In den letzten Jahren sind biologisch Biokunststoffe immer mehr zum Forschungsinteresse geworden. Die Gründe liegen einerseits in der Suche nach Alternativen zur Verwendung von Kunststoffen auf Erdölbasis angesichts der zur Neige gehenden Erdölreserven und andererseits am Anwachsen der Müllberge und den damit verbundenen Problemen. Biokunststoffe können wie konventionelle Kunststoffe für eine große Vielfalt von Produkten, eingesetzt werden. Vor allem für kurzlebige Güter, wie Verpackungen oder Catering-Artikel sind Produkte aus Biokunststoff in höchstem Maße geeignet. Biokunststoffe werden aus nachwachsenden Quellen gewonnen und sind durch Mikroorganismen, also durch Kompostierung wieder abbaubar. Das vorliegende Projekt befasst sich mit Polyhydroxyalkanoaten (PHA), diese unterscheiden sich von anderen Biokunststoffen durch vorteilhafte Eigenschaften, wie Gasbarriereeigenschaften, Wasseraufnahme und Schmelztemperatur. Im Rahmen des beantragten Impulsprojektes soll ein wirtschaftlicher und ökologischer Prozess zur Herstellung von PHA entwickelt werden. Die Herausforderung liegt darin, ein neues Verfahren zu entwickeln, in dem einerseits auf die gegenseitige Wechselwirkung der einzelnen Grundoperationen bedacht genommen wird und andererseits danach getrachtet wird, Prozessnebenprodukte, nicht als Abfallströme aus dem Prozess ausschleusen zu müssen, sondern durch geeignete Aufbereitung wieder in den Prozess rückzuführen. Maximale Kreislaufschließung soll ermöglichen, ein Produkt, das den Anforderungen an Ressourcenschonung, Deponieentlastung und Abfallverarbeitung genügt, in einem Verfahren der Cleaner Produktion herzustellen.
This data set presents the reconstructed vegetation cover for 446 Asian sites based on harmonized pollen data from the data set LegacyPollen 2.0. Sugita's REVEALS model (2007) was applied to all pollen records using REVEALSinR from the DISQOVER package (Theuerkauf et al. 2016). Pollen counts were translated into vegetation cover by accounting for taxon-specific pollen productivity and fall speed. Additionally, relevant source areas of pollen were calculated using the aforementioned taxon-specific parameters and a Gaussian plume model for deposition and dispersal. Values for relative pollen productivity and fall speed from the synthesis from Wiezcorek and Herzschuh (2010) were updated with recent studies used to reconstruct vegetation cover. The average values from all Northern Hemisphere values were used where taxon-specific continental values were unavailable. As REVEALS was conceived to reconstruct vegetation from large lakes, only records originating from large lakes (>= 50h) are marked as "valid as site" in the dataset. Reconstructions from other records can be used when spatially averaging several together. An example script to do so is provided on Zenodo (https://doi.org/10.5281/zenodo.12800290). Reconstructed tree cover was validated using modern Landsat remote sensing forest cover. Reconstructed tree cover has much lower errors than the original arboreal pollen percentages. Reconstructions of individual taxa are more uncertain. We present tables with reconstructed vegetation cover for all continents with original parameters. As further details, we list a table with the taxon-specific parameters used, metadata for all records, and a list of parameters adjusted in the default version of REVEALSinR.
As part of the CDRmare joint project GEOSTOR (https://geostor.cdrmare.de/), the BGR created detailed static geological 3D models for two potential CO2 storage structures in the Middle Buntsandstein in the Exclusive Economic Zone (EEZ) of the German North Sea and supplemented them with petrophysical parameters (e.g. porosities, permeabilities). The 3D geological model (Pilot area B; ~560 km2) is located in the north-western part of the German North Sea sector, the so-called “Entenschnabel”, an approximately 150 kilometer long and 30 kilometer wide area between the offshore sectors of the Netherlands, Denmark and Great Britain (pilot region B). The model in the Ducks Beak is based on several high-resolution 3D seismic data and geophysical/geological information from four exploration wells. It includes 20 generalized faults and the following 16 horizon surfaces: 1) Sea Floor, 2) Mid Miocene Unconformity, 3) Base Tertiary, 4) Base Upper Cretaceous, 5) Base Lower Cretaceous, 6) Base Upper Jurassic, 7) Base Lower Jurassic, 8) Base Muschelkalk, 9) Base Röt, 10) Base Solling Formation, 11) Base Detfurth Formation, 12) Base Volpriehausen Wechselfolge, 13) Base Volpriehausen Formation, 14) Base Triassic, 15) Base Zechstein, 16) Top Basement. The reservoir formed by sandstones of the Middle Buntsandstein is located within the Mads Graben, which is bounded to the west by the extensive Mads Fault (normal fault). Marine mudstones of the Upper Jurassic and Lower Cretaceous serve as the main seal formations. Petrophysical analyses of all considered well data were conducted and reservoir properties (including porosity and permeability) were calculated to determine the static reservoir capacity for these potential CO2 storage structures. The model parameterized and can be used for further dynamic simulations of storage capacity, geo-risk, and infrastructure analyses, in order to develop a comprehensive feasibility study for potential CO2 storage within the project framework. The 3D models were created by the BGR between 2021 and 2024. SKUA-GOCAD was used as the modeling software. We would like to thank AspenTech for providing licenses for their SSE software package as part of the Academic Program (https://www.aspentech.com/en/academic-program).
As part of the CDRmare joint project GEOSTOR (https://geostor.cdrmare.de/), the BGR created detailed static geological 3D models for two potential CO2 storage structures in the Middle Buntsandstein in the Exclusive Economic Zone (EEZ) of the German North Sea and supplemented them with petrophysical parameters (e.g. porosities, permeabilities). The 3D geological model (Pilot area A; ~1300 km2) is located on the West Schleswig Block in the area of the Henni salt pillow (pilot region A). It is based on 2D seismic data from various surveys and geophysical/geological information from four exploration wells. The model comprises 14 generalized faults and the following 14 horizon surfaces: 1) Sea Floor, 2) Mid Miocene Unconformity, 3) Base Rupelian, 4) Base Tertiary, 5) Base Upper Cretaceous, 6) Base Lower Cretaceous, 7) Base Muschelkalk, 8) Base Röt (Pelite), 9) Base Röt (Salinar), 10) Base Solling Formation, 11) Base Detfurth Formation, 12) Base Volpriehausen Formation, 13) Base Triassic, 14) Base Zechstein. The selected potential reservoir structure in the Middle Buntsandstein is formed by an anticline created by the uplift of the underlying Henni salt pillow. The primary reservoir unit is the 40-50 m thick Lower Volpriehausen Sandstone, the main sealing units are the Röt and the Lower Cretaceous. Petrophysical analyses of all considered well data were conducted and reservoir properties (including porosity and permeability) were calculated to determine the static reservoir capacity for these potential CO2 storage structures. Both models were parameterized and can be used for further dynamic simulations of storage capacity, geo-risk, and infrastructure analyses, in order to develop a comprehensive feasibility study for potential CO2 storage within the project framework. The 3D models were created by the BGR between 2021 and 2024. SKUA-GOCAD was used as the modeling software. We would like to thank AspenTech for providing licenses for their SSE software package as part of the Academic Program (https://www.aspentech.com/en/academic-program).
Multibeam data were collected with RV Polarstern along the route of cruise PS151 and data acquisition was almost continuously monitored during the survey. Multibeam sonar system was Teledyne/Atlas Hydrosweep DS3. SVPs were retrieved from CTD data and synthetic profiles from World Ocean Atlas 23. SVPs were processed with HydrOffice SoundSpeedManager (https://www.hydroffice.org/soundspeed/main) and extended with World Ocean Atlas 23 (https://www.ncei.noaa.gov/archive/accession/NCEI-WOA23). SVP data were applied during acquisition. Multibeam data are unprocessed and may contain outliers and blunders and should not be used for grid calculations and charting projects without further editing. The raw multibeam sonar data in Teledyne Reson multibeam processing format (.s7k) were recorded with Teledyne PDS software. Raw data files can be processed using software packages like CARIS HIPS/SIPS. For updated vessel configuration files check further details.
This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).
This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).
This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).
This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).
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