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Atmospheric methane and carbon dioxide concentrations measured during ALKOR cruise AL575 on 2022-07-11

Atmospheric carbon dioxide (CO2) and methane (CH4) concentrations were monitored during AL575 cruise on 2022-07-11 using a cavity ring down spectrometer (Picarro G2301-f CRDS) and GEOMARs 'Atmospheric Intake System' (AIS). The Picarro/AIS system was installed in the wet laboratory (starboard, main deck) of RV ALKOR and was connected by an aluminium tube to an air inlet nozzle placed at the bow of RV ALKOR. The air was pumped via the AIS intake tube with a flow rate of 2.67 litre per minute to the Picarro analyser. The atmospheric CH4, CO2, and water vapour concentrations were determined in real time at 2-3 Hz sampling rate. A time offset of 87 seconds between the air intake nozzle at the bow (6 m above sea surface) and the actual gas measurement at the Picarro was determined and the calculated flow rate considered, when correlating the gas data with navigation and weather data provided by the WERUM dship repository (https://dship.geomar.de). The weather data is published separately at doi:10.1594/PANGAEA.983833 .

Atmospheric methane and carbon dioxide concentrations measured during ALKOR cruise AL575 on 2022-06-30

Atmospheric carbon dioxide (CO2) and methane (CH4) concentrations were monitored during AL575 cruise on 2022-06-30 using a cavity ring down spectrometer (Picarro G2301-f CRDS) and GEOMARs 'Atmospheric Intake System' (AIS). The Picarro/AIS system was installed in the wet laboratory (starboard, main deck) of RV ALKOR and was connected by an aluminium tube to an air inlet nozzle placed at the bow of RV ALKOR. The air was pumped via the AIS intake tube with a flow rate of 2.67 litre per minute to the Picarro analyser. The atmospheric CH4, CO2, and water vapour concentrations were determined in real time at 2-3 Hz sampling rate. A time offset of 87 seconds between the air intake nozzle at the bow (6 m above sea surface) and the actual gas measurement at the Picarro was determined and the calculated flow rate considered, when correlating the gas data with navigation and weather data provided by the WERUM dship repository (https://dship.geomar.de). The weather data is published separately at doi:10.1594/PANGAEA.983833 .

Atmospheric methane and carbon dioxide concentrations measured during ALKOR cruise AL575 on 2022-06-29

Atmospheric carbon dioxide (CO2) and methane (CH4) concentrations were monitored during AL575 cruise on 2022-06-29 using a cavity ring down spectrometer (Picarro G2301-f CRDS) and GEOMARs 'Atmospheric Intake System' (AIS). The Picarro/AIS system was installed in the wet laboratory (starboard, main deck) of RV ALKOR and was connected by an aluminium tube to an air inlet nozzle placed at the bow of RV ALKOR. The air was pumped via the AIS intake tube with a flow rate of 2.67 litre per minute to the Picarro analyser. The atmospheric CH4, CO2, and water vapour concentrations were determined in real time at 2-3 Hz sampling rate. A time offset of 87 seconds between the air intake nozzle at the bow (6 m above sea surface) and the actual gas measurement at the Picarro was determined and the calculated flow rate considered, when correlating the gas data with navigation and weather data provided by the WERUM dship repository (https://dship.geomar.de). The weather data is published separately at doi:10.1594/PANGAEA.983833 .

Atmospheric methane and carbon dioxide concentrations measured during ALKOR cruise AL575 on 2022-07-10

Atmospheric carbon dioxide (CO2) and methane (CH4) concentrations were monitored during AL575 cruise on 2022-07-10 using a cavity ring down spectrometer (Picarro G2301-f CRDS) and GEOMARs 'Atmospheric Intake System' (AIS). The Picarro/AIS system was installed in the wet laboratory (starboard, main deck) of RV ALKOR and was connected by an aluminium tube to an air inlet nozzle placed at the bow of RV ALKOR. The air was pumped via the AIS intake tube with a flow rate of 2.67 litre per minute to the Picarro analyser. The atmospheric CH4, CO2, and water vapour concentrations were determined in real time at 2-3 Hz sampling rate. A time offset of 87 seconds between the air intake nozzle at the bow (6 m above sea surface) and the actual gas measurement at the Picarro was determined and the calculated flow rate considered, when correlating the gas data with navigation and weather data provided by the WERUM dship repository (https://dship.geomar.de). The weather data is published separately at doi:10.1594/PANGAEA.983833 .

Atmospheric methane and carbon dioxide concentrations measured during ALKOR cruise AL575 on 2022-07-12

Atmospheric carbon dioxide (CO2) and methane (CH4) concentrations were monitored during AL575 cruise on 2022-07-12 using a cavity ring down spectrometer (Picarro G2301-f CRDS) and GEOMARs 'Atmospheric Intake System' (AIS). The Picarro/AIS system was installed in the wet laboratory (starboard, main deck) of RV ALKOR and was connected by an aluminium tube to an air inlet nozzle placed at the bow of RV ALKOR. The air was pumped via the AIS intake tube with a flow rate of 2.67 litre per minute to the Picarro analyser. The atmospheric CH4, CO2, and water vapour concentrations were determined in real time at 2-3 Hz sampling rate. A time offset of 87 seconds between the air intake nozzle at the bow (6 m above sea surface) and the actual gas measurement at the Picarro was determined and the calculated flow rate considered, when correlating the gas data with navigation and weather data provided by the WERUM dship repository (https://dship.geomar.de). The weather data is published separately at doi:10.1594/PANGAEA.983833 .

Atmospheric methane and carbon dioxide concentrations measured during ALKOR cruise AL575, 29 June 2022 – 12 July 2022, Kiel – Kiel

Atmospheric carbon dioxide (CO2) and methane (CH4) concentrations were monitored during AL575 cruise (29.6.-12.7.2022) using a cavity ring down spectrometer (Picarro G2301-f CRDS) and GEOMARs 'Atmospheric Intake System' (AIS). The Picarro/AIS system was installed in the wet laboratory (starboard, main deck) of RV ALKOR and was connected by an aluminium tube to an air inlet nozzle placed at the bow of RV ALKOR. The air was pumped via the AIS intake tube with a flow rate of 2.67 litre per minute to the Picarro analyser. The atmospheric CH4, CO2, and water vapour concentrations were determined in real time at 2-3 Hz sampling rate. A time offset of 87 seconds between the air intake nozzle at the bow (6 m above sea surface) and the actual gas measurement at the Picarro was determined and the calculated flow rate considered, when correlating the gas data with navigation and weather data provided by the WERUM dship repository (https://dship.geomar.de). The weather data is published separately at doi:10.1594/PANGAEA.983833 .

Atmospheric methane and carbon dioxide concentrations measured during ALKOR cruise AL561 on 2021-08-02

Atmospheric gas concentrations of CH4 and CO2 were measured with Picarro G2301-f analyser during AL561 cruise onboard RV Alkor (02.-12.08.2021). The gas inlet was placed at the bow of RV Alkor, at 6 m above sea level, to identify natural and anthropogenic methane anomalies near the sea surface (Schmidt et al., 2021). Concentration data are correlated with GPS-position and weather data (DSHIP) using time stamps (UTC); calculated in 1-3s averages.

Atmospheric methane and carbon dioxide concentrations measured during ALKOR cruise AL561 on 2021-08-12

Atmospheric gas concentrations of CH4 and CO2 were measured with Picarro G2301-f analyser during AL561 cruise onboard RV Alkor (02.-12.08.2021). The gas inlet was placed at the bow of RV Alkor, at 6 m above sea level, to identify natural and anthropogenic methane anomalies near the sea surface (Schmidt et al., 2021). Concentration data are correlated with GPS-position and weather data (DSHIP) using time stamps (UTC); calculated in 1-3s averages.

Hydrographic parameters, dissolved CH4, atmospheric CH4 and CO2 along the river Elbe, August 2020

In August 2020 the research vessel Albis investigated the river Elbe from Schmielka towards Geesthacht. Basic hydrographic parameters were measured continuously, with a portable ferryBox. Dissolved methane was continuously determined with a degassing unit and a Greenhouse Gas Analyzer from LosGatosResearch. Atmospheric CH4 and CO2 was determined with a Licor system.

Dissolved methane on transects between Helgoland and Cuxhaven, in 2018

On three transects, in October, November and December 2018 with RV Uthörn dissolved methane was determined continuously . We used a degassing unit which was using surface water from the ship's water supply in an overflowing bucket. The gas mixture was subsequently analyzed with a Greenhouse Gas Analyzer from LosGatos. Conversion to methane concentration was performed with water samples, from which the methane content was determined with gas chromatography. Atmospheric methane was measured in certain intervals, by disconnecting the degasser, and connecting the Greenhouse Gas Analyzer with a tubing attached at about 6 m above the water surface at the ships upper deck. For basic hydrographic parameters were determined with a CTD (SSDA Sea and Sun Technology, Trappenkamp, Germany ) was placed in the same bucket as described above.

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