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Timeseries of binned benthic stable carbon isotope from ODP Site 162-982,130-807 and ODP Site 162-982

This dataset contains C. wuellerstorfi stable carbon isotope values binned by marine isotope stage from ODP Site 162-807 and ODP Site 162-982 that span the last 4.5 million years (Feng et al. 2022; Venz et al. 1999, 2002; Hodell & Venz-Curtis 2006). This isotope gradient reflects the accumulation of respired and disequilibrium carbon in the deep Pacific ocean relative to the North Atlantic. Also included are binned probstack δ18O (Ahn et al., 2017) and ΔGMST (Clark et al., 2024) values for comparison to the binned stable carbon isotope values.

The iron-snow regime in Fe-FeS cores: a numerical and experimental approach

In the Earth, the dynamo action is strongly linked to core freezing. There is a solid inner core, the growth of which provides a buoyancy flux that drives the dynamo. The buoyancy in this case derives from a difference in composition between the solid inner core and the fluid outer core. In planetary bodies smaller than the Earth, however, this core differentiation process may differ - Fe may precipitate at the core-mantle boundary (CMB) rather than in the center and may fall as iron snow and initially remelt with greater depth. A chemical stable sedimentation zone develops that comprises with time the entire core - at that time a solid inner core starts to grow. The dynamics of this system is not well understood and also whether it can generate a magnetic field or not. The Jovian moon Ganymede, which shows a present-day magnetic dipole field, is a candidate for which such a scenario has been suggested. We plan to study this Fe-snow regime with both a numerical and experimental approach. In the numerical study, we use a 2D/3D thermo-chemical convection model that considers crystallization and sinking of iron crystals together with the dynamics of the liquid core phase (for the 3D case the influence of the rotation of the Fe snow process is further studied).The numerical calculations will be complemented by two series of experiments: (1) investigations in metal alloys by means of X-ray radioscopy, and (2) measurements in transparent analogues by optical techniques. The experiments will examine typical features of the iron snow regime. On the one hand they will serve as a tool to validate the numerical approach and on the other hand they will yield important insight into sub-processes of the iron snow regime, which cannot be accessed within the numerical approach due to their complexity.

Agricultural And Aquaculture Facilities / Tierhaltungs- und Aufzuchtanlagen in Brandenburg

Der Datensatz Agricultural And Aquaculture Facilities / Tierhaltungs- und Aufzuchtanlagen in Brandenburg ist die Datengrundlage der interoperablen INSPIRE-Darstellungs- (WMS) und Downloaddienste (WFS): Tierhaltungsanlagen nach BImSchG in Brandenburg - Interoperabler INSPIRE View-Service (WMS-AF-TIERE) Tierhaltungsanlagen nach BImSchG in Brandenburg - Interoperabler INSPIRE Download-Service (WFS-AF-TIERE) Der Datenbestand beinhaltet die Punktdaten zu den betriebenen Tierhaltungsanlagen aus dem Anlageninformationssystem LIS-A. Die Angaben zu den Anlagen enthalten jeweils den Standort und die genehmigte Leistung. Dabei erfolgte eine sog. Schematransformation und Belegung der INSPIRE-relevanten Attribute. Der Datensatz Agricultural And Aquaculture Facilities / Tierhaltungs- und Aufzuchtanlagen in Brandenburg ist die Datengrundlage der interoperablen INSPIRE-Darstellungs- (WMS) und Downloaddienste (WFS): Tierhaltungsanlagen nach BImSchG in Brandenburg - Interoperabler INSPIRE View-Service (WMS-AF-TIERE) Tierhaltungsanlagen nach BImSchG in Brandenburg - Interoperabler INSPIRE Download-Service (WFS-AF-TIERE) Der Datenbestand beinhaltet die Punktdaten zu den betriebenen Tierhaltungsanlagen aus dem Anlageninformationssystem LIS-A. Die Angaben zu den Anlagen enthalten jeweils den Standort und die genehmigte Leistung. Dabei erfolgte eine sog. Schematransformation und Belegung der INSPIRE-relevanten Attribute. Der Datensatz Agricultural And Aquaculture Facilities / Tierhaltungs- und Aufzuchtanlagen in Brandenburg ist die Datengrundlage der interoperablen INSPIRE-Darstellungs- (WMS) und Downloaddienste (WFS): Tierhaltungsanlagen nach BImSchG in Brandenburg - Interoperabler INSPIRE View-Service (WMS-AF-TIERE) Tierhaltungsanlagen nach BImSchG in Brandenburg - Interoperabler INSPIRE Download-Service (WFS-AF-TIERE) Der Datenbestand beinhaltet die Punktdaten zu den betriebenen Tierhaltungsanlagen aus dem Anlageninformationssystem LIS-A. Die Angaben zu den Anlagen enthalten jeweils den Standort und die genehmigte Leistung. Dabei erfolgte eine sog. Schematransformation und Belegung der INSPIRE-relevanten Attribute.

Schwerpunktprogramm (SPP) 1158: Antarctic Research with Comparable Investigations in Arctic Sea Ice Areas; Bereich Infrastruktur - Antarktisforschung mit vergleichenden Untersuchungen in arktischen Eisgebieten, Untersuchungen von Änderungen der Klimavariabilität während der letzten 130 000 Jahre basierend auf einem Eisbohrkern von Skytrain Ice Rise, Westantarktis (CliVarSky130)

Die Westantarktis ist eine der Regionen der Erde, die am sensibelsten auf den aktuellen Klimawandel reagiert. Ein Zusammenbruch dieses Eisschildes in einem wärmeren Klima würde dramatische Folgen für den globalen Meeresspiegelanstieg haben. Dabei spielt nicht nur der Anstieg der globalen Mitteltemperatur eine Rolle, sondern in gleichem Maße auch Veränderungen der Klimavariabilität. Diese Veränderungen können das labile westantarktische System an Kipppunkte bringen, die wiederum zu unwiderruflichen eisdynamischen Prozessen führen. Um diese zum Teil abrupten Veränderungen in Zukunft besser einschätzen zu können, müssen diesbezügliche Modellprojektionen auf einer soliden Datenbasis stehen. Paläoklimatische Zeitreihen, in diesem Fall aus Eisbohrkernen, bieten solch eine Datengrundlage. Besonders interessant sind hierbei Zeitreihen, die zurückreichen in das letzte Glazial, oder idealerweise in die davorliegende letzte natürliche Warmzeit (ca. 110 000 - 130 000 Jahre vor heute). Solche langen Zeitreihen aus der Westantarktis sind allerdings bisher nur spärlich vorhanden. Im Rahmen des WACSWAIN Projekts (WArm Climate Stability of the West-Antarctic Ice sheet in the last iNterglacial) wurde kürzlich ein neuer Eiskern auf Skytrain Ice Rise gebohrt, der einen Zeitraum bis 126 000 Jahre vor heute abdeckt. Umfassende kontinuierliche Datensätze der stabilen Wasserisotope, der chemischen Spurenstoffe und der physikalischen Parameter wurden im Rahmen von WACSWAIN erhoben und stehen nun für weitere Analysen zur Verfügung. Außerdem wurden zum ersten Mal parallel zu den kontinuierlichen Messungen ausschnittweise Abschnitte des Kerns mit der ultra-hochauflösenden Methode der Laser Ablation (LA-ICP-MS) auf ihren Spurenstoffgehalt untersucht. Dies erlaubt die Analyse von Veränderungen in bisher nicht verfügbarer Detailliertheit. Das Ziel des hier vorgestellten Projektes ist es diese hochaufgelösten Signale zusammen mit den kontinuierlichen zu nutzen, um die Veränderungen der Klimavariabilität in dieser Region der Westantarktis in beispielloser Genauigkeit für den letzten glazialen Zyklus statistisch zu analysieren. Ein besonderer Fokus wird dabei auf Phasen mit abrupten Änderungen in den Temperatur- und Eisbedeckungsproxies, wie zum Beispiel einem signifikanten Anstieg der marinen Ionenkonzentration und der Wasserisotope im frühen Holozän, liegen. Die statistischen Analysen der vergangenen Klimavariabilität (Varianz, Amplitude, Skalierungsfaktoren) werden im Folgenden genutzt, um die aktuell zu beobachtenden Veränderungen in der Westantarktis besser verstehen zu können. Dies wird zusätzlich unterstützt durch das Testen der wissenschaftlichen Hypothesen über die Ursachen der Veränderungen mittels spezifischer, isotopengetriebener globaler Zirkulationsmodelle, sowie chemischer Transportmodelle atmosphärischer Spurenstoffe. Dieses Projekt wird somit einen wichtigen Beitrag zum Verständnis der westantarktischen Klimasystems in der Vergangenheit und Zukunft leisten.

Brackish water rewetting of a temperate coastal peatland in NE Germany: Effects on Biogeochemistry, Microorganisms and Greenhouse gas emissions

The rewetting of drained peatlands is a promising measure to mitigate carbon dioxide (CO2) emissions by preventing the further mineralization of the peat soil through aeration. While freshwater rewetted peatlands can be significant methane (CH4) sources in the short-term, in coastal ecosystems the input of sulfate-rich seawater could potentially mitigate these emissions. The purpose of the data collection was to examine whether the presence of sulfate, known as an alternative electron acceptor, can cause lower CH4 production and thus, emissions by favoring the growth of sulfate-reducers, which outcompete methanogens for substrate. We therefore investigated underlying variables such as the methane-cycling microbial community along with CH4 fluxes and set them in context with CO2 fluxes along a transect in a coastal peatland before and directly after rewetting. In this way, a conclusion about the short-term greenhouse gas mitigation potential of brackish water rewetting of coastal peatlands could be drawn. This data collection consists of six data sets, with direct comparisons before and after rewetting of CO2 and CH4 fluxes (Tab. 2) and associated microbial communities (Tab. 1) being the main data. Pore water geochemistry (Tab. 1 and 3) and surface water parameters (Tab. 4) were collected simultaneously to provide potential explanatory variables. The sampling of continuous water level (Tab. 5) within wells and atmospheric weather data (air and soil temperature, relative humidity, photosynthetic photon flux density; Tab. 6) from a weather station was done in addition. Measurements started in June/July/August 2019 after field installation was finalized and were conducted on the drained coastal fen "Polder Drammendorf" on the island of Rügen in North-East Germany. On 26th November 2019, the dike was opened and channeled in order to rewet the peatland with brackish water. Before, the dike separated the peatland from the adjacent bay "Kubitzer Bodden", which is part of a brackish lagoon system connected to the Baltic Sea. Therefore, the peatland was nearly completely flooded and now resembles a shallow lagoon with high fluctuating water levels. We measured along a humidity (pre-rewetting)/water level (post-rewetting) gradient (stations 0-8) towards and across the main North-South oriented drainage ditch, including four stations on the Eastern side of the ditch (1–4), two ditch stations (0, 5) and two stations (6, 7) on the Western side of the ditch. Station 8 was chosen as an additional station farther towards the adjacent bay on the Western side, but was only accessible before rewetting. CH4 and CO2 fluxes (stations 0-7) were calculated from online gas concentrations measurements using laser-based analyzers and manual closed chambers (Livingston, G. P., & Hutchinson, G. (1995). Enclosure-based measurement of trace gas exchange: Applications and sources of error. In P.A. Matson, & R.C. Harriss (Eds.). Biogenic trace gases: Measuring emissions from soil and water (pp. 14–51). Blackwell Science Ltd., Oxford, UK). Soil cores for microbial, dissolved gas concentrations and isotopic analysis were taken using a Russian type peat corer (De Vleeschouwer, F., Chambers, F. M., & Swindles, G. T. (2010). Coring and sub-sampling of peatlands for palaeoenvironmental research. Mires and Peat, 7, 1–10) before and after rewetting. Each time, we took duplicates at stations 1-8 for this rather labor-intensive process and divided the core into four depth sections: surface, 5–20, 20–40 and 40–50 cm. Subsamples for dissolved gases and stable carbon isotope analyses were taken with tip-cut syringes with a distinct volume of 3 ml (Omnifix, Braun, Bad Arolsen, Germany) and immediately placed into NaCl-saturated vials (20 ml, Agilent Technologies, 5182-0837, Santa Clara, USA) leaving no headspace and closed gas-tight using rubber stoppers and metal crimpers (both: diameter 20 mm, Glasgerätebau Ochs, Bovenden, Germany). Absolute abundances of specific functional target genes, including methane- and sulfate-cycling microorganisms, were measured with quantitative PCR (qPCR) after DNA was extracted (GeneMATRIX Soil DNA Purification Kit, Roboklon, Berlin, Germany) and quantified (Qubit 2.0 Fluorometer, ThermoFisher Scientific, Darmstadt, Germany). Surface and pore water parameters were measured in parallel to the gas measurements and soil coring for microbial analyses. Most surface water variables (pH, specific conductivity, salinity, nutrients, oxygen, sulfate and chloride concentrations, DOC/DIC) were measured in-situ using a multiparameter digital water quality meter or taken to the laboratory as water samples for further analysis. Likewise, pore water/soil variables (pH, specific conductivity, nutrients, metals, sulfate and chloride concentrations, CNS) were either measured in-situ or taken to the laboratory as soil samples. While surface water analysis was only conducted in the drainage ditch before rewetting, it was done along the entire transect after rewetting. In contrast, pore water/soil analysis was mostly conducted before rewetting and only repeated occasionally after rewetting where possible.

Water isotope time series (March 2020 - March 2021) of samples collected at A. P. Møller Skolen, Kleine Breite, Schlei

Time series of stable isotopes (δ2H and δ18O) were analyzed in water samples collected near the A. P. Møller Skolen, Schleswig (Kleine Breite, Schlei), in biweekly to monthly intervals between March 2020 and March 2021. Water was sampled with a pipette from ca. 0.5 m below water surface and directly transferred into a measurement vial. Isotope analysis was conducted at IGB Berlin, using a Picarro L2130-i cavity ring-down spectrometer. Water chemical parameters were measured in-situ with a modular WTW 3440 multiparameter devices and regularly calibrated conductivity cells (MPP 930 IDS, TetraCon® 925-P). The data give information about the seasonal isotope amplitude at the sampled locations and about spatial variability along the transects.

Seasonal water isotope values in eastern German lakes and rivers (Spree, Dahme, Elster and Mulde systems) in March, July, October 2022, and March 2023

Water isotopes (δ²H and δ¹⁸O) were analyzed in samples from lakes and rivers in eastern Germany. This sub-dataset is derived from water samples collected from lake and river shores. Seasonal samples were collected in March, July, October 2022, and in March 2023, with a plastic syringe from 20-50 cm depth below water surface and directly filtered and transferred into a measurement vial. Stable isotope analysis was conducted at IGB Berlin, using a Picarro L2130-i cavity ring-down spectrometer. Measurement uncertainty was quantified to <0.5 ‰ for δ²H and <0.2 ‰ for δ¹⁸O. Water chemical parameters were determined in-situ with a portable WTW-multiparameter probe. The data give information about the seasonal isotope amplitude at the sampled spots and about spatial isotope variability in different branches of the associated river systems.

Water isotope time series (March 2020 - March 2021) of samples collected in Kloster, Hiddensee

Time series of stable isotopes (δ2H and δ18O) were analyzed in water samples taken near the harbour of Kloster (Hiddensee), in biweekly to monthly intervals between March 2020 and March 2021. Water was sampled with a pipette from ca. 0.5 m below water surface and directly transferred into a measurement vial. Isotope analysis was conducted at IGB Berlin, using a Picarro L2130-i cavity ring-down spectrometer. Water chemical parameters were measured in-situ with WTW multiparameter measurement devices. The data give information about the seasonal isotope amplitude at the sampled locations and about spatial variability along the transects.

Water isotope time series (March 2020 - March 2021) of samples collected along the Zingster Bodden chain

Time series of stable isotopes (δ2H and δ18O) were analyzed in water samples collected at the Zingster Bodden chain in biweekly to monthly intervals between March 2020 and March 2021. Herefore, a Limnos sampler was used to obtain water from 0.5 to 1 m below surface. In the laboratory, a WTW 1970i conductivity meter and TetraCon 325 measuring cell were used to analyse electrical conductivity. Sub-samples were transferred into measurement vials before isotope analysis was conducted at IGB Berlin, using a Picarro L2130-i cavity ring-down spectrometer. Water chemical parameters were measured with regularly calibrated WTW multiparameter devices. The data give information about the seasonal isotope amplitude at the sampled locations and about spatial variability along the transects.

Water isotope values in shore samples collected in March and July 2020 from northeastern German lake systems

Water isotopes (δ2H and δ18O) were analyzed in samples collected in lakes associated to major riverine systems in northeastern Germany throughout 2020. This sub-dataset is derived from water samples collected from lake shores. Samples were taken in March and July 2020 with a pipette from 40-60 cm depth below water surface and directly transferred into a measurement vial. Stable isotope analysis was conducted at IGB Berlin, using a Picarro L2130-i cavity ring-down spectrometer. The data give information about the seasonal isotope amplitude in the sampled lakes and about spatial isotope variability in different branches of the associated riverine systems.

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