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Carbonate chemistry and river discharge dataset for the Elbe from incubation experiments and historical data records

This dataset provides carbonate chemistry and hydrological measurements supporting the analysis of the stability of alkalinity and carbon transport potential in the Elbe Estuary, northern Germany. It includes (1) results from laboratory incubation experiments using water samples from the Elbe conducted in 2023, (2) historical water chemistry monitoring records from multiple stations, and (3) monthly flow discharge measurements from the Neu Darchau gauging station. Experimental data were collected from the experiments varying salinity and seasonal conditions, and parameters measured include pH, temperature, and total alkalinity. Major ion concentrations (Na+, K+, Ca2+, Mg2+, Cl-, SO42-) were reconstructed from stoichiometry. The saturation states of calcite and aragonite, as well as pCO2, were calculated using the phreeqpython geochemical package. Historical data, covering carbonate chemistry and major ions at several stations and over multiple years, were collected from digitized sources and FGG Elbe. Together, this dataset facilitates the investigation of long-term trends in the carbonate system and carbon transport in the land ocean transition zone of the Elbe River.

Repository der KI-Ideenwerkstatt: toxfox-ocr

<p>Im Pilotprojekt <a href="https://www.ki-ideenwerkstatt.de/unterstuetzung-materialien/pilotprojekte/toxfox-mithilfe-von-ki-inhaltsstoffe-scannen/"><em>ToxFox</em></a> wurde 2024/25 gemeinsam mit dem <a href="https://www.bund.net/">BUND</a> eine KI-basierte OCR-L&ouml;sung (englisch: optical character recognition, Bild zu Text) entwickelt. Hierbei wird via FastAPI-Webanwendung ein per Smartphonekamera aufgenommens Bild der Informationstextes der Inhaltsstoffe auf Verpackung eines Produktes erfasst und anschlie&szlig;end eine Liste der gefundenen Schadstoffe nach INCI zur&uuml;ckgegeben. INCI steht f&uuml;r die Internationale Nomenklatur f&uuml;r kosmetische Inhaltsstoffe. Bisher musste f&uuml;r diesen Prozess der Barcode der Produkte gescannt werden. Mit der OCR-L&ouml;sung sollen u.a. Fehler korrigiert werden, die durch veraltete, auf Barcodes enthaltene Informationen entstehen oder sich durch eine Umbenennung der Chemikalien durch die Industrie ergeben k&ouml;nnten.</p>

Raw data of physical oceanography during RV MARIA S. MERIAN cruise MSM97/2

Raw physical oceanography data was acquired by a ship-based Seabird SBE911+ CTD-Rosette system onboard RV MARIA S. MERIAN during research cruise MSM97/2. The CTD system is comprised of a Seabird SBE911Plus including dual respectively redundant sensor and pump packages. The SBE11plus Deck Unit remains on board in a laboratory and supplies on one hand power to the SBE9plus underwater unit, on the other hand data telemetry between the SBE9plus and a measurement PC. The SBE9plus underwater unit itself holds a pressure sensor and is interfacing with dual SEB3 temperature, SBE4 conductivity and SBE43 oxygen sensors and two SBE5 pumps to provide a pumped water supply past each sensor. The system also carries an optical FLNTU sensor to measure a combinations of back-scattering, turbidity, and chlorophyll-a. To quantify the photo-synthetically active radiation a PAR sensor is installed as well. Water sampling is supported via 24 Niskin water sample bottles holding 10L each, fired via a SBE32 carousel water sampler.

Physical oceanography during RV MARIA S. MERIAN cruise MSM123

Physical oceanography data was acquired by a ship-based Seabird SBE911plus CTD-Rosette system onboard RV MARIA S. MERIAN during research cruise MSM123. The CTD system is comprised of a Seabird SBE911plus including dual respectively redundant sensor and pump packages. The SBE11plus Deck Unit remains on board in a laboratory and supplies on one hand power to the SBE9plus underwater unit, on the other hand data telemetry between the SBE9plus and a measurement PC. The SBE9plus underwater unit itself holds a pressure sensor and is interfacing with dual SEB3 temperature, SBE4 conductivity and SBE43 oxygen sensors, as well as two SBE5 pumps to provide a pumped water supply past each sensor. The system also carries an optical FLNTU sensor to measure a combination of back-scattering, turbidity, and chlorophyll-a. To quantify the photo-synthetically active radiation a PAR sensor is installed as well.

Geochemical parameters in peat depth profiles from ombrotrophic bogs in North and Central Europe. Pichlmaier Moor, Austria

This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).

Geochemical parameters in peat depth profiles from ombrotrophic bogs in North and Central Europe. Drebbersches Moor, Germany

This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).

Geochemical parameters in peat depth profiles from ombrotrophic bogs in North and Central Europe. Fochteloër Veen, the Netherlands

This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).

Geochemical parameters in peat depth profiles from ombrotrophic bogs in North and Central Europe. Pürgschachen Moor, Austria

This dataset contains geochemical variables measured in six depth profiles from ombrotrophic peatlands in North and Central Europe. Peat cores were taken during the spring and summer of 2022 from Amtsvenn (AV1), Germany; Drebbersches Moor (DM1), Germany; Fochteloër Veen (FV1), the Netherlands; Bagno Kusowo (KR1), Poland; Pichlmaier Moor (PI1), Austria and Pürgschachen Moor (PM1), Austria. The cores AV1, DM1 and KR1 were taken using a Wardenaar sampler (Royal Eijkelkamp, Giesbeek, the Netherlands) and had diameter of 10 cm. The cores FV1, PM1 and PI1 had an 8 cm diameter and were obtained using an Instorf sampler (Royal Eijkelkamp, Giesbeek, the Netherlands). The cores FV1, DM1 and KR1 were 100 cm, core AV1 was 95 cm, core PI1 was 85 cm and core PM1 was 200 cm. The cores were subsampeled in 1 cm (AV1, DM1, KR1, FV1) and 2 cm (PI1, PM1) sections. The subsamples were milled after freeze drying in a ballmill using tungen carbide accesoires. X-Ray Fluorescence (WD-XRF; ZSX Primus II, Rigaku, Tokyo, Japan) was used to determine Al (μg g-1), As (μg g-1), Ba (μg g-1), Br (μg g-1), Ca (g g-1), Cl (μg g-1), Cr (μg g-1), Cu (μg g-1), Fe (g g-1), K (g g-1), Mg (μg g-1), Mn (μg g-1), Na (μg g-1), P (μg g-1), Pb (μg g-1), Rb (μg g-1), S (μg g-1), Si (μg g-1), Sr (μg g-1), Ti (μg g-1) and Zn (μg g-1). These data were processed and calibrated using the iloekxrf package (Teickner & Knorr, 2024) in R. C, N and their stable isotopes were determined using an elemental analyser linked to an isotope ratio mass spectrometer (EA-3000, Eurovector, Pavia, Italy & Nu Horizon, Nu Instruments, Wrexham, UK). C and N were given in units g g-1 and stable isotopes were given as δ13C and δ15N for stable isotopes of C and N, respectively. Raw data C, N and stable isotope data were calibrated with certified standard and blank effects were corrected with the ilokeirms package (Teickner & Knorr, 2024). Using Fourier Transform Mid-Infrared Spectroscopy (FT-MIR) (Agilent Cary 670 FTIR spectromter, Agilent Technologies, Santa Clara, Ca, USA) humification indices (HI) were determined. Spectra were recorded from 600 cm-1 to 4000 cm-1 with a resolution of 2 cm-1 and baselines corrected with the ir package (Teickner, 2025) to estimate relative peack heights. The HI (no unit) for each sample was calculated by taking the ratio of intensities at 1630 cm-1 to the intensities at 1090 cm-1. Bulk densities (g cm-3) were estimated from FT-MIR data (Teickner et al., in preparation).

Global optimized REVEALS reconstruction of past vegetation cover for taxonomically harmonized pollen data sets

This data set presents the reconstructed vegetation cover for 3083 sites based on harmonized pollen data from the data set LegacyPollen 2.0 (https://doi.pangaea.de/10.1594/PANGAEA.965907) and optimized RPP values. 1115 sites are located in North America, 1435 in Europe, and 533 in Asia. Sugita's REVEALS model (2007) was applied to all pollen records using REVEALSinR from the DISQOVER package (Theuerkauf et al. 2016). Pollen counts were translated into vegetation cover by taking into account taxon-specific pollen productivity and fall speed. Additionally, relevant source areas of pollen were also calculated using the aforementioned taxon-specific parameters and a gaussian plume model for deposition and dispersal. In this optimized reconstruction, relative pollen productivity estimates for the ten most common taxa were first optimized by using reconstructed tree cover from modern pollen samples and LANDSAT remotely sensed tree cover (Townshend 2016) for North America, Europe, and Asia. Values for non-optimized taxa for relative pollen productivity and fall speed were taken from the synthesis from Wiezcorek and Herzschuh (2020). The average values from all Northern Hemisphere values were used where taxon-specific continental values were not available. We present tables with optimized reconstructed vegetation cover for all Europe, North America and Asia. As further details we list a table with the taxon-specific parameters used and a list of parameters adjusted in the default version of REVEALSinR.

REVEALS reconstruction of past vegetation cover with optimized RPP values for European samples

This data set presents the reconstructed vegetation cover for 1451 European sites based on harmonized pollen data from the data set LegacyPollen 2.0 and optimized RPP values. Sugita's REVEALS model (2007) was applied to all pollen records using REVEALSinR from the DISQOVER package (Theuerkauf et al. 2016). Pollen counts were translated into vegetation cover by taking into account taxon-specific pollen productivity and fall speed. Additionally, relevant source areas of pollen were also calculated using the aforementioned taxon-specific parameters and a gaussian plume model for deposition and dispersal and forest cover was reconstructed. In this optimized reconstruction, relative pollen productivity estimates for the ten most common taxa were first optimized by using reconstructed tree cover from modern pollen samples and LANDSAT remotely sensed tree cover (Sexton et al. 2013) for Europe. Values for non-optimized taxa for relative pollen productivity and fall speed were taken from the synthesis from Wiezcorek and Herzschuh (2020). The average values from all Northern Hemisphere values were used where taxon-specific continental values were not available. We present tables with optimized reconstructed vegetation cover for all records in Europe. As further details we list a table with the taxon-specific parameters used and a list of parameters adjusted in the default version of REVEALSinR.

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