The data set comprises petrophysical laboratory data for four carbonate rocks and one sandstone – both in solid rock and crushed state. Rock plugs and particle packings of intentionally crushed and sieved material are investigated. Thereby, eight particle size classes with a mean diameter between 0.032 and 9.66 mm are investigated. The data set includes complex electrical conductivity (from Spectral Induced Polarization – SIP), specific surface (from nitrogen adsorption) and porosity (from mercury intrusion MIP). Further analyses include e.g. particle geometry, Nuclear Magnetic Resonance (NMR), Scanning Electron Microscopy (SEM), Computer Tomography (μCT), uniaxial compression strength and mineralogical composition (chemical analysis, XRD).