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The hydrochemical and stable isotope composition of fresh surface water in rivers (Sieber and Oder) of a karst area in the southwestern foreland of the Harz Mountains, Germany, was investigated at several occasions between years 1986 and 1992. The campaigns covered different seasonal and hydrological (discharge) conditions, including a snow-melt induced high water at the rivers. Aim of the study was the investigation of the impact of discharge conditions at the river water loosing water to underground passage in the Basin of Pöhlde, dissolving carbonate and sulfate minerals in the karst aquifers, and reappearing in the karst springs of the Rhume river. Besides physical characterization, hydrochemical major and minor elements were measaured, as weill as the carbon isotope composition of DIC, the sulfur and oxygen isotope composition of sulfate, and the oxygen isotope composition of water. Results reflect the impact of hydrological conditions on the subterrestrial carbon and sulfur cycles.
n-alkane peak areas from GC-FID measurements. Compound specific hydrogen and carbon isotope measurements made using GC-IRMS. Samples taken from Auel Maar, Holzmaar, and Schalkenmehrener maar lake sediment cores spanning 60,000 years. Age model information and additional proxy data from the ELSA-20 stack are found in Sirocko et al., 2021 (Nature Geoscience) and Sirocko et al., 2022 (Scientific Reports). Full methodological details are found in Zander et al., 2025 (Rapid Communications in Mass Spectrometry).
A total of 556 samples (3 cm average sample spacing) were collected from the 12 m long Winsenberg section in order to reconstruct a floating timescale using cyclostratigraphic methods and to investigate paleoclimatic dynamics using selected elemental ratios. Samples were measured as a powder covered with Chemplex film on a Bruker S1 Titan 800 portable XRF at the University of Münster with the following settings: 40 kV, 20 mA, no filters, 75 s. Spectra were deconvoluted in Bruker Artrax software, and linearly calibrated using a set of 10 sedimentary standards of known composition and 11 calcite-quart mixtures. The composition of these standards is also included. Selected elemental ratios were tuned via the methods described in the accompanying manuscript, and are included in this dataset as well.
A total of 556 samples (3 cm average sample spacing) were collected from the 12 m long Winsenberg section in order to reconstruct a floating timescale using cyclostratigraphic methods and to investigate paleoclimatic dynamics using selected elemental ratios. Samples were measured as a powder covered with Chemplex film on a Bruker S1 Titan 800 portable XRF at the University of Münster with the following settings: 40 kV, 20 mA, no filters, 75 s. Spectra were deconvoluted in Bruker Artrax software, and linearly calibrated using a set of 10 sedimentary standards of known composition and 11 calcite-quart mixtures. The composition of these standards is also included. Selected elemental ratios were tuned via the methods described in the accompanying manuscript, and are included in this dataset as well.
A total of 556 samples (3 cm average sample spacing) were collected from the 12 m long Winsenberg section in order to reconstruct a floating timescale using cyclostratigraphic methods and to investigate paleoclimatic dynamics using selected elemental ratios. Samples were measured as a powder covered with Chemplex film on a Bruker S1 Titan 800 portable XRF at the University of Münster with the following settings: 40 kV, 20 mA, no filters, 75 s. Spectra were deconvoluted in Bruker Artrax software, and linearly calibrated using a set of 10 sedimentary standards of known composition and 11 calcite-quart mixtures. The composition of these standards is also included. Selected elemental ratios were tuned via the methods described in the accompanying manuscript, and are included in this dataset as well.
A total of 152 samples (8 cm average sample spacing) were analysed for carbonate d13C in order to identify the two characteristic positive excursions associated with the Lower and Upper Kellwasser Events. Measurements on powdered samples weighing 120-150 μg were carried out on a ThermoScientific Delta V Plus mass spectrometer at the University of Münster, using an in-house standard (Kabonat-1; δ13C = 1.46‰, δ18O = -1.19‰) for calibration and an external standard (NBS-19; δ13C = 1.95‰, δ18O = -2.20‰) for long-term performance monitoring.
A total of 556 samples (3 cm average sample spacing) were collected from the 12 m long Winsenberg section in order to reconstruct a floating timescale using cyclostratigraphic methods and to investigate paleoclimatic dynamics using selected elemental ratios. Samples were measured as a powder covered with Chemplex film on a Bruker S1 Titan 800 portable XRF at the University of Münster with the following settings: 40 kV, 20 mA, no filters, 75 s. Spectra were deconvoluted in Bruker Artrax software, and linearly calibrated using a set of 10 sedimentary standards of known composition and 11 calcite-quart mixtures. The composition of these standards is also included. Selected elemental ratios were tuned via the methods described in the accompanying manuscript, and are included in this dataset as well.
The first table provide data on the meteorological conditions of the sites where land snails were collected, and the calculated stable oxygen isotope compositions of local rainwater.
These data include carbon, oxygen and clumped isotope compositions of shells of natural populations of three land snail species (Clausilia pumila, Succinella oblonga and Trochulus hispidus) across Europe. δ¹³C, δ¹⁸O and Δ₄₇ values of snail shells from field-collections were determined in two laboratories (Institute for Nuclear Research, Debrecen, and Geological Institute, ETH Zürich) using IRMS. Detailed analysis and interpretations of the results obtained can be read in the original publication.
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