Der Umgang mit Nichtlinearitäten und die Frage des Upscaling stellen eine der größten Herausforderungen für technische und umweltrelevante Anwendungen im Gebiet der Strömungs- und Transportphänomene in porösen Medien dar. Eine Vielzahl hierarchischer (räumlicher und zeitlicher) Skalen können in porösen Medien identifiziert werden, die im Allgemeinen mit deren Heterogenitätsstrukturen zusammenhängen. Strömungs- und Transportphänomene können von gekoppelten Mechanismen verursacht oder beeinflusst werden, die von einem nichtlinearen Zusammenspiel von physikalischen, (geo-)chemischen und/oder biologischen Prozessen herrühren. Um Probleme auf diesem Feld sinnvoll angehen zu können, ist eine interdisziplinäre Umgebung unerlässlich. Die beteiligten Wissenschaftlerinnen und Wissenschaftler zeichnen sich in den unterschiedlichsten Arbeitsgebieten aus: angewandte Mathematik, Umwelt- und Bauingenieurwesen, Geowissenschaften und Erdölingenieurwissenschaften. Die gemeinsamen niederländisch-deutschen Forschungsprojekte werden an der TU Delft, der TU Eindhoven, der Universität Utrecht und der Universität Stuttgart durchgeführt. Grundlagenforschung, so wie etwa die Anwendung stochastischer Modelle und die Entwicklung effizienter numerischer Methoden, soll mit angewandter Forschung auf Feldern wie der Optimierung von Brennstoffzellen, Sequestrierung von CO2 oder der Vorhersage von Hangrutschungen verbunden werden. Als mögliche weiterführende Themen werden auch Anwendungen in der Papierherstellung oder der Biomechanik angestrebt. Ein zentraler Aspekt des Internationalen Graduiertenkollegs ist ein Lehrprogramm, das die Unterstützung von Lehre und Forschung von jungen Wissenschaftlerinnen und Wissenschaftlern zum Ziel hat. Dies soll erreicht werden, indem anspruchsvolle Kurse angeboten werden, die typischerweise die Fragestellungen der jungen Wissenschaftler abdecken. Außerdem soll alle vier Wochen via Videokonferenz ein Graduiertenseminar zur Diskussion von Forschungsergebnissen stattfinden. Es soll weiterhin ein Austauschprogramm geben, das Doktorandinnen und Doktoranden erlaubt, sechs bis neun Monate im Partnerland zu verbringen. Das somit entstehende internationale und interdisziplinäre Umfeld wird es Doktorandinnen und Doktoranden ermöglichen, effizient Spitzenforschung auf dem Feld der Nichtlinearitäten und des Upscaling im Untergrund durchzuführen.
Aims: Floods in small and medium-sized river catchments have often been a focus of attention in the past. In contrast to large rivers like the Rhine, the Elbe or the Danube, discharge can increase very rapidly in such catchments; we are thus confronted with a high damage potential combined with almost no time for advance warning. Since the heavy precipitation events causing such floods are often spatially very limited, they are difficult to forecast; long-term provision is therefore an important task, which makes it necessary to identify vulnerable regions and to develop prevention measures. For that purpose, one needs to know how the frequency and the intensity of floods will develop in the future, especially in the near future, i.e. the next few decades. Besides providing such prognoses, an important goal of this project was also to quantify their uncertainty. Method: These questions were studied by a team of meteorologists and hydrologists from KIT and GFZ. They simulated the natural chain 'large-scale weather - regional precipitation - catchment discharge' by a model chain 'global climate model (GCM) - regional climate model (RCM) - hydrological model (HM)'. As a novel feature, we performed so-called ensemble simulations in order to estimate the range of possible results, i.e. the uncertainty: we used two GCMs with different realizations, two RCMs and three HMs. The ensemble method, which is quite standard in physics, engineering and recently also in weather forecasting has hitherto rarely been used in regional climate modeling due to the very high computational demands. In our study, the demand was even higher due to the high spatial resolution (7 km by 7 km) we used; presently, regional studies use considerably larger grid boxes of about 100 km2. However, our study shows that a high resolution is necessary for a realistic simulation of the small-scale rainfall patterns and intensities. This combination of high resolution and an ensemble using results from global, regional and hydrological models is unique. Results: By way of example, we considered the low-mountain range rivers Mulde and Ruhr and the more alpine Ammer river in this study, all of which had severe flood events in the past. Our study confirms that heavy precipitation events will occur more frequently in the future. Does this also entail an increased flood risk? Our results indicate that in any case, the risk will not decrease. However, each catchment reacts differently, and different models may produce different precipitation and runoff regimes, emphasizing the need of ensemble studies. A statistically significant increase of floods is expected for the river Ruhr in winter and in summer. For the river Mulde, we observe a slight increase of floods during summer and autumn, and for the river Ammer a slight decrease in summer and a slight increase in winter.
Water is an intrinsic component of ecosystems acting as a key agent of lateral transport for particulate and dissolved nutrients, forcing energy transfers, triggering erosion, and driving biodiversity patterns. Given the drastic impact of land use and climate change on any of these components and the vulnerability of Ecuadorian ecosystems with regard to this global change, indicators are required that not merely describe the structural condition of ecosystems, but rather capture the functional relations and processes. This project aims at investigating a set of such functional indicators from the fields of hydrology and biogeochemistry. In particular we will investigate (1) flow regime and timing, (2) nutrient cycling and flux rates, and (3) sediment fluxes as likely indicators. For assessing flow regime and timing we will concentrate on studying stable water isotopes to estimate mean transit time distributions that are likely to be impacted by changes in rainfall patterns and land use. Hysteresis loops of nitrate concentrations and calculated flux rates will be used as functional indicators for nutrient fluxes, most likely to be altered by changes in temperature as well as by land use and management. Finally, sediment fluxes will be measured to indicate surface runoff contribution to total discharge, mainly influenced by intensity of rainfall as well as land use. Monitoring of (1) will be based on intensive sampling campaigns of stable water isotopes in stream water and precipitation, while for (2) and (3) we plan to install automatic, high temporal-resolution field analytical instruments. Based on the data obtained by this intensive, bust cost effective monitoring, we will develop the functional indicators. This also provides a solid database for process-based model development. Models that are able to simulate these indicators are needed to enable projections into the future and to investigate the resilience of Ecuadorian landscape to global change. For the intended model set up we will couple the Catchment Modeling Framework, the biogeochemical LandscapeDNDC model and semi-empirical models for aquatic diversity. Global change scenarios will then be analyzed to capture the likely reaction of functional indicators. Finally, we will contribute to the written guidelines for developing a comprehensive monitoring program for biodiversity and ecosystem functions. Right from the beginning we will cooperate with four SENESCYT companion projects and three local non-university partners to ensure that the developed monitoring program will be appreciated by locals and stakeholders. Monitoring and modelling will focus on all three research areas in the Páramo (Cajas National Park), the dry forest (Reserva Laipuna) and the tropical montane cloud forest (Reserva Biologica San Francisco).
Salinity reduces the productivity of cucumber (Cucumis sativus L.) through osmotic and ionic effects. For given atmospheric conditions we hypothesize the existence of an optimal canopy structure at which water use efficiency is maximal and salt accumulation per unit of dry matter production is minimal. This canopy structure optimum can be predicted by integrating physiological processes over the canopy using a functional-structural plant model (FSPM). This model needs to represent the influence of osmotic stress on plant morphology and stomatal conductance, the accumulation of toxic ions and their dynamics in the different compartments of the system, and their toxic effects in the leaf. Experiments will be conducted to parameterize an extended cucumber FSPM. In in-silico experiments with the FSPM we attempt to identify which canopy structure could lead to maximum long-term water use efficiency with minimum ionic stress. The results from in-silico experiments will be evaluated by comparing different canopy structures in greenhouses. Finally, the FSPM will be used to investigate to which extent the improvement of individual mechanisms of salt tolerance like reduced sensitivity of stomatal conductance or leaf expansion can contribute to whole-plant salt tolerance.
During microbial turnover of organic chemicals in soil, non-extractable residues (NER) are formed frequently. Studies on NER formation usually performed with radioisotope labelled tracer compounds are limited to localisation and quantitative analyses but their chemical composition is left unknown. Recently, we could show for 2,4-dichlorophenoxyacetic acid and ibuprofen that during microbial turnover in soil nearly all NER were derived from microbial biomass, since degrading bacteria use the pollutant carbon for their biomass synthesis. Their cell debris is subsequently stabilised within soil organic matter (SOM) forming biogenic NER (bioNER). It is still unknown whether bioNER are also formed during biodegradation of other, structurally different compound classes of organic contaminants. Therefore, agricultural soil will be incubated with labelled compounds of five classes of commonly used and emerging pesticides: organophosphate, phenylurea, triazinone, benzothiadiazine and aryloxyphenoxypropionic acid. The fate of the label will be monitored in both living and non-living SOM pools and the formation of bioNER will be quantified for each compound over extended periods of time. In addition, soil samples from long-term lysimeter studies with 14C-labelled pesticide residues (e.g. triazine, benzothiazole and phenoxypropionic acid group) will be also analysed for bioNER formation. The results will be summarised to identify the metabolic conditions of microorganisms needed for bioNER formation and to develop an extended concept of risk assessment including bioNER formation in soils.
The sorption of anions in geotechnical multibarrier systems of planned high level waste repositories (HLWR) and of non-ionic and organic pollutants in conventional waste disposals are in the center of recent research. In aquatic systems, persistent radionuclides such as 79Se, 99Tc, 129I exist in a form of anions. There is strongly increasing need to find materials with high sorption capacities for such pollutants. Specific requirements on barrier materials are long-term stability of adsorbent under various conditions such as T > 100 C, varying hydrostatic pressure, and the presence of competing ions. Organo-clays are capable to sorb high amounts of cations, anions and non-polar molecules simultaneously having selectivity for certain ions. This project is proposed to improve the understanding of sorption and desorption processes in organo-clays. Additionally, the modification of material properties under varying chemical and thermal conditions will be determined by performing diffusion and advection experiments. Changes by sorption and diffusion will be analyzed by determining surface charge and contact angles. Molecular simulations on models of organo-clays will be conducted in an accord with experiments with aim to understand and analyze experimental results. The computational part of the project will profit from the collaboration of German partner with the group in Vienna, which has a long standing experience in a modeling of clay minerals.
During the first project period we developed a general approach to quantify soil pore structure based on X-ray micro-tomography Vogel et al. (2010) which is applicable at various scales to cover soil pores larger that 0.05 mm in a representative way. Based on this method we generated equivalent network models to numerically simulate flow and transport of dissolved chemicals. The existing network model was extended to handle reactive transport and infiltration processes which are especially critical for matter flux in soil. The results were compared to experimental findings. The original research question 'what does a particle see on its way through soil' could be answered quantitatively for various boundary conditions including steady state flux and infiltration. However, we identified various critical aspects of the proposed modeling concept which will be in the focus of the second period. This includes 1) the spatial arrangement of interfaces having different quality which is crucial for chemical interactions and pore scale water dynamics, 2) the realistic multiphase dynamics at the pore scale which need to reflect the dynamic pressure and movement of trapped non-wetting phase and 3) the parametrization of structural complexity which need to be developed beyond the measurement of continuous Minkowski functions to allow the development of quantitative relations between structure and function. These aspects will be explored in a joint experiments in cooperation with partners within the SPP.
Elaboration of various Guidance Documents (R1-Efficiency, Definitions, Waste Hierarchy, Exemptions and Separate Collection, Mixing Ban) - Elaboration of an EU-Guidance Document for the calculation of the R1-Efficiency factor for municipal solid waste incineration plants in collaboration with the working group on R1-Efficiency consisting of MS representatives, other stakeholders including the industry and NGOs - Organisation and realisation of Awareness Raising Events on the legal implementation of the new Waste Framework Directive (2008/98/EC) and its practical enforcement in 15 Member States - Guidance for implementation and enforcement of the Waste Shipment Regulation (1013/2006/EC) (Article 18, Annex 7, Article 49 and 50), Proposal for a guideline on financial guarantee under the waste shipment regulation, including stakeholder involvement - Revision on guidance document for waste management planning, including stakeholder involvement - Identification of need for minimum treatment standards for waste streams and treatment methods not covered by IPPC, pursuant to Article 27, elaboration of a corresponding proposals for need of action, including stakeholder involvement - Elaboration and Management of an Electronic forum for information exchange as regards the waste shipment regulation.
(1) Terrestrische Biota der Antarktis sind durch geografische Isolation und inselhafte Verteilung geprägt. Die isolierte Lage der Antarktis und die Beschränkung auf weit voneinander entfernte kleine Habitatflecken haben zu einem hohen Endemiten-Anteil und einer starken Regionalisierung der Fauna und Flora geführt. Genetische Differenzierung, lokale Anpassung und die Evolution kryptischer Arten sind die Folge. Die Biodiversitäts-Konvention (CBD) betrachtet genetische Diversität als einen Eckpfeiler biologischer Vielfalt und stellt sie damit in eine Reihe mit der Diversität von Arten und Ökosystemen. Durch Einschleppung ortsfremder Arten und Homogenisierung bislang getrennter Genpools bedroht der Mensch jedoch zunehmend diese Isolation und genetische Differenzierung vieler antarktischer Biota. (2) Obwohl Flechten als wichtigste Primärproduzenten antarktische terrestrische Lebensräume dominieren, fehlen zurzeit Daten zu ihrer genetischen Struktur und Diversität. Der Umfang inter- und intrakontinentalen Genflusses ist bisher völlig unbekannt. Es ist deswegen derzeit unmöglich, den aktuellen und zukünftigen menschlichen Einfluss auf antarktische Flechtenpopulationen auch nur annähernd abzuschätzen.(3) Wir schlagen vor, mittels molekulargenetischer Daten die populationsgenetische Struktur von sechs weit verbreiteten Flechtenarten mit unterschiedlichen Ausbreitungsstrategien zu untersuchen. Dabei soll die Nullhypothese überprüft werden, dass Flechtenpopulationen genetisch nicht differenziert sind. Zusätzlich wollen wir abschätzen, ob menschliche Aktivitäten zur Einschleppung ortsfremder Arten oder Genotypen und zur Homogenisierung von Genpools beitragen. Hierfür sollen Lokalitäten mit hohem und niedrigem menschlichen Einfluss verglichen werden. Das Projekt schafft damit unverzichtbare Grunddaten für die Entwicklung von Schutzstrategien in der Antarktis.
In diesem Heft sind die wichtigsten Aspekte zu oberflächennahen Rohstoffen zusammengestellt: - Fördermengen, Arbeitsplätze, wirtschaftliche Bedeutung - Verteilung der Vorkommen im Land - Standortgebundenheit - Raumnutzungskonflikte - Transportkostenempfindlichkeit - Marine Lagerstätten - Zuständigkeiten in Mecklenburg-Vorpommern, Bergrecht - Gesetzlicher Auftrag der Raumordnung und Landesplanung - Planerische Umsetzung - Ausgleich der Nutzungskonflikte - Bedarfsprognose - Reichweite der in der Regionalen Raumordnungsprogrammen sichergestellten Flächen - Rekultivierung - Wiedernutzbarmachung
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