API src

Found 77 results.

Regionalplanung Sachsen - Raumstruktur

Dieser Datensatz enthält Daten der Planungsregionen Oberes Elbtal/Osterzgebirge, Region Chemnitz und Oberlausitz-Niederschlesien und deckt im Endausbau den gesamten Freistaat Sachsen ab. Entsprechend des Landesentwicklungsplanes 2013 als fachübergreifendes Gesamtkonzept zur räumlichen Entwicklung, Ordnung und Sicherung des Freistaates Sachsen stellen die Regionalpläne einen verbindlichen Rahmen für die räumliche Entwicklung, Ordnung und Sicherung des Raumes dar. Im Datensatz sind regionalplanerische Festlegungen des Komplexes Raumstruktur enthalten. Die rechtsverbindlichen Pläne werden in der Regel in Maßstäben zwischen 1:300.000 und 1:450.000 erstellt.

Entwicklung neuer zeolithischer Redoxkatalysatoren für die selektive Reduktion von NO durch Ammoniak durch Aufklärung der Beziehungen zwischen Katalysatorstruktur und katalytischen Eigenschaften

Ziel des Vorhabens ist die Entwicklung hochaktiver, selektiver und stabiler zeolithischer Redoxkatalysatoren für die selektive Reduktion von Stickstoffoxiden mit Ammoniak. Zu diesem Zweck werden durch Kombination katalytischer Untersuchungen mit Studien zur physikochemischen Charakterisierung von Aktivkomponente und Matrix (Methoden: EPR, ferromagnetische Resonanz (FMR), Mößbauerspektroskopie, EXAFX, XPS, ISS, UV-Vis, IR, Raman, XRD) gesicherte Erkenntnisse über die erforderliche Struktur der Redoxkomponente und der zeolithischen Matrix erarbeitet, die in verbesserte Präparationsstrategien für eine neue Katalysatorgeneration umgesetzt werden. Bezüglich der Strukturierung der Übergangsmetallkomponente ist durch Kombination katalytischer mit spektroskopischen Techniken zwischen der Wirkung isolierter Ionen auf Kationenplätzen sowie intra- bzw. extra-zeolithischer Oxidaggregate zu differenzieren, wobei dem Beweis der katalytischen Relevanz von Spezies über spektroskopische in situ-Studien (EPR, UV-Vis, Raman, EXAFS) besondere Bedeutung zukommt (1.-3. Jahr).

Chironomidae whole or half head capsules counts in sediment core Haem13 from lake Hämelsee

This dataset provides counts of chironomid head capsules for the Lateglacial sediment sequence retrieved from Lake Hämelsee (Germany) in 2013. Counts per taxon are presented against both depth (m) and age (cal yr. BP), and the total amount of material used for analysis (in g) is provided as well. The chironomid data provides information on Lateglacial ecosystem dynamics and were used to interpret changes in aquatic diversity as well as in local climate conditions. A total of 123 samples from the Lateglacial section of the core were treated with warm KOH (10%) to de-flocculate the material and subsequently rinsed through a sieve with a 100-µm mesh. Chironomid head capsules (HCs) were hand-picked from the residue using a Bogorov sorting tray and mounted on permanent microscope slides using Euparal mounting medium. HCs were identified using Brooks et al. (2007) and the dataset presented here has been matched to the taxonomy of the merged Norwegian/Swiss chironomid-climate calibration dataset. Several samples had low chironomid concentrations and for these we amalgamated adjacent samples (within lithological boundaries) to reach a minimum count sum of 50 head capsules per sample. This process resulted in the final chironomid dataset that is presented here, containing 97 samples. All analyses were performed in the laboratories of the University of Amsterdam, the Netherlands.

GDGTs in sediment core Haem13 from lake Hämelsee

This dataset provides glycerol dialkyl glycerol tetraethers (GDGTs) concentrations for the Lateglacial sediment sequence retrieved from Lake Hämelsee (Germany) in 2013. GDGTs concentrations (ng/g) are presented against both depth (m) and age (cal yr. BP). The GDGTs dataset was used to calculate the GDGT-0/crenarchaeol ratio, which was interpreted to represent lake water oxygenation, which, given the local settings, was likely driven by changes in windiness. Additionally, the GDGT dataset was used to calculate the degree of methylation of 5-methyl brGDGTs (MBT'5me), which can be used to reconstruct past temperature change through translation MBT'5me into mean temperature of the months above freezing. As such, the GDGT data provides information on LGIT climate dynamics at lake Hämelsee. Of the 167 samples used for lipid extraction (see https://doi.pangaea.de/10.1594/PANGAEA.964524), the alcohol/fatty acid fraction of 94 samples was further processed to analyse glycerol dialkyl glycerol tetraethers (GDGTs), which are membrane lipids of certain archaea and bacteria (Schouten et al., 2013). In short, a known amount of internal standard was added to each fraction, which was then redissolved in hexane:isopropanol 99:1 and passed over a 0.45 µm PTFE filter prior to injection on a Agilent 1260 Infinity ultra-high performance liquid chromatograph coupled to an Agilent 6130 single quadrupole mass spectrometer following the settings and elution protocol of Hopmans et al. (2016). A minimum peak area of 3000 and a signal-to-noise ratio of >3 was maintained as detection limit. Quantification of the GDGTs is based on the assumption that the mass spectrometer equally responds to the GDGTs and the internal standard. All analyses were performed in the laboratories of Utrecht University, the Netherlands.

Total organic carbon data of the Devonian Kellwasser Crisis interval (ca. 372 Ma) at Winsenberg, Germany

A total of 34 samples (35 cm average sample spacing) were analysed for organic carbon d13C in order to identify the two characteristic positive excursions associated with the Lower and Upper Kellwasser Events. Measurements were carried out at the Analytical, Environmental and Geo-Chemistry Research Group (AMGC) of the Vrije Universiteit Brussel (Belgium). The samples were decarbonated with 10% HCl in two steps, rinsed with milliQ water, and dried in an oven at 50°C. Total organic carbon (TOC) contents and δ13Corg compositions were determined on a Euro EA 150 Elemental Analyzer (CHNS) - Euro Vector HT-PyrOH combustion system coupled to a Nu-Instruments Horizon 2 isotope ratio mass spectrometer.

Integrated Mineral, Whole-Rock Geochemistry and Isotopic dataset of the Transminas and Pirenópolis Dike Swarms, Southeastern and Central Brazil

This dataset includes new geochemical and isotopic analyses for 46 samples from the Transminas and Pirenópolis dike swarms in southeastern and central Brazil. It comprises whole-rock major and trace element compositions, and Sr-Nd-Pb isotopes. The new analyses are presented for 46 samples using the bulk and in-situ data templates developed by EarthChem. Analytical work was conducted at the Geoanalítica Core Facility of the Instituto de Geociências, University of São Paulo, and at the Geochronology Laboratory of the University of Brasília, both in Brazil.

Estimated adjusted depth of CO2 of FB2001 drill core from Messel

This table contains atmospheric CO2-estimates based on stomata retrieved in the Messel fossil pit and published by Grein (2010) and Grein et al. (2011). The data is based on leaves retrieved from the Messel fossil pit (earliest Middle Eocene; 47.66 to 47.22 Ma). The leaves were microscopically analysed for their stomata density and which was then converted into atmospheric CO2 content (cf. Grein 2010, Grein et al., 2011 for details about the algorithm). The plant fossils were listed with their original outcrop depth which was marked down relative to marker beds. We projected the outcrop depth (m) onto the FB2001 drill core depth using the marker beds as reference horizons. The age (Ma) as well as mean, maximum and minimum of the CO2 estimates are reported as well as the respective plant species.

Recurrence times of siderite layers of FB2001 drill core from Messel

To investigate variability and drivers of extreme precipitation events under high greenhouse gas concentrations prevalent during the Eocene we computed recurrence times of Fe/Ti peaks in the XRF scanning record of FB2001, reflecting siderite layers that are interpreted to reflect strong precipitation events. Fe/Ti-peaks were detected based on a peak-detection algorithm, followed by counting over a sliding window. Recurrence times were calculated based on the number of Fe/Ti peaks per 5 ka window. Upper and lower boundaries of recurrence times are calculated based on bootstrapping. The record covers the period 47.66 to 47.22 Ma

Mean Annual Air Temperatures of FB2001 drill core from Messel

This table contains Mean Annual Temperatures (MAT) reconstructed using branched GDGTs obtained on core FB2001 from Messel (earliest Middle Eocene; 47.66 to 47.22 Ma), relative to the core depth and age. The error given reflects the calibration error. Samples from the depth interval 17.38 to 30.88 m were analyzed in Frankfurt by high-performance liquid chromatography coupled to atmospheric pressure chemical ionization mass spectrometry (HPLC-APCI-MS) on a Shimadzu UFLC device coupled to an AB Sciex 3200QTrap. Samples from the interval between 35.94 to 70.94 m core analyzed at RWTH Aachen University, Aachen (Germany), using an Agilent 1260 Infinity II HPLC coupled to an Agilent LC/MSD XT mass spectrometer.

XRF Fe/TI and K/Ti ratios of FB2001 drill core from Messel

The data contains Fe/Ti and K/Ti ratios obtained via XRF core scanning of drill core FB2001 from the Messel fossil pit (earliest Middle Eocene; 47.66 to 47.22 Ma) versus core depth and age. Scanning was performed at the Institute of Institute of Earth Sciences, Heidelberg University (Germany), with an Avvatech (Gen. IV) X-Ray Fluorescence Scanner. The purpose of this analysis was to objectively detect and quantify the occurrence of siderite layers in the Messel oil shale. These siderite layers are interpreted to represent extreme precipitation events.

1 2 3 4 5 6 7 8