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Forschergruppe (FOR) 1598: From Catchments as Organised Systems to Models based on Dynamic Functional Units (CAOS), Forschergruppe (FOR) 1598: From Catchments as Organised Systems to Models based on Dynamic Functional Units (CAOS)

Within phase 2 of the CAOS research unit we will work towards a holistic framework to explore how spatial organization alongside with spatial heterogeneity controls terrestrial water and energy cycles in intermediate scale catchments. 'Holistic' means for us to link the 'how' to the 'why' by drawing from generic understanding of landscape formation and biotic controls on processes and structures as well as to rely on exemplary experimental learning in a hypothesis and theory based manner. This also implies treatment of soil, vegetation and atmosphere as coupled system rather than a linear combination of different compartments. To jointly work towards this goal we propose 7 projects which will closely cooperate within two overarching work packages:WP1: Linking hydrological similarity with landscape structure across scalesWP2: Searching for appropriate catchment models and organizing principles. Within WP1 we will further refine the existing stratified multi-method and multi-sensor setup to search for functional entities in the Attert and, if they exist, to learn in an exemplary manner which structural features control functional characteristics. This essentially includes identification of suitable metrics to discriminate functional and structural similarity from data as well as identification of useful quantitative descriptors for the rather fuzzy term 'hydrological function'. Overall we aim to synthesize a protocol to decide 'where to assess which data for what reasons' for characterizing hydrological functioning across a scale range of four orders of magnitude.Within WP2 we will foster our distillery of parsimonious and nevertheless physically consistent model structures which rely on observable quantities and make use of symmetries in the landscape to simplify the governing model equations in a hypothesis based manner. To this end we will compare concurring model structures (among those the CAOS model) and work towards a framework for an objective model inter comparison with special emphasis on a) the added value of different data/information sources and b) on consistency of predictions with respect to distributed dynamics and integral flows. Additionally, we aim in WP2 at linking the 'how' to the 'why' by synthesizing testable hypotheses that could explain whether spatial organization has evolved in accordance with candidate organizing principles. Ecology, fluvial geomorphology and thermodynamics offer a large set of candidate organizing principles for this issue. Based on our recent work we will focus especially on thermodynamic limits and optimality principles like maximum entropy production, explore their value for uncalibrated hydrological predictions and work out the necessary requirements on data and models for testing these principles. We put special emphasis on a possible experimental falsification of these candidate principles; also in close collaboration with the B2-Landscape Evolution Observatory in Tucson, Arizona.

Geochemical parameters in peat depth profiles from ombrotrophic bogs in North and Central Europe. Drebbersches Moor, Germany

This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).

Geochemical parameters in peat depth profiles from ombrotrophic bogs in North and Central Europe. Fochteloër Veen, the Netherlands

This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).

Geochemical parameters in peat depth profiles from ombrotrophic bogs in North and Central Europe. Pichlmaier Moor, Austria

This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).

Geochemical parameters in peat depth profiles from ombrotrophic bogs in North and Central Europe. Pürgschachen Moor, Austria

This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).

Global optimized REVEALS reconstruction of past vegetation cover for taxonomically harmonized pollen data sets

This data set presents the reconstructed vegetation cover for 3083 sites based on harmonized pollen data from the data set LegacyPollen 2.0 (https://doi.pangaea.de/10.1594/PANGAEA.965907) and optimized RPP values. 1115 sites are located in North America, 1435 in Europe, and 533 in Asia. Sugita's REVEALS model (2007) was applied to all pollen records using REVEALSinR from the DISQOVER package (Theuerkauf et al. 2016). Pollen counts were translated into vegetation cover by taking into account taxon-specific pollen productivity and fall speed. Additionally, relevant source areas of pollen were also calculated using the aforementioned taxon-specific parameters and a gaussian plume model for deposition and dispersal. In this optimized reconstruction, relative pollen productivity estimates for the ten most common taxa were first optimized by using reconstructed tree cover from modern pollen samples and LANDSAT remotely sensed tree cover (Townshend 2016) for North America, Europe, and Asia. Values for non-optimized taxa for relative pollen productivity and fall speed were taken from the synthesis from Wiezcorek and Herzschuh (2020). The average values from all Northern Hemisphere values were used where taxon-specific continental values were not available. We present tables with optimized reconstructed vegetation cover for all Europe, North America and Asia. As further details we list a table with the taxon-specific parameters used and a list of parameters adjusted in the default version of REVEALSinR.

REVEALS reconstruction of past vegetation cover with optimized RPP values for European samples

This data set presents the reconstructed vegetation cover for 1451 European sites based on harmonized pollen data from the data set LegacyPollen 2.0 and optimized RPP values. Sugita's REVEALS model (2007) was applied to all pollen records using REVEALSinR from the DISQOVER package (Theuerkauf et al. 2016). Pollen counts were translated into vegetation cover by taking into account taxon-specific pollen productivity and fall speed. Additionally, relevant source areas of pollen were also calculated using the aforementioned taxon-specific parameters and a gaussian plume model for deposition and dispersal and forest cover was reconstructed. In this optimized reconstruction, relative pollen productivity estimates for the ten most common taxa were first optimized by using reconstructed tree cover from modern pollen samples and LANDSAT remotely sensed tree cover (Sexton et al. 2013) for Europe. Values for non-optimized taxa for relative pollen productivity and fall speed were taken from the synthesis from Wiezcorek and Herzschuh (2020). The average values from all Northern Hemisphere values were used where taxon-specific continental values were not available. We present tables with optimized reconstructed vegetation cover for all records in Europe. As further details we list a table with the taxon-specific parameters used and a list of parameters adjusted in the default version of REVEALSinR.

REVEALS reconstruction of past vegetation cover with optimized RPP values for Asian samples

This data set presents the reconstructed vegetation cover for 706 Asian sites based on harmonized pollen data from the data set LegacyPollen 2.0 and optimized RPP values. Sugita's REVEALS model (2007) was applied to all pollen records using REVEALSinR from the DISQOVER package (Theuerkauf et al. 2016). Pollen counts were translated into vegetation cover by taking into account taxon-specific pollen productivity and fall speed. Additionally, relevant source areas of pollen were also calculated using the aforementioned taxon-specific parameters and a gaussian plume model for deposition and dispersal and forest cover was reconstructed. In this optimized reconstruction, relative pollen productivity estimates for the ten most common taxa were first optimized by using reconstructed tree cover from modern pollen samples and LANDSAT remotely sensed tree cover (Sexton et al. 2013) for Asia. Values for non-optimized taxa for relative pollen productivity and fall speed were taken from the synthesis from Wiezcorek and Herzschuh (2020). The average values from all Northern Hemisphere values were used where taxon-specific continental values were not available. We present tables with optimized reconstructed vegetation cover for records in Asia. As further details we list a table with the taxon-specific parameters used and a list of parameters adjusted in the default version of REVEALSinR.

LegacyVegetation: Northern Hemisphere reconstruction of past plant cover and total tree cover from pollen archives of the last 14 ka

This data set presents the reconstructed vegetation cover for 2773 sites based on harmonized pollen data from the data set LegacyPollen 2.0 (https://doi.pangaea.de/10.1594/PANGAEA.965907). 1040 sites are located in North America, 1287 in Europe, and 446 in Asia. Sugita's REVEALS model (2007) was applied to all pollen records using REVEALSinR from the DISQOVER package (Theuerkauf et al. 2016). Pollen counts were translated into vegetation cover by accounting for taxon-specific pollen productivity and fall speed. Additionally, relevant source areas of pollen were calculated using the aforementioned taxon-specific parameters and a Gaussian plume model for deposition and dispersal. Values for relative pollen productivity and fall speed from the synthesis from Wiezcorek and Herzschuh (2010) were updated with recent studies used to reconstruct vegetation cover. The average values from all Northern Hemisphere values were used where taxon-specific continental values were unavailable. As REVEALS was conceived to reconstruct vegetation from large lakes, only records originating from large lakes (>= 50h) are marked as "valid as site" in the dataset. Reconstructions from other records can be used when spatially averaging several together. An example script to do so is provided on Zenodo (https://doi.org/10.5281/zenodo.12800290). Reconstructed tree cover was validated using modern Landsat remote sensing forest cover. Reconstructed tree cover has much lower errors than the original arboreal pollen percentages. Reconstructions of individual taxa are more uncertain. We present tables with reconstructed vegetation cover for all continents with original parameters. As further details, we list a table with the taxon-specific parameters used, metadata for all records, and a list of parameters adjusted in the default version of REVEALSinR.

LegacyVegetation: Asian reconstruction of past plant cover and total tree cover from pollen archives of the last 14 ka

This data set presents the reconstructed vegetation cover for 446 Asian sites based on harmonized pollen data from the data set LegacyPollen 2.0. Sugita's REVEALS model (2007) was applied to all pollen records using REVEALSinR from the DISQOVER package (Theuerkauf et al. 2016). Pollen counts were translated into vegetation cover by accounting for taxon-specific pollen productivity and fall speed. Additionally, relevant source areas of pollen were calculated using the aforementioned taxon-specific parameters and a Gaussian plume model for deposition and dispersal. Values for relative pollen productivity and fall speed from the synthesis from Wiezcorek and Herzschuh (2010) were updated with recent studies used to reconstruct vegetation cover. The average values from all Northern Hemisphere values were used where taxon-specific continental values were unavailable. As REVEALS was conceived to reconstruct vegetation from large lakes, only records originating from large lakes (>= 50h) are marked as "valid as site" in the dataset. Reconstructions from other records can be used when spatially averaging several together. An example script to do so is provided on Zenodo (https://doi.org/10.5281/zenodo.12800290). Reconstructed tree cover was validated using modern Landsat remote sensing forest cover. Reconstructed tree cover has much lower errors than the original arboreal pollen percentages. Reconstructions of individual taxa are more uncertain. We present tables with reconstructed vegetation cover for all continents with original parameters. As further details, we list a table with the taxon-specific parameters used, metadata for all records, and a list of parameters adjusted in the default version of REVEALSinR.

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