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Distribution and concentration of nutrients, carbon compounds and methane in water samples in the southern German Bight (North Sea) in September 2024 during the MOSES Sternfahrt 12

The 12th Sternfahrt of the ElbeXtreme and MOSES projects took place in 2024 from September 02 to 13, within the area of the German Bight (North Sea). Its objective was to get a more systematic grid of sampling data by spatially integrated onboard sensors. Therefore, the MOSES-laboratory container was installed again. Water samples were taken from the surface with a rosette or via Niskin bottles. The first part of the cruise was conducted by the research vessel (RV) Ludwig Prandtl, starting on the 2nd of September on Heligoland. From there, the crew navigated towards Cuxhaven covering some stations from previous MOSES cruises. For the next days, the ship followed a rectangular track, shifting northward each day, heading towards Heligoland again. Due to strong winds, the sampling stations were reduced to three on the last day. On Heligoland the RV Mya II took over the laboratory container and other sampling equipment for the second part of the cruise. Persistent strong winds delayed the start of the cruise until September 11. Since most of the planned stations were already covered from the RV Ludwig Prandtl, the crew decided to expand the sampling area using a more systematic zig-zag line. With the return of Mya II in the afternoon of the 13th September 2024, the campaign was successfully finished.

Continuous recordings of environmental parameters at station 22, Flueggesand (2022-10 - 2024-09)

Additionally, at four shallow water stations (Booknis Eck, Buelk, Behrensdorf and Katharinenhof) temperature, salinity and dissolved oxygen are continuously logged at 2-3 m depth by self-contained data loggers. These are: (I) MiniDOT loggers (Precision Measurement Engineering; http://pme.com; ±10 µmol L-1 or ±5 % saturation) including copper antifouling option (copper plate and mesh) to measure dissolved oxygen concentration and (II) DST CT salinity & temperature loggers (Star-Oddi; http://star-oddi.com; ±1.5 mS cm-1) to record the conductivity. Both sensor types additionally record water temperature with an accuracy of ± 0.1 °C. The sampling interval was set to 30 minutes for all parameters. In context of the long-term monitoring project RegLocDiv (Regional-Local-Diversity) by M. Wahl (Franz, M. et al. 2019a), another seven stations were equipped with the same two types of sensors at 4-6 m depth to continuously record environmental parameters (again: temperature, salinity, dissolved oxygen) and included into this data set. These stations are at: Falshoeft, Booknis Eck, Schoenberg, Westermarkelsdorf, Staberhuk, Kellenhusen and Salzhaff (abandoned in 2023). Since 2021, in the context of implementing a reef monitoring to fulfil obligations by the EU Habitats Directive, step-by-step, eleven further stations were installed at reefs in the Schleswig-Holstein Baltic Sea. These are at: Platengrund (14 m depth) and Mittelgrund (8 m) (both since 2021), at Walkyriengrund (9 m), Brodtener Ufer (8 m), Außenschlei (11 m), Kalkgrund (8 m), Stollergrund (7.5 m) and Flueggesand (10 m) (all since 2022), as well as at Gabelsflach (10 m), Sagasbank (8.5 m) and Stabehuk (11.5 m) (all since 2023). Again, at all of these 11 stations, temperature, salinity and dissolved oxygen are continuously logged by self-contained data loggers: Conductivity (and temperature) is logged by HOBO® Salt Water Conductivity/Salinity Data Logger (Onset Computer Corporation, Bourne, MA, USA; https://www.onsetcomp.com) using the U2X protective housing to prevent fouling on the sensors. The same MiniDOT loggers (Precision Measurement Engineering) as at the above mentioned more shallow stations (including antifouling copper plate and mesh) are used to measure dissolved oxygen concentration. Dissolved oxygen concentration data measured by the MiniDOT loggers are corrected for a depth of 10 m (or 2,5 m on the shallow stations) using the software provided by the manufacturer. Additionally, a manual compensation for salinity was calculated (see details in Franz, M. et al. 2019b). Quality control was carried out by spike and gradient tests, following recommendations of SeaDataNet quality control procedures (see https://seadatanet.org/Standards/Data-Quality-Control). All data values were flagged according to applied quality checks using the following flags: 1 = Pass, 2 = Suspect, 3 = Fail, 4 = Visually suspect, 5 = Salinity compensation fail (further explanations can be found in Franz, M. et al. 2019b).

High-resolution measurements of essential climate variables in the North Sea from the autonomous surface vehicle HALOBATES during RV Heincke cruise HE626

The autonomous surface vehicle HALOBATES collected key climate variables, including sea surface temperature (SST) and salinity (SSS), during the RV Heincke cruise HE626 in the German Bight. HALOBATES recorded SST and SSS at seven different depths with a high vertical resolution of approximately 10 cm, ranging from the near-surface layer (NSL) (between 30 and 100 cm) to the sea-surface microlayer (SML) (uppermost millimeter). Temperature and conductivity (used for salinity calculation) were measured using conductivity, temperature, and depth (CTD) sensors connected to a flow-through system on HALOBATES. Additional temperature sensors were placed beneath the catamaran to capture in-situ temperature at six depths within the NSL. Salinity measurements were adjusted using discrete water samples to correct for any sensor biases. During the operation, two data loggers equipped with meteorological stations on the catamaran monitored essential weather conditions. HALOBATES was in operation from July 21, 2023, to August 8, 2023.

Continuous thermosalinograph oceanography along RV POLARSTERN cruise track PS148

Raw data acquired by two SBE21 thermosalinograph and two auxiliary SBE38 temperature sensor (Sea-Bird Scientific, USA) installed in an underway seawater flow-through system on board RV Polarstern were processed to yield a calibrated and validated data set of temperature and salinity along the cruise track. Data were downloaded from DAVIS SHIP data base (https://dship.awi.de) at a resolution of 1 sec, and converted to temperature and conductivity using the pre-deployment factory calibration coefficients. The converted data were averaged to 1 min values, outliers were removed, and sensor drift was corrected using coefficients obtained from a post-season calibration performed at Sea-Bird at the end of the measurement season. Salinity was calculated from internal temperature, conductivity and pressure according to the PSS-78 Practical Salinity Scale. Processed data are provided as 1 min means of seawater temperature, conductivity and salinity, aligned with position data taken from the master track. Quality flags are appended according to the SeaDataNet Data Quality Control Procedures (version from May 2010). More details are described in the attached processing report.

High-resolution measurements of essential climate variables in the North Sea from the autonomous surface vehicle HALOBATES during RV Heincke cruise HE614

The autonomous surface vehicle HALOBATES measured Essential Climate Variables (ECV), such as sea surface temperature (SST) and salinity (SSS), during the RV Heincke cruise HE614 in the German Bight. HALOBATES captured the SST and SSS at seven depths with a high vertical resolution of about 10 cm, from the near-surface layer (NSL) (between 30 and 100 cm) and the sea surface microlayer (SML) (upper millimeter). Conductivity, temperature, and depth (CTD) sensors measured temperature and conductivity (for salinity calculation) via a flow-through system on HALOBATES. Additional temperature sensors were mounted underneath the catamaran to measure in-situ temperature in situ at six depths in the NSL. Salinity was corrected with discrete water samples to remove biases between the sensors. Two data loggers with several meteorological stations on the catamaran captured important weather variables during operation time. The surfactant concentration was measured from discrete samples of SML and 100 cm depth. HALOBATES was operated between 01 March 2023 and 22 March 2023.

Continuous thermosalinograph oceanography along RV HEINCKE cruise track HE601

Raw data acquired by a thermosalinograph (SBE21, SeaBird GmbH) on board RV HEINCKE were processed to receive a calibrated and validated data set of seawater temperature and salinity. Data were downloaded from DAVIS SHIP data base (https://dship.awi.de) with a resolution of 1 sec. The SBE21 was equipped with an additional external temperature sensor (SBE38, Sea-Bird GmbH). Raw data are converted to temperature and conductivity values using the calibration coefficients from the calibration before deployment. However, data can only be finally processed after replacement and renewed calibration because correction values for the sensor drift can only be obtained by the post cruise calibration. The thermosalinograph on board RV HEINCKE is exchanged about once a year and calibration procedures are conducted after every exchange. Salinity was calculated according to the instructions from the Practical Salinity Scale PSS-78 using the obtained internal temperature and conductivity data. Processed data are provided as 1min means of salinity and seawater temperature aligned with position data taken from master track of the respective cruise. Quality flags are appended according to the SeaDataNet Data Quality Control Procedures (version from May 2010).

Continuous thermosalinograph oceanography along RV HEINCKE cruise track HE643

Raw data acquired by a thermosalinograph (SBE21, SeaBird GmbH) on board RV HEINCKE were processed to receive a calibrated and validated data set of seawater temperature and salinity. Data were downloaded from DAVIS SHIP data base (https://dship.awi.de) with a resolution of 1 sec. The SBE21 was equipped with an additional external temperature sensor (SBE38, Sea-Bird GmbH). Raw data are converted to temperature and conductivity values using the calibration coefficients from the calibration before deployment. However, data can only be finally processed after replacement and renewed calibration because correction values for the sensor drift can only be obtained by the post cruise calibration. The thermosalinograph on board RV HEINCKE is exchanged about once a year and calibration procedures are conducted after every exchange. Salinity was calculated according to the instructions from the Practical Salinity Scale PSS-78 using the obtained internal temperature and conductivity data. Processed data are provided as 1min means of salinity and seawater temperature aligned with position data taken from master track of the respective cruise. Quality flags are appended according to the SeaDataNet Data Quality Control Procedures (version from May 2010).

Continuous thermosalinograph oceanography along RV HEINCKE cruise track HE617

Raw data acquired by a thermosalinograph (SBE21, SeaBird GmbH) on board RV HEINCKE were processed to receive a calibrated and validated data set of seawater temperature and salinity. Data were downloaded from DAVIS SHIP data base (https://dship.awi.de) with a resolution of 1 sec. The SBE21 was equipped with an additional external temperature sensor (SBE38, Sea-Bird GmbH). Raw data are converted to temperature and conductivity values using the calibration coefficients from the calibration before deployment. However, data can only be finally processed after replacement and renewed calibration because correction values for the sensor drift can only be obtained by the post cruise calibration. The thermosalinograph on board RV HEINCKE is exchanged about once a year and calibration procedures are conducted after every exchange. Salinity was calculated according to the instructions from the Practical Salinity Scale PSS-78 using the obtained internal temperature and conductivity data. Processed data are provided as 1min means of salinity and seawater temperature aligned with position data taken from master track of the respective cruise. Quality flags are appended according to the SeaDataNet Data Quality Control Procedures (version from May 2010).

Continuous thermosalinograph oceanography along RV HEINCKE cruise track HE600

Raw data acquired by a thermosalinograph (SBE21, SeaBird GmbH) on board RV HEINCKE were processed to receive a calibrated and validated data set of seawater temperature and salinity. Data were downloaded from DAVIS SHIP data base (https://dship.awi.de) with a resolution of 1 sec. The SBE21 was equipped with an additional external temperature sensor (SBE38, Sea-Bird GmbH). Raw data are converted to temperature and conductivity values using the calibration coefficients from the calibration before deployment. However, data can only be finally processed after replacement and renewed calibration because correction values for the sensor drift can only be obtained by the post cruise calibration. The thermosalinograph on board RV HEINCKE is exchanged about once a year and calibration procedures are conducted after every exchange. Salinity was calculated according to the instructions from the Practical Salinity Scale PSS-78 using the obtained internal temperature and conductivity data. Processed data are provided as 1min means of salinity and seawater temperature aligned with position data taken from master track of the respective cruise. Quality flags are appended according to the SeaDataNet Data Quality Control Procedures (version from May 2010).

Temperature measurements from SIMBA-type sea ice mass balance buoy 2022T97

Temperature and heating-induced temperature difference profiles were measured through the atmosphere, sea ice, and ocean using a SIMBA-type sea ice mass balance buoy equipped with a several meter long thermistor chain. The present dataset was recorded by SIMBA 2022T97 (original name NPOL_0803) installed on drifting sea ice in the Arctic Ocean during the expedition Kronprins Haakon AO22 in 2022. Data is available between 2022-08-06 10:38:00 and 2022-11-22 03:02:00. The thermistor chain was Variable 5 m long and included 241 sensors with a regular spacing of 2 cm. The resulting time series includes the evolution of temperature and temperature differences at 30 s and 120 s during a heating cycle of 120 s as a function of location, depth and time. The sampling intervals were usually between hourly and daily, but were most frequently configured to 6 hours for temperature, and 24 hours for temperature differences. In addition to temperatures and geographic location, barometric pressure, ~1 m air temperature, instrument tilt, and compass heading were measured. The present dataset was processed as follows: obvious inconsistencies (missing values) and unrealistic values of GPS position have been removed. This instrument was deployed as part of the project Arctic Passion.

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