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Sample information, major element stream chemistry, inversion model setup and results, sample corrections for precipitation and degassing, and CO2 exchange calculations

Tables that include information and calculations associated with water samples collected from rivers in Central Italy. The goal of the project was to determine the carbon budget for the Central Apennine Mountains of Italy, by accounting for weathering reactions that are responsible for either CO2 drawdown or release into the atmosphere. The carbon budget was created by: 1) analysing samples from different water bodies and sources in the Central Apennines (rivers, lakes, and groundwater) for ion and isotope signatures, and 2) by incorporating the ion and isotope signatures from the waters into an inversion model that partitions these signatures into different sources (e.g. minerals, vegetation, atmospheric sources) around the landscape. All data associated with this publication are provided in a single excel spreadsheet that contains a separate tab for each of the 18 Tables. The supplementary data include: 1) Information on the locations of the water samples and associated water bodies, described in the “Sampling Methods” section, 2) ion and isotope measurements from the water samples, described in the “Analytical Procedure” section, 3) the setup and output from the inversion model, and 4) the CO2 calculations that form the basis for the carbon budget, described in the “Data Processing” section. Water samples were collected over two seasons, in winter and summer; data in the tables are divided by sampling season, where indicated in the content description. For a full description of the sampling strategy, data, and methods, please refer to: Erlanger et al. (2024) “Deep CO2 release and the carbon budget of the central Apennines modulated by geodynamics” Nature Geoscience.

Major element stream water chemistry, compiled 10Be erosion rates, and analyses of weathering across an erosion-rate gradient in in southern Taiwan

This dataset was used to analyse the link between chemical weathering and erosion rates across the southern tip of Taiwan. The weathering of silicate minerals is a key component of Earth’s long-term carbon cycle, and it stabilises Earth’s climate by sequestering carbon dioxide (CO2) from the atmosphere – thereby balancing CO2-emissions from the mantle. Conversely, the weathering of accessory carbonate and sulphides acts as a CO2 source. Chemical weathering is fundamentally dependent on the exposure of fresh minerals by erosion. With these data we investigated the link between the exposure of rocks by erosion and the chemical weathering of silicates, carbonates, and sulphides across a landscape with a significant erosion-rate gradient and comparatively little variation in runoff and lithology. This dataset includes new major element chemistry and water isotopes of river waters collected from across the southern tip of Taiwan as well as associated topographic and lithologic data (tab 1 in the excel table). Moreover, the data include a compilation of published 10Be-derived erosion rates from a subset of the sampled rivers (tab 2 in the excel file) and available major element chemistry from hotsprings in the region (tab 3 in the excel file). Using a mixing model, we derived the cation contributions from silicate and carbonate weathering as well as from hotspring and cyclic sources. Further, we estimated the erosion rates for each sample from the compiled 10Be data and the steepness of river channels, and we estimated saturation and pH in the weathering zone. For more information please refer to the associated data description file and especially to Bufe et al. (2021).

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