data Set S4", m/z 361; "Data Set S5", m/z 417) and include mass difference matching results (non-indicative dm features, standard compound (14 phenolics) dm features, and SIRIUS library spectra Δm features). "Data Set S6" contains the full dm feature lists and several data tables on individual DOM precursor properties (for example, aggregated matching results for indicative dm features (incl. N- and S-containing precursors), DOM precursor fragmentation sensitivity data, two-way clustering data of precursors and dm features, and structure suggestions classified into broader structural families ("scaffolds"). "Data Set S7" contains the results of a two-way clustering analysis using 725 SIRIUS-annotated dm features. In this dataset, the dm data is used to estimate structural compositions of individual DOM precursor ions. More details can be found in the related manuscript by the same authors.

Structural insight into conifer forest topsoil dissolved organic matter (Wetzstein, Germany) by Orbitrap tandem MS mass difference matching

Ultrahigh-resolution Fourier transform tandem mass spectrometry was employed to reveal novel structural detail of the natural complex mixture dissolved organic matter (DOM) that is found ubiquitously in soils and rivers. We developed and evaluated a novel approach to decipher the structural detail that is encrypted in DOM. A DOM sample from a spruce forest (Wetzstein, Germany, 50° 27' 13" N; 11° 27' 27" E; 785 meter above sea level) was used as a representative biodegraded DOM mixture of high complexity and measured by direct-injection tandem mass spectrometry (DI-ESI-Orbitrap-MS/MS). The unknowns in DOM were then compared with indicative tandem MS features (mass differences, "Δm" features) from known standard compounds (14 phenolic standard substances measured in parallel, and 11280 library mass spectra available from the java-based software framework SIRIUS) and natural product and in-silico structure suggestions. The dataset consists of six subsets (Data Set ds01 - ds06), all of which are xlsx files.

Correlation between geological and geomechanical properties of cataclastic rocks with various petrological content

Les difficultes techniques associees au percement de galeries dans des formations geologiques tectonisees sont frequentes. Elles peuvent se traduire par des convergences instantanees et/ou differees, de brusques effondrements de louvrage, par des debourrages de faille ou par des venues deau. Ces differents phenomenes ont un impact tres important sur lavancement du chantier, ainsi que sur sa securite. Deux theses realisees alEPFL (Habimana, 1999 et Bürgi, 1999) ont demontreque des roches afaibles cohesions (roches cataclastiques et kakirites), difficilement classifiables par les methodes courantes de caracterisation utilisees par les ingenieurs, peuvent etre decrites de maniere plus robuste tant dun point de vue mecanique que geologique, et quune prediction sur leur comportement mecanique deviendrait des lors possible. Le but du present projet consiste aetendre lapproche geologique/geomecanique couplee ades series de roches de contenus petrologiques differents, et avalider les observations de Habimana et Bürgi (1999). De plus, une evaluation de la methode danalyse XRCT (X Ray Computed Tomography) pour letude petrographique tridimensionnelle non destructive des roches est effectuee, visant a fournir un outil supplementaire dans la determination danisotropies au sein des materiaux en question avant la realisation des tests triaxiaux prevus. Cette approche ameliore considerablement les observations microstructurales classiques sur lames minces en les etendant ala 3D et semble pouvoir apporter un complement important quant ala prediction de la deformation observee de l'echantillon cataclastique. (FRA)

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