Most soils develop distinct soil architecture during pedogenesis and soil organic carbon (SOC) is sequestered within a hierarchical system of mineral-organic associations and aggregates. Permafrost soils store large amounts of carbon due to their permanently frozen subsoil and a lack of oxygen in the active layer, but they lack complex soil structure. With permafrost thaw more oxidative conditions and increasing soil temperature presumably enhance the build-up of more complex units of soil architecture and may counterbalance, at least partly, SOC mineralization. We aim to explore the development of mineral-organic associations and aggregates under different permafrost impact with respect to SOC stabilization. This information will be linked to environmental control factors relevant for SOC turnover at the pedon and stand scale to bridge processes occurring at the aggregate scale to larger spatial dimensions. We will combine in situ spectroscopic techniques with fractionation approaches and identify mechanisms relevant for SOC turnover at different scales by multivariate statistics and variogram analyses. From this we expect a deeper knowledge about soil architecture formation in the transition of permafrost soils to terrestrial soils and a scale-spanning mechanistic understanding of SOC cycling in permafrost regions.
Chromium (Cr) is introduced into the environment by several anthropogenic activities. A striking ex-ample is the area around Kanpur in the Indian state of Uttar Pradesh, where large amounts of Cr-containing wastes have been recently illegally deposited. Hexavalent Cr, a highly toxic and mobile contaminant, is present in significant amounts in these wastes, severely affecting the quality of sur-roundings soils, sediments, and ground waters. The first major goal of this study is to clarify the solid phase speciation of Cr in these wastes and to examine its leaching behavior. X-ray diffraction and synchrotron-based X-ray absorption spectroscopy techniques will be employed for quantitative solid phase speciation of Cr. Its leaching behavior will be studied in column experiments performed at un-saturated moisture conditions with flow interruptions simulating monsoon rain events. Combined with geochemical modeling, the results will allow the evaluation of the leaching potential and release kinetics of Cr from the waste materials. The second major goal is to investigate the spatial distribution, speciation, and solubility of Cr in the rooting zone of chromate-contaminated soils surrounding the landfills, and to study the suitability of biochar as novel soil amendment for mitigating the deleterious effects of chromate pollution. Detailed field samplings and laboratory soil incubation studies will be carried out with two agricultural soils and biochar from the Kanpur region.
The decomposition of terrestrial organic material such as leaf litter represents a fundamental ecosystem function in streams that delivers energy for local and downstream food webs. Although agriculture dominates most regions in Europe and fungicides are applied widely, effects of currently used fungicides on the aquatic decomposer community and consequently the leaf decomposition rate are largely unknown. Also potential compensation of such hypothesised adverse effects due to nutrients or higher average water temperatures associated with climate change are not considered. Moreover, climate change is predicted to alter the community of aquatic decomposers and an open question is, whether this alteration impacts the leaf decomposition rate. The current projects follows a tripartite design to answer these research questions. Firstly, a field study in a vine growing region where fungicides are applied in large amounts will be conducted to whether there is a dose-response relationship between the exposure to fungicides and the leaf decomposition rate. Secondly, experiments in artificial streams with field communities will be carried out to assess potential compensatory mechanisms of nutrients and temperature for effects of fungicides. Thirdly, field experiments with communities exhibiting a gradient of taxa sensitive to climate change will be used to investigate potential climate-related effects on the leaf decomposition rate.
Water is an intrinsic component of ecosystems acting as a key agent of lateral transport for particulate and dissolved nutrients, forcing energy transfers, triggering erosion, and driving biodiversity patterns. Given the drastic impact of land use and climate change on any of these components and the vulnerability of Ecuadorian ecosystems with regard to this global change, indicators are required that not merely describe the structural condition of ecosystems, but rather capture the functional relations and processes. This project aims at investigating a set of such functional indicators from the fields of hydrology and biogeochemistry. In particular we will investigate (1) flow regime and timing, (2) nutrient cycling and flux rates, and (3) sediment fluxes as likely indicators. For assessing flow regime and timing we will concentrate on studying stable water isotopes to estimate mean transit time distributions that are likely to be impacted by changes in rainfall patterns and land use. Hysteresis loops of nitrate concentrations and calculated flux rates will be used as functional indicators for nutrient fluxes, most likely to be altered by changes in temperature as well as by land use and management. Finally, sediment fluxes will be measured to indicate surface runoff contribution to total discharge, mainly influenced by intensity of rainfall as well as land use. Monitoring of (1) will be based on intensive sampling campaigns of stable water isotopes in stream water and precipitation, while for (2) and (3) we plan to install automatic, high temporal-resolution field analytical instruments. Based on the data obtained by this intensive, bust cost effective monitoring, we will develop the functional indicators. This also provides a solid database for process-based model development. Models that are able to simulate these indicators are needed to enable projections into the future and to investigate the resilience of Ecuadorian landscape to global change. For the intended model set up we will couple the Catchment Modeling Framework, the biogeochemical LandscapeDNDC model and semi-empirical models for aquatic diversity. Global change scenarios will then be analyzed to capture the likely reaction of functional indicators. Finally, we will contribute to the written guidelines for developing a comprehensive monitoring program for biodiversity and ecosystem functions. Right from the beginning we will cooperate with four SENESCYT companion projects and three local non-university partners to ensure that the developed monitoring program will be appreciated by locals and stakeholders. Monitoring and modelling will focus on all three research areas in the Páramo (Cajas National Park), the dry forest (Reserva Laipuna) and the tropical montane cloud forest (Reserva Biologica San Francisco).
It has been suggested that dying and decaying fine roots and root exudation represent important, if not the most important, sources of soil organic carbon (SOC) in forest soils. This may be especially true for deep-reaching roots in the subsoil, but precise data to prove this assumption are lacking. This subproject (1) examines the distribution and abundance of fine roots (greater than 2 mm diameter) and coarse roots (greater than 2 mm) in the subsoil to 240 cm depth of the three subsoil observatories in a mature European beech (Fagus sylvatica) stand, (2) quantifies the turnover of beech fine roots by direct observation (mini-rhizotron approach), (3) measures the decomposition of dead fine root mass in different soil depths, and (4) quantifies root exudation and the N-uptake potential with novel techniques under in situ conditions with the aim (i) to quantify the C flux to the SOC pool upon root death in the subsoil, (ii) to obtain a quantitative estimate of root exudation in the subsoil, and (iii) to assess the uptake activity of fine roots in the subsoil as compared to roots in the topsoil. Key methods applied are (a) the microscopic distinction between live and dead fine root mass, (b) the estimation of fine and coarse root age by the 14C bomb approach and annual ring counting in roots, (c) the direct observation of the formation and disappearance of fine roots in rhizotron tubes by sequential root imaging (CI-600 system, CID) and the calculation of root turnover, (d) the measurement of root litter decomposition using litter bags under field and controlled laboratory conditions, (e) the estimation of root N-uptake capacity by exposing intact fine roots to 15NH4+ and 15NO3- solutions, and (f) the measurement of root exudation by exposing intact fine root branches to trap solutions in cuvettes in the field and analysing for carbohydrates and amino acids by HPLC and Py-FIMS (cooperation with Prof. A. Fischer, University of Trier). The obtained data will be analysed for differences in root abundance and activity between subsoil (100-200 cm) and topsoil (0-20 cm) and will be related to soil chemical and soil biological data collected by the partner projects that may control root turnover and exudation in the subsoil. In a supplementary study, fine root biomass distribution and root turnover will also be studied at the four additional beech sites for examining root-borne C fluxes in the subsoil of beech forests under contrasting soil conditions of different geological substrates (Triassic limestone and sandstone, Quaternary sand and loess deposits).
Gasaustausch findet in der Atmosphäre primär durch turbulenten und laminaren Fluss statt. Im Boden dagegen spielt advektiver Gastransport eine untergeordnete Rolle, stattdessen dominiert Diffusion die Transportprozesse. Trotz der Unterschiedlichkeit und scheinbaren Unabhängigkeit dieser Prozesse wurde während Freilanduntersuchungen ein Anstieg von Gastransportraten im Boden um mehrere 10 % während Phasen starken Windes beobachtet. Dieser Anstieg ist auf wind-induzierte Druckfluktuationen zurückzuführen, die sich in das luftgefüllte Porensystem des Bodens fortpflanzen und zu einem minimal oszillierenden Luftmassenfluss führen (Pressure-pumping Effekt). Durch den oszillierenden Charakter des Luftmassenflusses ist der direkte Beitrag zum Gastransport sehr gering. Die damit einhergehende Dispersion führt jedoch zu einem Anstieg der effektiven Gastransportrate entgegen des Konzentrationsgradienten. Wird der Pressure-pumping (PP) Effekt bei der Bestimmung von Gasflüssen mit der Gradienten- und Kammermethode nicht berücksichtigt, kann dies zu großen Unsicherheiten in der Bestimmung von Bodengasflüssen führen. Insbesondere für das langfristige Monitoring von treibhausrelevanten Gasflüssen stellen diese Unsicherheiten ein zentrales Problem dar. Wir stellen vier Hypothesen auf:(H1) Der PP-Effekt ist abhängig von Bodeneigenschaften.(H2) Die Ausprägung von Luftdruckfluktuationen ist abhängig von der Rauigkeit verschiedener Landnutzungen (Wald, Grasland, landwirtschaftliche Kulturen, Stadt)(H3) Kammermessungen werden durch Luftdruckfluktuationen beeinflusst.(H4) Der Austausch und Umsatz von Methan in Böden von Mittelgebirgswäldern wird durch den PP-Effekt verstärkt. Die Hypothesen 1, 3 und 4 werden mittels Laboruntersuchungen von Proben verschiedener Böden und Bodenfeuchtebedingungen überprüft. Die Hypothese 2 wird durch Freilandmessungen an verschiedenen Standorten überprüft. Ziele des Vorhabens sind: (Z1) Modelle zu entwickeln, die die Quantifizierung des Einflusses der Bodenstruktur auf den PP-Effekt ermöglichen, (Z2) den Effekt der Oberflächenrauigkeit auf Luftdruckschwankungen zu quantifizieren, (Z3) Schwellenwerte zu definieren, die die Bestimmung von Standorten mit ausgeprägtem PP-Effekt ermöglichen, (Z4) Faktoren für die Berücksichtigung des PP-Effekts für Kammermessungen zu entwickeln, (Z5) Faktoren für die Berücksichtigung des PP-Effekts für die Gradienten Methode zu entwickeln, (Z6) den Einfluss des PP-Effekts auf die Methanaufnahme von Böden in Mittelgebirgswäldern zu bestimmen. Ein besseres Verständnis des bisher nur unzureichend untersuchten PP-Effekts wird wesentlich dazu beitragen, die Verlässlichkeit und Präzision von Messungen von Bodengasflüssen zu steigern, die die Grundlage für weitergehende Forschung darstellen.
We are currently facing the urgent need to improve our understanding of carbon cycling in subsoils, because the organic carbon pool below 30 cm depth is considerably larger than that in the topsoil and a substantial part of the subsoil C pool appears to be much less recalcitrant than expected over the last decades. Therefore, small changes in environmental conditions could change not only carbon cycling in topsoils, but also in subsoils. While organic matter stabilization mechanisms and factors controlling its turnover are well understood in topsoils, the underlying mechanisms are not valid in subsoils due to depth dependent differences regarding (1) amounts and composition of C-pools and C-inputs, (2) aeration, moisture and temperature regimes, (3) relevance of specific soil organic carbon (SOC) stabilisation mechanisms and (4) spatial heterogeneity of physico-chemical and biological parameters. Due to very low C concentrations and high spatio-temporal variability of properties and processes, the investigation of subsoil phenomena and processes poses major methodological, instrumental and analytical challenges. This project will face these challenges with a transdisciplinary team of soil scientists applying innovative approaches and considering the magnitude, chemical and isotopic composition and 14C-content of all relevant C-flux components and C-fractions. Taking also the spatial and temporal variability into account, will allow us to understand the four-dimensional changes of C-cycling in this environment. The nine closely interlinked subprojects coordinated by the central project will combine field C-flux measurements with detailed analyses of subsoil properties and in-situ experiments at a central field site on a sandy soil near Hannover. The field measurements are supplemented by laboratory studies for the determination of factors controlling C stabilization and C turnover. Ultimately, the results generated by the subprojects and the data synthesized in the coordinating project will greatly enhance our knowledge and conceptual understanding of the processes and controlling factors of subsoil carbon turnover as a prerequisite for numerical modelling of C-dynamics in subsoils.
Unwetter richten in der Schweiz jährlich Schäden von rund 360 Millionen an (Mittel der Jahre 1972 bis 2007, teuerungsbereinigt). Diese Schäden werden von der WSL, im Auftrag des Bundesamtes für Umwelt BAFU, seit 1972 aufgrund von Zeitungsmeldungen systematisch erfasst und analysiert. Berücksichtigt werden Schäden durch auf natürliche Weise ausgelöste Hochwasser, Murgänge, Rutschungen und (seit 2002) Felsbewegungen. Die vorgeherrschten Witterungsbedingungen werden, wenn möglich, als Ursache ebenfalls aufgenommen. Die Datenbank wird in Bezug auf Ort, Ausmass und Ursache, aber auch im Hinblick auf die zeitliche und räumliche Verteilung der Unwetterereignisse ausgewertet und analysiert. Die Ergebnisse werden jährlich in der Zeitschrift Wasser Energie Luft publiziert. Die Schadensdaten werden öffentlichen Institutionen auf Anfrage zur Verfügung gestellt und dienen somit als breite Informationsbasis für die Gefahrenbeurteilung.
Introduction: In Malaysia, excessive nutrients from livestock waste management systems are currently released to the environment. Particularly, large amounts of manure from intensive pig production areas are being excreted daily and are not being fully utilised. Alternatively, the excess manure can be applied as an organic fertiliser source in neighbouring cropping systems on the small landholdings of the pig farms to improve soil fertility so that its nutrients will be available for crop uptake instead of being discharged into water streams. Thus, there is a need for better tools to analyse the present situation, to evaluate and monitor alternative livestock production systems and manure management scenarios, and to support farmers in the proper management of manure and fertiliser application. Such tools are essential to quantify, and assess nutrient fluxes, manure quality and content, manure storage and application rate to the land as well as its environmental effects. Several computer models of animal waste management systems to assist producers and authorities are now available. However, it is felt that more development is needed to adopt such models to the humid tropics and conditions of Malaysia and other developing countries in the region. Objectives: The aim is to develop a novel model to evaluate nutrient emission scenarios and the impact of livestock waste at the landscape or regional level in humid tropics. The study will link and improve existing models to evaluate emission of N to the atmosphere, and leaching of nutrients to groundwater and surface water. The simulation outputs of the models will be integrated with a GIS spatial analysis to model the distribution of nutrient emission, leaching and appropriate manure application on neighbouring crop lands and as an information and decision support tool for the relevant users.
Aktuelle wissenschaftliche Studien legen nahe, dass die aktuelle Erderwärmung durch Treibhausgasemissionen hervorgerufen wird, die vom Menschen verursacht sind. Um gegen diese Entwicklung geeignete Maßnahmen ergreifen zu können bzw. um zu überprüfen, ob solche Maßnahmen von Erfolg gekrönt sind, ist es notwendig, die Schadstoffkonzentrationen inklusive der zugehörigen Emissionsquellen genau zu kennen. Diese Informationen sind bisher jedoch sehr lückenhaft und beruhen auf sogenannten 'bottom-up' Berechnungen. Da diese Kalkulationen nicht auf direkten Messungen beruhen, weisen sie große Ungenauigkeiten auf und sind außerdem nicht in der Lage, bisher unbekannte Emissionsquellen zu identifizieren. In dem hier vorgestellten Projekt soll ein mesoskaliges Netzwerk für die Überwachung von Luftschadstoffen wie CO2, CH4, CO, NO2 und O3 aufgebaut werden, das auf dem neuartigen Konzept der differentiellen Säulenmessung beruht. Bei diesem Ansatz wird die Differenz zwischen den Luftsäulen luv- und leewärts einer Stadt gebildet. Diese Differenz ist proportional zu den emittierten Schadstoffen und somit eine Maßzahl für die Emissionen, welche in der Stadt generiert werden.Mithilfe dieser Methode wird es in Zukunft möglich sein, städtische Emissionen über lange Zeiträume hinweg zu überwachen. Damit können neue Informationen über die Generierung und Umverteilung von Luftschadstoffen gewonnen werden. Wir werden u.a. folgende zentrale Fragen beantworten: Wie verhält sich der tatsächliche Trend der CO2, CH4 und NO2 Emissionen in München über mehrere Jahre? Wo sind die Emissions-Hotspots? Wie akkurat sind die bisherigen 'bottom-up' Abschätzungen? Wie effektiv sind die Maßnahmen zur Emissionsreduzierung tatsächlich? Sind vor allem für Methan weitere Maßnahmen zur Reduzierung der Emissionen notwendig? Zu diesem Zweck werden wir ein vollautomatisiertes Messnetzwerk aufbauen und passende Methoden zur Modellierung entwickeln, welche u.a. auf STILT (Stochastic Time-Inverted Lagrangian Transport) und CFD (Computational Fluid Dynamics) basieren. Mithilfe der Modellierungsresultate werden wir eine Strategie entwerfen, wie städtische Netzwerke zur Überwachung von Luftschadstoffen aufgebaut werden müssen, um repräsentative Ergebnisse zu erhalten. Außerdem können mit den so gewonnenen städtischen Emissionszahlen z.B. dem Stadtreferat, den Stadtwerken München oder der Bayerischen Staatsregierung Möglichkeiten zur Beurteilung der Effektivität der angewandten Klimaschutzmaßnahmen an die Hand gegeben werden. Das hier vorgestellte Messnetzwerk dient somit als Prototyp, um die grundlegenden Fragen zum Aufbau eines solchen Sensornetzwerks zu klären, damit objektive Aussagen zu städtischen Emissionen möglich werden. Dieses Projekt ist weltweit einmalig und wird zukunftsweisende Ergebnisse liefern.
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