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Absolute abundances of methane- and sulfate-cycling microorganisms, pore water gas concentrations and stable carbon isotopes (Table 1)

Soil cores for microbial, dissolved gas concentrations and isotopic analysis were taken using a Russian type peat corer (De Vleeschouwer et al. 2010) before and after rewetting. Each time, we took duplicates at stations 1-8 for this rather labor-intensive process and divided the core into four depth sections: surface, 5–20, 20–40 and 40–50 cm. Subsamples for dissolved gases and stable carbon isotope analyses were taken with tip-cut syringes with a distinct volume of 3 ml (Omnifix, Braun, Bad Arolsen, Germany) and immediately placed into NaCl-saturated vials (20 ml, Agilent Technologies, 5182-0837, Santa Clara, USA) leaving no headspace and closed gas-tight using rubber stoppers and metal crimpers (both: diameter 20 mm, Glasgerätebau Ochs, Bovenden, Germany).

Repository der KI-Ideenwerkstatt: faszination_naechtlicher_vogelzug

# Faszination Nächtlicher Vogelzug A web component for visualizing migratory bird detections on an interactive map. Built with React, MapLibre GL, and the BirdWeather GraphQL API. Designed for embedding into CMS platforms like Contao. ## Tech Stack - **React 19** + **TypeScript** (Vite) - **MapLibre GL** -- WebGL map rendering (Stadia Maps dark theme) - **Supercluster** -- per-species spatial clustering - **Apollo Client 4** -- GraphQL data fetching with caching - **GraphQL Code Generation** -- type-safe queries from BirdWeather schema - **SunCalc** -- astronomical day/night calculations - **Tailwind CSS 4** + **Ant Design 6** -- UI - **Vitest** -- testing ## Features - **Interactive map** with color-coded detection clusters per species - **Timeline animation** with autoplay, step controls, and throttled slider - **Night-only mode** that compresses inactive daytime hours using SunCalc sunrise/sunset calculations - **Day/night overlay** showing the terminator (day/night boundary) as a real-time GeoJSON polygon - **Species search** with autocomplete and availability checking per map viewport - **Supplementary layers** (light pollution, noise mapping via WMS) - **Web component** (`<zug-birdnet>`) for CMS embedding without routing ## Project Structure ``` src/ main.tsx Web component registration App.tsx Root component, species selection state api/ fragments.ts GraphQL fragments (DetectionItem, SpeciesItem) queries.ts GraphQL queries (detections, species, search) useDetections.ts Detection fetch hook with prefetching components/ DatesProvider.tsx Time state context (date range, animation, night mode) MapProvider.tsx MapLibre GL instance context SpeciesDropdown.tsx Species selection with search autocomplete Timeline.tsx Date picker, animation slider, playback controls LayersDropdown.tsx Toggle info layers (light pollution, noise) InfoPopup.tsx Map info marker popups map/ Map.tsx MapLibre GL initialization and rendering clusterUtils.ts Per-species Supercluster index creation colorUtils.ts MapLibre paint expression builder mapStyles.ts Map layer definitions usePersistentColors.ts Stable color assignment per species infopoints.ts Static info marker data lib/ apollo-client.ts Apollo Client with cache type policies buildAvailableSpeciesQuery.ts Dynamic aliased query generation getDayPolygon.ts Day/night terminator polygon calculation getTranslatedSpeciesName.ts i18n species name lookup isNotNull.ts, hasNonNullProp.ts Type guard utilities throttle.ts Throttle utility gql/ Auto-generated GraphQL types (do not edit) ``` ## Architecture Three React context providers compose the application: ``` ApolloProvider GraphQL caching and data fetching DatesProvider Date range, animation state, night-only time segments MapProvider MapLibre GL map instance App Species selection, filtered detections, color mapping ``` **Data flow:** Apollo fetches detections for the current bounding box and date range. Detections are filtered client-side by the visualisation time window (controlled by the timeline slider). Each species gets its own Supercluster index for independent color-coded clustering. Cluster features are rendered via MapLibre GL layers with dynamic `match` paint expressions. **GraphQL:** Queries and fragments are defined in `src/api/` and typed via `@graphql-codegen/client-preset`. Run `npm run codegen` after schema changes to regenerate `src/gql/`. ## Development ```sh npm install npm run dev ``` The dev server uses a self-signed SSL certificate via `@vitejs/plugin-basic-ssl`. Accept the browser warning on first visit. Other commands: ```sh npm run build # Production build npm run test # Run tests npm run lint # ESLint npm run codegen # Regenerate GraphQL types ``` ## Build & Integration Run `npm run build` to produce the `dist/` folder. The build outputs stable filenames (no hashes) and splits vendor dependencies into separate chunks for caching: ``` dist/ index.html assets/ index.css App styles (Tailwind + Ant Design) index.js Application code, React, Supercluster, dayjs, SunCalc maplibre.js MapLibre GL antd.js Ant Design + icons apollo.js Apollo Client + graphql ``` Only `index.js` changes on application updates. Vendor chunks are cache-stable between deploys. To embed the web component, include the built CSS and JS, then use the custom element: ```html <link rel="stylesheet" href="/assets/index.css"> <script type="module" src="/assets/index.js"></script> <zug-birdnet></zug-birdnet> ``` No routing. The component is self-contained and can be placed anywhere on the page. Third-party CMS integration (e.g., Contao) only needs to include the built assets and the custom element tag. ## Configuration App-level settings are in `src/config.ts`: | Option | Default | Description | |---|---|---| | `SHOW_DEMO_INFOPOINTS` | `false` | Show static info markers on the map (demo/development only) |

Timeseries of binned benthic stable carbon isotope from ODP Site 162-982,130-807 and ODP Site 162-982

This dataset contains C. wuellerstorfi stable carbon isotope values binned by marine isotope stage from ODP Site 162-807 and ODP Site 162-982 that span the last 4.5 million years (Feng et al. 2022; Venz et al. 1999, 2002; Hodell & Venz-Curtis 2006). This isotope gradient reflects the accumulation of respired and disequilibrium carbon in the deep Pacific ocean relative to the North Atlantic. Also included are binned probstack δ18O (Ahn et al., 2017) and ΔGMST (Clark et al., 2024) values for comparison to the binned stable carbon isotope values.

The iron-snow regime in Fe-FeS cores: a numerical and experimental approach

In the Earth, the dynamo action is strongly linked to core freezing. There is a solid inner core, the growth of which provides a buoyancy flux that drives the dynamo. The buoyancy in this case derives from a difference in composition between the solid inner core and the fluid outer core. In planetary bodies smaller than the Earth, however, this core differentiation process may differ - Fe may precipitate at the core-mantle boundary (CMB) rather than in the center and may fall as iron snow and initially remelt with greater depth. A chemical stable sedimentation zone develops that comprises with time the entire core - at that time a solid inner core starts to grow. The dynamics of this system is not well understood and also whether it can generate a magnetic field or not. The Jovian moon Ganymede, which shows a present-day magnetic dipole field, is a candidate for which such a scenario has been suggested. We plan to study this Fe-snow regime with both a numerical and experimental approach. In the numerical study, we use a 2D/3D thermo-chemical convection model that considers crystallization and sinking of iron crystals together with the dynamics of the liquid core phase (for the 3D case the influence of the rotation of the Fe snow process is further studied).The numerical calculations will be complemented by two series of experiments: (1) investigations in metal alloys by means of X-ray radioscopy, and (2) measurements in transparent analogues by optical techniques. The experiments will examine typical features of the iron snow regime. On the one hand they will serve as a tool to validate the numerical approach and on the other hand they will yield important insight into sub-processes of the iron snow regime, which cannot be accessed within the numerical approach due to their complexity.

(Bio)geochemical data Pürgschachen Moor

The dataset contains multi-proxy-analyses (element geochemistry, stable Pb isotopes, humification index, ash content) of a 500-cm-long, 14C dated peat core covering the past ~5000 years from the ombrotrophic Pürgschachen Moor in the Styrian Enns Valley (Austrian Alps).

4.5 million years of deep ocean carbon isotope gradients and trace metals redox data

This dataset contains a 4.5 million year record of the benthic stable carbon isotope gradient between Ocean Drilling Program Sites 982 and 807 and a long trace metals dataset from ODP Site 1208. In addition, we include compiled timeslice data from throughout the deep ocean that characterize the stable carbon isotope difference between benthic stable isotope composition of C. wuellerstorfi at Site 982 and that site.

Bebauungsplan Nr. 200 "Sondergebiet Tierhaltungsanlagen" der Gemeinde Geeste

Die Gemeinde Geeste liegt im Landkreis Emsland und umfasst die Ortsteile Bramhar, Dalum, Geeste, Groß Hesepe, Klein Hesepe, Osterbrock und Varloh.

Brackish water rewetting of a temperate coastal peatland in NE Germany: Effects on Biogeochemistry, Microorganisms and Greenhouse gas emissions

The rewetting of drained peatlands is a promising measure to mitigate carbon dioxide (CO2) emissions by preventing the further mineralization of the peat soil through aeration. While freshwater rewetted peatlands can be significant methane (CH4) sources in the short-term, in coastal ecosystems the input of sulfate-rich seawater could potentially mitigate these emissions. The purpose of the data collection was to examine whether the presence of sulfate, known as an alternative electron acceptor, can cause lower CH4 production and thus, emissions by favoring the growth of sulfate-reducers, which outcompete methanogens for substrate. We therefore investigated underlying variables such as the methane-cycling microbial community along with CH4 fluxes and set them in context with CO2 fluxes along a transect in a coastal peatland before and directly after rewetting. In this way, a conclusion about the short-term greenhouse gas mitigation potential of brackish water rewetting of coastal peatlands could be drawn. This data collection consists of six data sets, with direct comparisons before and after rewetting of CO2 and CH4 fluxes (Tab. 2) and associated microbial communities (Tab. 1) being the main data. Pore water geochemistry (Tab. 1 and 3) and surface water parameters (Tab. 4) were collected simultaneously to provide potential explanatory variables. The sampling of continuous water level (Tab. 5) within wells and atmospheric weather data (air and soil temperature, relative humidity, photosynthetic photon flux density; Tab. 6) from a weather station was done in addition. Measurements started in June/July/August 2019 after field installation was finalized and were conducted on the drained coastal fen "Polder Drammendorf" on the island of Rügen in North-East Germany. On 26th November 2019, the dike was opened and channeled in order to rewet the peatland with brackish water. Before, the dike separated the peatland from the adjacent bay "Kubitzer Bodden", which is part of a brackish lagoon system connected to the Baltic Sea. Therefore, the peatland was nearly completely flooded and now resembles a shallow lagoon with high fluctuating water levels. We measured along a humidity (pre-rewetting)/water level (post-rewetting) gradient (stations 0-8) towards and across the main North-South oriented drainage ditch, including four stations on the Eastern side of the ditch (1–4), two ditch stations (0, 5) and two stations (6, 7) on the Western side of the ditch. Station 8 was chosen as an additional station farther towards the adjacent bay on the Western side, but was only accessible before rewetting. CH4 and CO2 fluxes (stations 0-7) were calculated from online gas concentrations measurements using laser-based analyzers and manual closed chambers (Livingston, G. P., & Hutchinson, G. (1995). Enclosure-based measurement of trace gas exchange: Applications and sources of error. In P.A. Matson, & R.C. Harriss (Eds.). Biogenic trace gases: Measuring emissions from soil and water (pp. 14–51). Blackwell Science Ltd., Oxford, UK). Soil cores for microbial, dissolved gas concentrations and isotopic analysis were taken using a Russian type peat corer (De Vleeschouwer, F., Chambers, F. M., & Swindles, G. T. (2010). Coring and sub-sampling of peatlands for palaeoenvironmental research. Mires and Peat, 7, 1–10) before and after rewetting. Each time, we took duplicates at stations 1-8 for this rather labor-intensive process and divided the core into four depth sections: surface, 5–20, 20–40 and 40–50 cm. Subsamples for dissolved gases and stable carbon isotope analyses were taken with tip-cut syringes with a distinct volume of 3 ml (Omnifix, Braun, Bad Arolsen, Germany) and immediately placed into NaCl-saturated vials (20 ml, Agilent Technologies, 5182-0837, Santa Clara, USA) leaving no headspace and closed gas-tight using rubber stoppers and metal crimpers (both: diameter 20 mm, Glasgerätebau Ochs, Bovenden, Germany). Absolute abundances of specific functional target genes, including methane- and sulfate-cycling microorganisms, were measured with quantitative PCR (qPCR) after DNA was extracted (GeneMATRIX Soil DNA Purification Kit, Roboklon, Berlin, Germany) and quantified (Qubit 2.0 Fluorometer, ThermoFisher Scientific, Darmstadt, Germany). Surface and pore water parameters were measured in parallel to the gas measurements and soil coring for microbial analyses. Most surface water variables (pH, specific conductivity, salinity, nutrients, oxygen, sulfate and chloride concentrations, DOC/DIC) were measured in-situ using a multiparameter digital water quality meter or taken to the laboratory as water samples for further analysis. Likewise, pore water/soil variables (pH, specific conductivity, nutrients, metals, sulfate and chloride concentrations, CNS) were either measured in-situ or taken to the laboratory as soil samples. While surface water analysis was only conducted in the drainage ditch before rewetting, it was done along the entire transect after rewetting. In contrast, pore water/soil analysis was mostly conducted before rewetting and only repeated occasionally after rewetting where possible.

Tripelelement-Stabilisotopensignaturen zur Untersuchung des atmosphärischen Chlormethanbudgets

Die stratosphärische Ozonschicht absorbiert die UV-C und UV-B Sonnenstrahlung und schützt damit Pflanzen, Tiere und Menschen vor Strahlenschäden. Durch anthropogen emittierte Fluorchlorkohlenwasserstoffe (FCKWs) wird die Ozonschicht abgebaut. Da FCKWs seit dem Montrealer Protokoll stark zurückgegangen sind, werden halogenierte Verbindungen wie Chlormethan (CH3Cl), die aus natürlichen Quellen freigesetzt werden, für den Abbau der Ozonschicht in der Stratosphäre zunehmend relevant. CH3Cl ist das am häufigsten vorkommende chlorhaltige Spurengas in der Erdatmosphäre, das für etwa 17% der durch Chlor katalysierten Ozonzerstörung in der Stratosphäre verantwortlich ist. Daher wird CH3Cl vornehmlich die zukünftigen Gehalte an stratosphärischem Chlor bestimmen. Die aktuellen Schätzungen des globalen CH3Cl-Budgets und die Verteilung der Quellen und Senken sind sehr unsicher. Ein besseres Verständnis des atmosphärischen CH3Cl-Budgets ist daher das Hauptziel dieses Projektes.Die Analyse stabiler Isotopenverhältnisse von Wasserstoff (H), Kohlenstoff (C) und Chlor (Cl) hat sich zu einem wichtigen Werkzeug zur Untersuchung des atmosphärischen CH3Cl-Budgets entwickelt. Das zugrundeliegende Konzept besteht darin, dass das atmosphärische Isotopenverhältnis einer Verbindung wie CH3Cl gleich der Summe der Isotopenflüsse aus allen Quellen angesehen werden kann, korrigiert um den gewichteten durchschnittlichen kinetischen Isotopeneffekt aller Abbauprozesse. Dadurch ist es möglich, die Bedeutung wichtiger Quellen und Senken mit bekannten Isotopensignaturen zu entschlüsseln. Eine Grundvoraussetzung für detaillierte Hochrechnungen des globalen Budgets ist die Bestimmung der durchschnittlichen Isotopenverhältnisse von H, C und Cl des troposphärischen CH3Cl. Aufgrund der relativ geringen Konzentration von atmosphärischem CH3Cl von ~550 ppbv stellt dies eine große messtechnische Herausforderung dar. Daher liegt der Schwerpunkt dieses Antrags auf der erfolgreichen Entwicklung von Dreifachelement-Isotopenmethoden zur genauen Messung von atmosphärischem CH3Cl.Im ersten Schritt wird ein Probenahmesystem für große Luftmengen konstruiert und für die Messungen der stabilen Isotopenverhältnisse von CH3Cl optimiert. Das Probenahmegerät wird zunächst im Labor getestet und dann zum Sammeln von Luftproben an drei verschiedenen Orten eingesetzt: an der Universität Heidelberg, am Hohenpeißenberg und im Schneefernerhaus. Die Probenahmen werden über einen Zeitraum von einem Jahr durchgeführt, um möglichst auch saisonale Schwankungen zu erfassen. Die Isotopenverhältnisse der Proben werden mit modernsten massenspektrometrischen Methoden im Labor gemessen. Die Ergebnisse aller Standorte und Zeitpunkte werden in der Gesamtheit evaluiert, um die durchschnittlichen stabilen H-, C und Cl-Isotopenwerte einschließlich ihrer saisonalen Schwankungen darzustellen. Abschließend werden die Daten hinsichtlich ihrer Anwendbarkeit für komplexe numerische Modelle kritisch diskutiert.

Titanium stable isotope compositions of Neoarchean tonalite-trondhjemite-granodiorite (TTG) suites from the Eastern Goldfields Superterrane, Yilgarn Craton

We report the titanium (Ti) stable isotope compositions (δ49Ti) of Neoarchean (ca. 2700-2650 Ma) tonalite-trondhjemite-granodiorite (TTG) suites from the Eastern Goldfields Superterrane, Yilgarn Craton. Samples were selected to cover the full range of trace element compositions exhibited by TTGs, and are primarily from the Kalgoorlie-Kambalda region of the Kalgoorlie Terrane. Ti stable isotope compositions were measured using multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) at the Cardiff Earth Laboratory for Trace Element and Isotope Chemistry (CELTIC), Cardiff University. The Ti isotope compositions of these samples (file: 2025-009_Spencer-et-al_Ti-Isotope-Data.xlsx) are presented alongside a compilation of their major and trace element concentrations (file: 2025-009_Spencer-et-al_Compiled-Isotope-Major-Trace-Element-Data.xlsx) taken from the Western Australian Geochemistry Database (WACHEM). Most TTG samples have δ49Ti values between 0.2 to 0.6‰ that increase with SiO2 content, while two highly evolved TTGs have δ49Ti > 1‰. At SiO2 ≈ 70 wt% the different TTG geochemical groups display distinct Ti isotope compositions.

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