Das Projekt "Steady-State Dilution and Mixing-Controlled Reactions in Three-Dimensional Heterogeneous Porous" wird vom Umweltbundesamt gefördert und von Eberhard Karls Universität Tübingen, Zentrum für Angewandte Geowissenschaften (ZAG), Arbeitsgruppe Hydrogeology durchgeführt. Understanding transport of contaminants is fundamental for the management of groundwater re-sources and the implementation of remedial strategies. In particular, mixing processes in saturated porous media play a pivotal role in determining the fate and transport of chemicals released in the subsurface. In fact, many abiotic and biological reactions in contaminated aquifers are limited by the availability of reaction partners. Under steady-state flow and transport conditions, dissolved reactants come into contact only through transverse mixing. In homogeneous porous media, transverse mixing is determined by diffusion and pore-scale dispersion, while in heterogeneous formations these local mixing processes are enhanced. Recent studies investigated the enhancement of transverse mixing due to the presence of heterogeneities in two-dimensional systems. Here, mixing enhancement can solely be attributed to flow focusing within high-permeability inclusions. In the proposed work, we will investigate mixing processes in three dimensions using high-resolution laboratory bench-scale experiments and advanced modeling techniques. The objective of the proposed research is to quantitatively assess how 3-D heterogeneity and anisotropy of hydraulic conductivity affect mixing processes via (i) flow focusing and de-focusing, (ii) increase of the plume surface, (iii) twisting and intertwining of streamlines and (iv) compound-specific diffusive/dispersive properties of the solute species undergoing transport. The results of the experimental and modeling investigation will allow us to identify effective large-scale parameters useful for a correct description of conservative and reactive mixing at field scales allowing to explain discrepancies between field observations, bench-scale experiments and current stochastic theory.
Das Projekt "B 2.3: Transport of agrochemicals in a watershed in Northern Thailand - Phase 3" wird vom Umweltbundesamt gefördert und von Universität Hohenheim, Institut für Bodenkunde und Standortslehre, Fachgebiet Biogeophysik durchgeführt. Land use changes of the last decades in the mountainous regions of Northern Thailand have been accompanied by an increased input of agrochemicals, which might be transferred to rivers by surface and/or subsurface flow. Where the river water is used for household consumption, irrigation and other purposes, agrochemical losses pose a serious risk to the environment and food safety. In the first and the second phase, subproject B2 collected data on and gained knowledge of the vertical and lateral transport processes that govern the environmental fate of selected agrochemicals at the plot and the hillslope scale (Ciglasch et al., 2005; Kahl et al., 2006). In the third phase, B2.3 will turn from the hillslope to the watershed scale. For simulation of water flow and pesticide transport the SWAT model (Neitsch et al., 2002b) will be adapted and used. The study area will be the Mae Sa watershed (138 km2), which includes the Mae Sa Noi subcatchment where B2 carried out detailed investigations during the last two phases. The specific focus of the subproject will be the parameterization and calibration of the SWAT model and its integration into the model network of the SFB. The SFB database has been established and can be used for model parameterization. In addition, high-quality geo-data are available from the Geoinformatic and Space Technology Development Agency (GISTDA) in Chiang Mai. For model calibration, discharge measurements are available for the Mae Sa Noi subcatchment (12 km2) and for the neighboring Mae Nai subcatchment (18 km2). To collect data on the Mae Sa watershed discharge, at the very beginning of the third phase gauging stations will be established in a midstream position and at the outlet of the watershed. Pesticide fluxes will be measured at each gauging station as well as in the Mae Sa Noi subcatchment, where B2.2 has operated two flumes equipped with automatic discharge-proportional water samplers since 2004. Rainfall distribution and intensity will be monitored with a net of automatic rain gauges. Hydrograph separation will be performed using soil and river temperatures (Kobayashi et al., 1999). Within the watershed temperature loggers will be installed at different soil depths to measure the temperature of the different discharge components. Already at the beginning of the second year of the third phase we will start to couple the SWAT model with land use and farm household models of the SFB and to use the model to assess the effect of land use and land management changes on the loss of pesticides to surface waters.
Das Projekt "Towards a Guideline for Digital Soil Mapping in Ecuador" wird vom Umweltbundesamt gefördert und von Universität Bayreuth, Abteilung Bodenphysik durchgeführt. Research experience in digital soil mapping (DSM) shall be extended and deepened in two further research areas in order to develop a guideline for DSM in Ecuador. The guideline will give an overview: a) about the DSM approach, b) the different sampling designs developed according to the area size, accessibility and terrain complexity, c) the various methods from the field of supervised machine learning to develop digital soil maps, and d) the implementation with open source software. The soil-landscapes of the three investigation areas will be analysed and soil-landscape models will be developed by supervised machine learning techniques, in order to spatially predict soil properties from point data based on environmental prediction parameters. By using the so developed digital soil maps as principal input, a functional soil-landscape analysis is carried out to determine landslide, erosion and anthropogenic disturbance risk zones as well as estimate the soil organic carbon stocks and soil fertility.
Das Projekt "WiSSCy: Impact of Wind, Rain, and Surface Slicks on Air-Sea CO2 Transfer Velocity - Tank Experiments" wird vom Umweltbundesamt gefördert und von Universität Hamburg, Zentrum für Meeres- und Klimaforschung, Institut für Meereskunde (IfM) durchgeführt. The goal is to improve the understanding of the parameterization of air-sea gas exchange with emphasis on CO2. This is being done using the linear wind-wave tank facility of the University of Hamburg. Using this facility, gas exchange coefficients are inferred by measuring gas transfer under a wide variety of parameters such as wind, mechanically generated waves, rain, and surface films. Our emphasis is on the physical processes involved in the air-sea gas exchange and its quantitative measurement. Experiments are conducted with freshwater and with salt water to test the influence of salinity on the gas exchange parameters. All experiments are being performed for evasion and invasion to investigate if rain-induced gas transfer is symmetrical or asymmetrical. While these experiments do not address in great detail the small-scale processes that are involved in the transfer, they allow to determine parameterizations of the gas exchange as a function of parameters of the atmospheric boundary layers as they are needed in climate models and for the analysis of satellite data.
Das Projekt "Soil N dynamics as affected by different land use in Western and Southern China" wird vom Umweltbundesamt gefördert und von Technische Universität Dresden, Institut für Bodenkunde und Standortslehre durchgeführt. The aim of the research project is to quantify the stocks and turnover of soil nitrogen in Western and Southern China as dependent from soil structure and land use. Key soil characteristics are determined at representative sites with regional specific land use and degradation status. The investigations will follow a land use gradient of natural forests, arable and pasture soils, the latter ones considering different degradation and rehabilitation status. The actual and potential soil nitrogen turnover will be horizon-wise quantified and related to soil structure and land use impacts. Beside mineral nitrogen, also preliminary organic N compounds using physical and chemical extraction will be detected. Parameters for the investigations are, beside total C and N stocks and distribution, gross and net N mineralization, nitrification, microbial biomass C and N and microbial respiration and indicators for soil N turnover like active N pools and light fraction of organic matter. In the last phase the structure of the soil microbial microbial community will be determined and related to indicators of nitrogen status and efficiency. The research activities will be carried out in close co-operation with the Institute for Soil and Water Conservation/ Yangling University at loess soils and the Nanjing Institute for Soil Science/ Chinese Academy for Science in Nanjing at red soil sites.
Das Projekt "Biomass Fuell Cell Utility System (BIOCELLUS)" wird vom Umweltbundesamt gefördert und von Technische Universität München, TUM School of Engineering and Design, Fakultät für Maschinenwesen, Lehrstuhl für Energiesysteme durchgeführt. Objective: Energy from Biomass needs highly efficient small-scale energy systems in order to achieve cost effective solutions for decentralized generation especially in Mediterranean and Southern areas, and for applications without adequate heat consumer. Thus fuel cells are an attractive option for decentralized generation from biomass and agricultural residues but they have to meet at least two outstanding challenges: 1. Fuel cell materials and the gas cleaning technologies have to treat high dust loads of the fuel gas and pollutants like tars, alkalines and heavy metals. 2. The system integration has to allow efficiencies of at least 40-50 percent even within a power range of few tens or hundreds of kW. This proposal addresses in particular these two aims. Hence the first part of the project will focus on the investigation of the impact of these pollutants on degradation and performance characteristics of SOFC fuel cells in order to specify the requirements for appropriate gas cleaning system (WP 1-2). These tests will be performed at six existing gasification sites, which represent the most common and applicable gasification technologies. WP 3 will finally test and demonstrate the selected gas cleaning technologies in order to verify the specifications obtained from the gasification tests. The results will be used for the development, installation and testing of an innovative SOFC - Gasification concept, which will especially match the particular requirements of fuel cell systems for the conversion of biomass feedstock. The innovative concept comprises to heat an allothermal gasifier with the exhaust heat of the fuel cell by means of liquid metal heat pipes. Internal cooling of the stack and the recirculation of waste heat increases the system efficiency significantly. This so-called TopCycle concept promises electrical efficiencies of above 50 percent even for small-scale systems without any combined processes.
Das Projekt "B 1.2: Efficient water use in limestone areas - Phase 2" wird vom Umweltbundesamt gefördert und von Universität Hohenheim, Institut für Bodenkunde und Standortslehre durchgeführt. The elevated areas of Northern Thailand highlands are inhabited by ethnic minorities. On the other hand, the Thai majority prefers the valley bottoms. Population growth of all groups, reforestation and commercialisation of agriculture lead to an increasing pressure on land and water resources. Therefore, intensified land and water use systems are desired which are resource conserving at the same time. Here, special problem areas are the karstic limestone catchments due to the limited of surface waters.Own pre-investigations together with subproject A1 have shown, that land use systems there are subsistence oriented and local farmers do not use irrigation. But they would like to develop such technology, especially in order to increase staple crop production (highland rice, maize). But lack of irrigation possibilities is also responsible for the lack of diversification of land use systems with respect to orchards. One possibility to increase staple crop yields is to prolong the vegetation period by use of water harvesting technologies. Aim of this project is to develop such low cost water harvesting technologies (together with subproject B3.1) based on a participatory approach and to model the effect of these on the water balance at the catchments scale. This will be done on the basis of the previous variability studies and should lead to model tools, which allow to evaluate ex ante SFB innovation effects on the water balance. The project area is the Bor Krai catchments. Here, weirs will be installed to quantify surface water availability. An investigation plot will be situated near the village of Bor Krai which serves for water balance measurements (TDR/densitometry) and at the same time as demonstration plot for the local community. Here water harvesting by means of filling the soils field capacity at the end of the rainy season by gravity irrigation in order to prolong the vegetation period will be researched. Through cropping of participatory evaluated varieties the crop yield should be increased. The water consumption of traditionally managed and dominant crops (including orchards) will be measured at three further sites in the catchment (TDR, tensiometer). The water balance of the soil cover in the karst catchment will be based on the coupling of a SOTER map with a water transport model. The data base will be completed by soil type mapping, spatially randomised collection of soil physical properties (texture, bulk density, infiltration, water retention curve) and determination of the ku-function at two representative sites. As project results the available water amount for irrigation purposes will be quantified. The effective use of this water reserve will lead to increased productivity of the dominant crops and limitations to orchard productivity will be reduced. (abridged text)
Das Projekt "Soil aeration - the key factor of oak decline in Southwest Germany?" wird vom Umweltbundesamt gefördert und von Universität Freiburg, Institut für Geo- und Umweltnaturwissenschaften, Professur für Bodenökologie durchgeführt. Many research efforts to identify the key factors of oak decline in Europe conclude that it is a 'complex disease'. This result can hardly be falsified because of its fuzziness. A significant contribution of pathogene fungi is not without controversy, because the primary pathogenicity is not proven (Johnsson, 2004). Our starting point is the resarch of Gaertig et al. (2002) who found that on a spatial integration level of 28 oak stands in Baden-Wuerttemberg the symptoms of oak health are significantly correlated with soil aeration. Large-scale changes of soil structure in oak stands during the last decades can be attributed to the mechanization of logging (Vossbrink and Horn, 2004) as well as to a decrease of earthworm activity in acidified soils. In the proposed project we want to establish a relationship between roots and aeration-relevant parameters in a three-dimensional space. This laborious procedure is necessary because the soil-air access is highly heterogeneous and by this way forms a three-dimensional pattern. This makes one-dimensional models unefficient. By modelling the soil air access in a three-dimensional space we want to test the aeration hypothesis. Important indicators of rooting are clustering of fine roots, necrosis, or space discrimination. By assessing simultaneously soil-chemical and soil-physical parameters in the same spatial resolution, alternative hypotheses can be tested. As modelling tools point statistics, non parametric regression (GAM), and a three dimensional solution of the instationary gas-diffusion equation will be used.
Das Projekt "AURORa - Investigation of the Radar Backscatter of Rain Impinging on the Ocean Surface" wird vom Umweltbundesamt gefördert und von Universität Hamburg, Zentrum für Meeres- und Klimaforschung, Institut für Meereskunde (IfM) durchgeführt. Over land, observations of rain rates are more or less operational. To obtain information about precipitation at the coastal zones, weather radars are used. However, over the oceans, especially away from the main shipping routes, no direct precipitation measurements are performed. In these regions, satellite data can provide information about precipitation events. Satellites deploying passive and active microwave sensors can operate independently of cloud cover and time of day. Passive microwave sensors give crude estimates of rain rates over large areas but cannot resolve small-scale rain events of short duration as are often observed in the tropics, for example. Active microwave sensors with high resolutions, such as synthetic aperture radars can provide more reliable information. Though the effect of rain on the atmosphere is a very topical area of research, the radar backscattering mechanisms at the water surface during rain events combined with wind are still not well understood. The purpose of this project is to investigate the radar backscattering from the water surface in the presence of rain and wind in order to interpret satellite radar data produced by active microwave sensors. Furthermore, the results should be embedded into models of the radar backscattering from the water surface to allow for estimating rain rates by using satellite data. Research topics: Rain impinging on a water surfaces generates splash products including crowns, cavities, stalks and secondary drops, which do not propagate, and ring waves and subsurface turbulence. We are investigating this phenomena at the wind-wave tank of the University of Hamburg. The tank is fitted with an artificial rain simulator of 2.3 m2 area mounted 4.5 m over the water surface. Rain drops of 2.1 and 2.9 mm in diameter with rain rates up to 100 mm/h have been produced. Wind with speeds 10 m/s and monomolecular slicks act on the water surface. The influence of the rain on the water surface is measured with a resistance type wire gauge, a two dimensional laser slope gauge and an coherent 9.8 GHz (x band) continuous wave scatterometer operating at VV-, HH- and HV-polarization. The influence of rain below the water surface is measured with colored raindrops which are observed with a video camera to investigate the turbulent motion and the depth of the mixed layer. At the North Sea Port of Buesum in Germany, a scatterometer operating at all polarizations and five frequencies will be mounted during summer of this year. The radar backscatter of the sea surface during rain events will be measured in combination with meteorological observations. With help of these measurements, existing radar backscatter models of the water surface will be improved for the presence of rain events. To validate the improved models, ERS-2 SAR-images will be compared with weather radar data.
Das Projekt "Improvement of oil palm wood by bio resin application" wird vom Umweltbundesamt gefördert und von Technische Universität Dresden, Fachrichtung Forstwissenschaften, Institut für Forstnutzung und Forsttechnik, Professur für Forstnutzung durchgeführt. Reinforcement of oil palm wood by using Bioresin to improve its physical, mechanical and machinery properties. Concerning the utilization of oil palm wood, which is available in large number throughout the year, especially when the mature plants has reached its economic life span (approx. 25 years). Normally, this mature plant should be replanting. According to the projection of oil palm plantation development in Indonesia, there are more than 16 million cubic meter of this bulky material starting 2010. This large amount of biomass, if no real effort, will become a serious problem. Unfortunately, the current replanting method (push-felled) sounds risky and in several companies follow by burning method, which is really not solve problem, but creating the other serious problem, such as air pollution. The oil palm wood characteristics as a monocotyledons species is naturally quite different compare to the common wood (dicotyledonous). Originally the oil palm tree has various densities along the trunk and its density decreased linearly with trunk height and towards the centre of the trunk. Green oil palm trunk is also very susceptible to fungal and insect attack due to the high sugar and starch content. Hence, the utilization of this material is not fully utilized yet and still poses a serious environmental problem. Yet, compared to the various intensive researches and the economically important of the oil palm, processing technology and diversification of palm oil based products mainly from CPO and PKO, the oil palm solid waste, particularly the oil palm wood, has received relatively little research attention. This might be due to lack or insufficient the scientific information and Know-How of this material and might be also due to the difficulties of using with the OPT. Although several investigations have already conducted in the field of OPT, but a sufficient knowledge shall be achieved in order to design and establish the new tailor-made wood products based on oil palm wood. Hence, this study was directed to focus the characteristics of OPT including anatomical, physical, mechanical and machinery properties, and in order to use the OPT for structural purposes, the wood properties of OPT were improved and reinforced with Bioresin through the development of wood modification techniques.
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