Shallow groundwater of the huge deltaic systems of Asia like the Red River Delta in Vietnam is often enriched in inorganic arsenic (As), threatening the health of millions of residents. The massive abstraction of groundwater in these areas locally causes an irreversible mixing of arsenic-free groundwater resources with arsenic-rich groundwater. Increased concentrations of competitive anions, especially phosphate (PO43-), decrease the immobilization capacity of the sediments. During transport, the mobility of dissolved As in local aquifers is strongly influenced by adsorption to sedimentary and ubiquitously occurring iron(oxyhydr)oxides. Additionally, arsenic-rich groundwater is often enriched in reduced iron (Fe2+) as well, which is capable to react with iron(oxyhydr)oxides, thereby inducing mineral transformations. Such transformations permanently affect the arsenic adsorption and immobilization capacity of the sediments.Within the scope of this research project, the underlying mechanisms related to As transport and the resulting threat to arsenic-free groundwater resources will be characterized in cooperation with the Swiss Federal Institute of Aquatic Science and Technology (Eawag). The research concept aims at assessing the complex interactions within the arsenic-iron-phosphate-system under field conditions at a study site next to the Red River. First, filtration experiments using local groundwater enriched in As and PO43- will be used to determine the As adsorption capacity of different and previously geochemically characterized iron(oxyhydr)oxides. In a second step, sample carrier containing As loaded iron(oxyhydr)oxides will be introduced into surface near aquifer parts of the study site (via existing groundwater monitoring wells). These samples will be exposed to local groundwater characterized by increased As, Fe2+ and PO43- concentrations for the following nine months. Using the in situ exposition of predefined iron(oxyhydr)oxides, it will be possible to distinguish potential mineral transformations and their influences on the As immobilization capacity of the respective iron(oxyhydr)oxides. By combining the results and outcomes of the field experiments, new and important conclusions regarding the mobility of As can be drawn. The data can be used to create a hydrochemical transport model describing reactive As transport within the investigation area. In addition, the results of the in situ exposition experiments will allow to draw conclusions in respective to the long term As immobilization capacity of different iron(oxyhydr)oxides, which is an essential information regarding in situ decontamination techniques.
Der asiatische Sommermonsun ist charakterisiert durch hohe Konvektion über Südasien, die mit der asiatischen Monsun-Antizyklone (AMA) zusammenhängt, der sich von der oberen Troposphäre bis in die untere Stratosphäre (UTLS) erstreckt. Diese Antizyclone ist das ausgeprägteste Zirkulationsmuster in diesen Höhen während des borealen Sommer. Es ist bekannt, dass der Export von Monsunluft quasi-isentropisch aus der AMA sowohl im Osten als auch im Westen, einen großen Einfluss auf die Zusammensetzung der außertropischen unteren Stratosphäre hat. Jedoch sind die relative Stärken der beiden Wege bisher unbekannt. Der Transport von Luftmassen aus der AMA in die nördliche außertropische UTLS wirkt sich entscheidend auf die Chemie der Stratosphäre und ihrenStrahlungshaushalt (z.B. durch Transport von H2O, Aerosol oder ozonschädigende Stoffe) aus. Im Rahmen dieses Projekts AirExam wird der quasi-isentropischer Luftmassenexport aus der AMA durch verschiedene Wegen und seine Auswirkungen auf Chemie und Strahlung der außertropische UTLS quantifiziert durch u.a. HALO-Flugzeugmessungen (insbesondere aus die für Sommer 2023 geplanten PHILEAS-Kampagne), Simulationen mit dem Chemischen Transportmodell CLaMS und Strahlungsberechnungen. Unser Projekt AirExam wird sich mit den folgenden offenen Schlüsselfragen befassen:1) Welchen relativen Beitrag leisten die beiden quasi-horizontalen Transportwege (nach Westen und Osten) aus dem asiatischen Monsun-Antizyklon zur Zusammensetzung der außertropischen unteren Stratosphäre?2) Wie groß ist die jährliche Variabilität des Transports aus der asiatischen Monsun-Antizyklone in die außertropische untere Stratosphäre und was sind die Hauptquellenregionen auf der Erde Oberfläche?3) Was ist die Auswirkung des Wasserdampftransports aus der asiatischen Monsun-Antizyklone zum H2O-Budget der außertropischen UTLS und seine Strahlungswirkung?In unserem Projekt werden wir HALO-Messungen (insbesondere H2O) mit globalen 3-dimensionalen CLaMS-Simulationen kombinieren, die von neuen hochaufgelösten ERA-5-Reanalyse des ECMWF angetrieben werden. CLaMS-Simulationen auf der Grundlage von ERA-5 sind ein neues Instrument zur zuverlässigen Beschreibung von Transportprozessen in der Region des asiatischen Monsuns und seiner globalen Auswirkungen. Die Strahlungswirkung des durch den asiatischen Monsun verursachten H2O-Anstiegs im Sommer und Herbst wird mit Hilfe des Strahlungs-Transfercodes Edwards und Slingo berechnet. H2O ist das wichtigste Treibhausgas, und die Befeuchtung der Stratosphäre ist eine wichtige Triebkraft des Klimawandels. Unser Projekt AirExam wird die Auswirkungen des verstärkten H2O-Transports in die untere Stratosphäre quantifizieren und kann daher dazu beitragen, die potenziellen Risiken des Luftmassentransports aus der asiatischen Monsunregion auf die globale Stratosphäre zu bewerten.
Outbreaks of foodborne illness linked to consumptions of fresh, or partially processed, agricultural products are a growing concern in industrialized and developing countries. The incidence of human pathogens on fresh fruits and vegetables is often related to the use of recycled wastewaster in surface irrigation as well as high amounts of animal manure in agricultural management practice. Thereby the soil inhabiting fauna plays an important role in the transport and dissemination of microorganisms. The focus of the proposed project is on nematodes, well known vectors for bacteria and viruses in soil. The major goals are to: (1) survey human pathogens in soil and on/in free-living and plant parasitic nematodes in agriculture field sites irrigated with recycled wastewater or fertilized with fresh animal manure in Israel and the Palestinian Authority, (2) assess the function of nematodes as vectors in transmitting bacteria from microbial hot spots to plants, and (3) localize bacteria on and/or within the nematode and identify bacterial factors required for survival in the nematode host. Understanding the mechanisms involved in dissemination of human pathogens by nematodes will enhance the ability to develop practical means to minimize contamination of fresh produce and increase safety in food production.
Methane (CH4) is a major greenhouse gas of which the atmospheric concentration has more than doubled since pre-industrial times. Soils can act as both, source and sink for atmospheric CH4, while upland forest soils generally act as CH4 consumers. Oxidation rates depend on factors influenced by the climate like soil temperature and soil moisture but also on soil properties like soil structure, texture and chemical properties. Many of these parameters directly influence soil aeration. CH4 oxidation in soils seems to be controlled by the supply with atmospheric CH4, and thus soil aeration is a key factor. We aim to investigate the importance of soil-gas transport-processes for CH4 oxidation in forest soils from the variability the intra-site level, down to small-scale (0.1 m), using new approaches of field measurements. Further we will investigate the temporal evolution of soil CH4 consumption and the influence of environmental factors during the season. Based on previous results, we hypothesize that turbulence-driven pressure-pumping modifies the transport of CH4 into the soil, and thus, also CH4 consumption. To improve the understanding of horizontal patterns of CH4 oxidation we want to integrate the vertical dimension on the different scales using an enhanced gradient flux method. To overcome the constraints of the classical gradient method we will apply gas-diffusivity measurements in-situ using tracer gases and Finite-Element-Modeling. Similar to the geophysical technique of Electrical Resistivity Tomography we want to develop a Gas Diffusivity Tomography. This will allow to derive the three-dimensional distribution of soil gas diffusivity and methane oxidation.
In this project we experimentally explore the transport of engineered inorganic nanoparticles (EINP) through soils. This is done for original EINPs and some pre-aged form. Transport of NPs in soil is expected to be different from that of reactive solutes, in that hydrodynamic drag, inertial and shear forces as well as the affinity to water-gas interfaces are expected to be more relevant. Hence, the mobility of EINPs in soil is highly sensitive to the morphology of the porous structure and the dynamics of water saturation.This project provides the pore network structure for natural soils using X-ray micro-tomography to allow for an up-scaling of pore-scale interactions explored by project partners to the scale of soil horizons. The pore structure is represented by a network model suitable for pore scale simulations including the dynamics of water-gas interfaces.Pore network simulations will be compared to column experiments for conservative tracers as well as for unaltered and pre-aged EINPs (obtained from INTERFACE). This includes steady state flow scenarios for saturated (ponding) and unsaturated conditions as well as for transient flow to explore the impact of moving water-gas interfaces. The final goal is to arrive at a consistent interpretation of experimental findings and numerical simulations to develop a module for modelling EINP transfer through soil as a function of particle properties, soil structural characteristics and external forcing in terms of flux boundary conditions.
Labor- und Feldstudien zeigen, dass die Oberflächengrenzschicht des Ozeans (â€Ìsurface microlayerâ€Ì, kurz SML) die biogeochemischen Kreisläufe von klimaaktiven und atmosphärisch wichtigen Spurengasen wie Kohlenstoffdioxid (CO2), Kohlenstoffmonoxid (CO), Methan (CH4), Lachgas (N2O) und Dimethylsulfid (DMS) stark beeinflusst: (i) Jüngste Studien aus den PASSME- und SOPRAN-Projekten haben hervorgehoben, dass Anreicherungen von oberflächenaktiven Substanzen (d.h. Tensiden) einen starken (dämpfenden) Effekt sowohl auf die CO2- als auch auf die N2O-Flüsse über die SML/Atmosphären-Grenzfläche hinweg haben und (ii) Spurengase können durch (mikro)biologische oder (photo)chemische Prozesse in der SML produziert und verbraucht werden. Daher kann der oberste Teil des Ozeans, einschließlich der SML, verglichen mit dem Wasser, das in der Mischungsschicht unterhalb der SML zu finden ist, eine bedeutende Quelle oder Senke für diese Gase sein, was von sehr großer Relevanz für die Forschungseinheit BASS ist. Die Konzentrationen von CO2, N2O und anderen gelösten Gasen in der SML (oder den oberen Zentimetern des Ozeans) unterscheiden sich nachweislich von ihren Konzentrationen unterhalb der SML. Typischerweise werden die Nettoquellen und -senken wichtiger atmosphärischer Spurengase mit Konzentrationen berechnet, die in der Mischungsschicht gemessen wurden und mit Gasaustauschgeschwindigkeiten, die die SML nicht berücksichtigen. Diese Diskrepanzen führen zu falsch berechneten Austauschflüssen, die in der Folge zu großen Unsicherheiten in den Berechnungen der Klima-Antrieben und der Luftqualität in Erdsystemmodellen führen können. Durch die Verknüpfung unserer Spurengasmessungen mit Messungen von (i) der Dynamik und den molekularen Eigenschaften der organischen Materie und speziell des organischen Kohlenstoffs (SP1.1; SP1.5), (ii) der biologischen Diversität und der Stoffwechselaktivität (SP1.2), (iii) den optischen Eigenschaften der organischen Materie (SP1.3), (iv) der photochemischen Umwandlung der organischen Materie (SP1.4) und (v) den physikalischen Transportprozessen (SP2.3) werden wir ein umfassendes Verständnis darüber erlangen, wie die SML die Variabilität der Spurengasflüsse beeinflusst.
Agriculture is the major contributor of nitrogen to ecosystems, both by organic and inorganic fertilizers. Percolation of nitrate to groundwater and further transport to surface waters is assumed to be one of the major pathways in the fate of this nitrogen. The quantification of groundwater and associated nitrate flux to streams is still challenging. In particular because we lack understanding of the spatial distribution and temporal variability of groundwater and associated NO3- fluxes. In this preliminary study we will focus on the identification and quantification of groundwater and associated nitrate fluxes by combining high resolution distributed fiber-optic temperature sensing (DTS) with in situ UV photometry (ProPS). DTS is a new technique that is capable to measure temperature over distances of km with a spatial resolution of ca1 m and an accuracy of 0.01 K. It has been applied successfully to identify and quantify sources of groundwater discharge to streams. ProPS is a submersible UV process photometer, which uses high precision spectral analyses to provide single substance concentrations, in our case NO3-, at minute intervals and a detection limit of less than 0.05 mg l-1 (ca.0.01 mg NO3--Nl-1). We will conduct field experiments using artificial point sources of lateral inflow to test DTS and ProPS based quantification approaches and estimate their uncertainty. The selected study area is the Schwingbach catchment in Hessen, Germany, which has a good monitoring infrastructure. Preliminary research on hydrological fluxes and field observations indicate that the catchment favors the intended study.
Sediment erosion and transport is critical to the ecological and commercial health of aquatic habitats from watershed to sea. There is now a consensus that microorganisms inhabiting the system mediate the erosive response of natural sediments ('ecosystem engineers') along with physicochemical properties. The biological mechanism is through secretion of a microbial organic glue (EPS: extracellular polymeric substances) that enhances binding forces between sediment grains to impact sediment stability and post-entrainment flocculation. The proposed work will elucidate the functional capability of heterotrophic bacteria, cyanobacteria and eukaryotic microalgae for mediating freshwater sediments to influence sediment erosion and transport. The potential and relevance of natural biofilms to provide this important 'ecosystem service' will be investigated for different niches in a freshwater habitat. Thereby, variations of the EPS 'quality' and 'quantity' to influence cohesion within sediments and flocs will be related to shifts in biofilm composition, sediment characteristics (e.g. organic background) and varying abiotic conditions (e.g. light, hydrodynamic regime) in the water body. Thus, the proposed interdisciplinary work will contribute to a conceptual understanding of microbial sediment engineering that represents an important ecosystem function in freshwater habitats. The research has wide implications for the water framework directive and sediment management strategies.
The 'hydraulic activation of stomata' (HAS) describes the establishment of continuous liquid water connections along stomatal walls, which affects individual stomata. It enables the efficient bidirectional transport of water, solutes, and hydraulic signals between the leaf interior and leaf surface and makes stomatal transpiration partly independent of stomatal aperture. While in our earlier work we postulated the existence of these connections and contributed substantially to their final approval, this research proposal focusses on the fundamental significance of HAS for the water and nutrient relations of plants, for atmosphere/plant interaction, and for the modelling of gas exchange. The planned experimental investigations aim to describe HAS formation by hygroscopic salts, to examine new concepts of the plant humidity sensor, nocturnal transpiration, stomatal water uptake, and the 'extended apoplast', as well as the significance of epicuticle waxes for atmospheric particle capture. Together, this should lead both to the further development of new theoretical concepts describing plant adaptations to aerosol regimes, and to practical applications in foliar fertilization, plant protection, and improvement of salt stress tolerance.
Groundwater contamination by organic compounds represents a widespread environmental problem. The heterogeneity of geological formations and the complexity of physical and biogeochemical subsurface processes, often hamper a quantitative characterization of contaminated aquifers. Compound specific stable isotope analysis (CSIA) has emerged as a novel approach to investigate contaminant transformation and to relate contaminant sources to downgradient contamination. This method generally assumes that only (bio)chemical transformations are associated with isotope effects. However, recent studies have revealed isotope fractionation of organic contaminants by physical processes, therefore pointing to the need of further research to determine the influence of both transport and reactive processes on the observed overall isotope fractionation. While the effect of gasphase diffusion on isotope ratios has been studied in detail, possible effects of aqueous phase diffusion and dispersion have received little attention so far.The goals of this study are to quantify carbon (13C/12C) and, for chlorinated compounds, chlorine (37Cl/35Cl) isotope fractionation during diffusive/dispersive transport of organic contaminants in groundwater and to determine its consequences for source allocation and assessment of reactive processes using isotopes. The proposed research is based on the combination of high-resolution experimental studies, both at the laboratory (i.e. zero-, one- and two-dimensional systems) and at the field scales, and solute transport modeling. The project combines the expertise in the field of contaminant transport with the expertise on isotope methods in contaminant hydrogeology.
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