The dataset presented here encompasses the results of the geochemical analyses of water and recent carbonate samples collected in the El Peinado basin located in the Southern Puna Plateau in Catamarca, Argentina. This system formed by the hypersaline lake Laguna del Peinado, numerous hydrothermal springs, and the small hypersaline lake Laguna Turquesa, provides a natural laboratory to study carbonate formation and the mechanisms that control the incorporation of various elements and isotopes into their structure under a broad range of geochemical conditions. Geochemical analyses include data on the physicochemical parameters, elemental, and isotopic (δ18O, δ2H, δ11B) composition of the waters, and data on the elemental and isotopic (δ18O, δ13C, δ11B) composition of the carbonates. These data allowed us to calculate element partition coefficients and isotopic fractionation between coupled water-carbonate samples from this natural setting, which are also included here. This dataset also includes the results of water modelling using the software PHREEQC, which contains data on the chemical speciation of carbon and boron, the species contributing to total alkalinity, and mineral saturation indices. This information is useful for all those dealing with geochemistry of hypersaline lakes, geochemistry of continental carbonates, as well as paleoenvironmental and paleoclimatic studies using lake carbonates as archives. These data correspond to the research article “On the origin and processes controlling the elemental and isotopic composition of carbonates in hypersaline Andean lakes”. The full description of the data is provided in the data description file.
This dataset was used to analyse the link between chemical weathering and erosion rates across the southern tip of Taiwan. The weathering of silicate minerals is a key component of Earth’s long-term carbon cycle, and it stabilises Earth’s climate by sequestering carbon dioxide (CO2) from the atmosphere – thereby balancing CO2-emissions from the mantle. Conversely, the weathering of accessory carbonate and sulphides acts as a CO2 source. Chemical weathering is fundamentally dependent on the exposure of fresh minerals by erosion. With these data we investigated the link between the exposure of rocks by erosion and the chemical weathering of silicates, carbonates, and sulphides across a landscape with a significant erosion-rate gradient and comparatively little variation in runoff and lithology.
This dataset includes new major element chemistry and water isotopes of river waters collected from across the southern tip of Taiwan as well as associated topographic and lithologic data (tab 1 in the excel table). Moreover, the data include a compilation of published 10Be-derived erosion rates from a subset of the sampled rivers (tab 2 in the excel file) and available major element chemistry from hotsprings in the region (tab 3 in the excel file). Using a mixing model, we derived the cation contributions from silicate and carbonate weathering as well as from hotspring and cyclic sources. Further, we estimated the erosion rates for each sample from the compiled 10Be data and the steepness of river channels, and we estimated saturation and pH in the weathering zone.
For more information please refer to the associated data description file and especially to Bufe et al. (2021).