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Entwicklung neuer zeolithischer Redoxkatalysatoren für die selektive Reduktion von NO durch Ammoniak durch Aufklärung der Beziehungen zwischen Katalysatorstruktur und katalytischen Eigenschaften

Ziel des Vorhabens ist die Entwicklung hochaktiver, selektiver und stabiler zeolithischer Redoxkatalysatoren für die selektive Reduktion von Stickstoffoxiden mit Ammoniak. Zu diesem Zweck werden durch Kombination katalytischer Untersuchungen mit Studien zur physikochemischen Charakterisierung von Aktivkomponente und Matrix (Methoden: EPR, ferromagnetische Resonanz (FMR), Mößbauerspektroskopie, EXAFX, XPS, ISS, UV-Vis, IR, Raman, XRD) gesicherte Erkenntnisse über die erforderliche Struktur der Redoxkomponente und der zeolithischen Matrix erarbeitet, die in verbesserte Präparationsstrategien für eine neue Katalysatorgeneration umgesetzt werden. Bezüglich der Strukturierung der Übergangsmetallkomponente ist durch Kombination katalytischer mit spektroskopischen Techniken zwischen der Wirkung isolierter Ionen auf Kationenplätzen sowie intra- bzw. extra-zeolithischer Oxidaggregate zu differenzieren, wobei dem Beweis der katalytischen Relevanz von Spezies über spektroskopische in situ-Studien (EPR, UV-Vis, Raman, EXAFS) besondere Bedeutung zukommt (1.-3. Jahr).

CrossData - Regionalplanung - Raumstruktur

Es sind regionalplanerische Festlegungen des Komplexes Raumstruktur für die deutsch-tschechische grenzüberschreitende Zusammenarbeit der Planungsbehörden dargestellt. Der Datensatz enthält Daten der Planungsregionen Region Chemnitz, Oberes Elbtal-Osterzgebirge und Oberlausitz-Niederschlesien. Entsprechend des Landesentwicklungsplanes 2013 als fachübergreifendes Gesamtkonzept zur räumlichen Entwicklung, Ordnung und Sicherung des Freistaates Sachsen stellen die Regionalpläne einen verbindlichen Rahmen für die räumliche Entwicklung, Ordnung und Sicherung des Raumes dar. Die rechtsverbindlichen Pläne werden in der Regel im Maßstab 1:100.000 erstellt.

Expert dataset: A whole rock geochemical dataset for magmatic rocks drilled on the mid-Norwegian margin

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Regionalplanung Sachsen - Raumstruktur

Dieser Datensatz enthält Daten der Planungsregionen Oberes Elbtal/Osterzgebirge, Region Chemnitz und Oberlausitz-Niederschlesien und deckt im Endausbau den gesamten Freistaat Sachsen ab. Entsprechend des Landesentwicklungsplanes 2013 als fachübergreifendes Gesamtkonzept zur räumlichen Entwicklung, Ordnung und Sicherung des Freistaates Sachsen stellen die Regionalpläne einen verbindlichen Rahmen für die räumliche Entwicklung, Ordnung und Sicherung des Raumes dar. Im Datensatz sind regionalplanerische Festlegungen des Komplexes Raumstruktur enthalten. Die rechtsverbindlichen Pläne werden in der Regel in Maßstäben zwischen 1:300.000 und 1:450.000 erstellt.

Chemical analyses of the Eastern Australian Potassic Suite: Whole-rock major, trace, and volatile element geochemistry

These data represent the most complete set of analyses of the Eastern Australian Potassic suite. The data include whole-rock major-, trace-, and volatile-element analyses including loss-on-ignition measurements for 48 samples from 21 spatially distinct leucite-bearing volcanic surface expressions. These expressions range from topographically prominent volcanic edifices and mounds, through to lava flows, with four sample locations (8 samples total) coming from active quarry sites. Location and elevation data as well as methods used are provided. Trace-element data are available for 45 samples and include a total of 41 elements, while volatile-element data are available for 47 samples. All samples have major element analyses (10 elements). This is an update on the dataset provided in version 1 (https://doi.org/10.25625/AB5PLG). Additional information on the sample texture, description, and analytical methods has been added. This update also rectifies mismatches between some trace-element analyses and the corresponding samples. Data for Sn have been removed due to poor accuracy and precision.

Integrated Mineral, Whole-Rock Geochemistry and Isotopic dataset of the Transminas and Pirenópolis Dike Swarms, Southeastern and Central Brazil

This dataset includes new geochemical and isotopic analyses for 46 samples from the Transminas and Pirenópolis dike swarms in southeastern and central Brazil. It comprises whole-rock major and trace element compositions, and Sr-Nd-Pb isotopes. The new analyses are presented for 46 samples using the bulk and in-situ data templates developed by EarthChem. Analytical work was conducted at the Geoanalítica Core Facility of the Instituto de Geociências, University of São Paulo, and at the Geochronology Laboratory of the University of Brasília, both in Brazil.

Point-scale IWV and zenith total delay (ZTD) derived for 66 stations of the global navigation satellite system (GNSS) Upper Rhine Graben network (GURN)

The ground-based global navigation satellite system (GNSS) technic was employed to retrieve the integrated water vapor (IWV) at 66 stations of the GNSS Upper Rhine Graben network (GURN). The GNSS IWV dataset is synchronous with the associated InSAR dataset, with 219 days available during the period March 2015 – July 2019. GNSS zenith total delay (ZTD) estimates are calculated every one hour and then converted to IWV with additional meteorological parameters from ERA5. The GNSS IWV of all the stations are saved in daily files in the second version of the Solution (Software/Technique) Independent Exchange (SINEX) format for TROpospheric parameters. GNSS station information is given in the file headers. In addition, the associated meteorological parameters from ERA5 are also provided, such as station pressure and weighted mean temperature.

Total organic carbon data of the Devonian Kellwasser Crisis interval (ca. 372 Ma) at Winsenberg, Germany

A total of 34 samples (35 cm average sample spacing) were analysed for organic carbon d13C in order to identify the two characteristic positive excursions associated with the Lower and Upper Kellwasser Events. Measurements were carried out at the Analytical, Environmental and Geo-Chemistry Research Group (AMGC) of the Vrije Universiteit Brussel (Belgium). The samples were decarbonated with 10% HCl in two steps, rinsed with milliQ water, and dried in an oven at 50°C. Total organic carbon (TOC) contents and δ13Corg compositions were determined on a Euro EA 150 Elemental Analyzer (CHNS) - Euro Vector HT-PyrOH combustion system coupled to a Nu-Instruments Horizon 2 isotope ratio mass spectrometer.

Tuned SiO2/CaO ratios of the Devonian Kellwasser Crisis interval (ca. 372 Ma) at Winsenberg, Germany

A total of 556 samples (3 cm average sample spacing) were collected from the 12 m long Winsenberg section in order to reconstruct a floating timescale using cyclostratigraphic methods and to investigate paleoclimatic dynamics using selected elemental ratios. Samples were measured as a powder covered with Chemplex film on a Bruker S1 Titan 800 portable XRF at the University of Münster with the following settings: 40 kV, 20 mA, no filters, 75 s. Spectra were deconvoluted in Bruker Artrax software, and linearly calibrated using a set of 10 sedimentary standards of known composition and 11 calcite-quart mixtures. The composition of these standards is also included. Selected elemental ratios were tuned via the methods described in the accompanying manuscript, and are included in this dataset as well.

Estimated adjusted depth of CO2 of FB2001 drill core from Messel

This table contains atmospheric CO2-estimates based on stomata retrieved in the Messel fossil pit and published by Grein (2010) and Grein et al. (2011). The data is based on leaves retrieved from the Messel fossil pit (earliest Middle Eocene; 47.66 to 47.22 Ma). The leaves were microscopically analysed for their stomata density and which was then converted into atmospheric CO2 content (cf. Grein 2010, Grein et al., 2011 for details about the algorithm). The plant fossils were listed with their original outcrop depth which was marked down relative to marker beds. We projected the outcrop depth (m) onto the FB2001 drill core depth using the marker beds as reference horizons. The age (Ma) as well as mean, maximum and minimum of the CO2 estimates are reported as well as the respective plant species.

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