Organotin and especially butyltin compounds are used for a variety of applications, e.g. as biocides, stabilizers, catalysts and intermediates in chemical syntheses. Tributyltin (TBT) compounds exhibit the greatest toxicity of all organotins and have even been characterized as one of the most toxic groups of xenobiotics ever produced and deliberately introduced into the environment. TBT is not only used as an active biocidal compound in antifouling paints, which are designed to prevent marine and freshwater biota from settlement on ship hulls, harbour and offshore installations, but also as a biocide in wood preservatives, textiles, dispersion paints and agricultural pesticides. Additionally, it occurs as a by-product of mono- (MBT) and dibutyltin (DBT) compounds, which are used as UV stabilizer in many plastics and for other applications. Triphenyltin (TPT) compounds are also used as the active biocide in antifouling paints outside Europe and furthermore as an agricultural fungicide since the early 1960s to combat a range of fungal diseases in various crops, particularly potato blight, leaf spot and powdery mildew on sugar beet, peanuts and celery, other fungi on hop, brown rust on beans, grey moulds on onions, rice blast and coffee leaf rust. Although the use of TBT and TPT was regulated in many countries world-wide from restrictions for certain applications to a total ban, these compounds are still present in the environment. In the early 1970s the impact of TBT on nontarget organisms became apparent. Among the broad variety of malformations caused by TBT in aquatic animals, molluscs have been found to be an extremely sensitive group of invertebrates and no other pathological condition produced by TBT at relative low concentrations rivals that of the imposex phenomenon in prosobranch gastropods speaking in terms of sensitivity. TBT induces imposex in marine prosobranchs at concentrations as low as 0,5 ng TBT-Sn/L. Since 1993, for the littorinid snail Littorina littorea a second virilisation phenomenon, termed intersex, is known. In female specimens affected by intersex the pallial oviduct is transformed of towards a male morphology with a final supplanting of female organs by the corresponding male formations. Imposex and intersex are morphological alterations caused by a chronic exposure to ultra-trace concentrations of TBT. A biological effect monitoring offers the possibility to determine the degree of contamination with organotin compounds in the aquatic environment and especially in coastal waters without using any expensive analytical methods. Furthermore, the biological effect monitoring allows an assessment of the existing TBT pollution on the basis of biological effects. Such results are normally more relevant for the ecosystem than pure analytical data. usw.
Salinity reduces the productivity of cucumber (Cucumis sativus L.) through osmotic and ionic effects. For given atmospheric conditions we hypothesize the existence of an optimal canopy structure at which water use efficiency is maximal and salt accumulation per unit of dry matter production is minimal. This canopy structure optimum can be predicted by integrating physiological processes over the canopy using a functional-structural plant model (FSPM). This model needs to represent the influence of osmotic stress on plant morphology and stomatal conductance, the accumulation of toxic ions and their dynamics in the different compartments of the system, and their toxic effects in the leaf. Experiments will be conducted to parameterize an extended cucumber FSPM. In in-silico experiments with the FSPM we attempt to identify which canopy structure could lead to maximum long-term water use efficiency with minimum ionic stress. The results from in-silico experiments will be evaluated by comparing different canopy structures in greenhouses. Finally, the FSPM will be used to investigate to which extent the improvement of individual mechanisms of salt tolerance like reduced sensitivity of stomatal conductance or leaf expansion can contribute to whole-plant salt tolerance.
In the last decades agricultural policy has gained increasingly in complexity. Nowadays it influences the food and agricultural sector from the global market down to the farm level. Widespread research questions, like the impact of the WTO negotiations on the farm structure, most often require comprehensive modeling frameworks. Thus, different types of models are utilized according to their comparative advantages and combined in a strategically useful way to more accurately represent micro and macro aspects of the food and agricultural sector. Consequently, in recent years we have seen an increase in the development and application of model linkages. Given this background, the overall objective of this subproject is a systematic sensitivity analysis of model linkages that gradually involves more and more characteristics of the linkage and the corresponding transfer of results between models. In addition, the project aims to answer the following specific question: How does structural change at the farm level influence aggregate supply and technical progress? Under which conditions is it possible to derive macro-relationships from micro-relationships? How does the aggregation level influence the model results and how can possible problems be overcome? This procedure is used to quantify the effects and to derive conditions for optimal interaction of the connected models. The analysis is based on the general equilibrium model GTAP (Global Trade Analysis Project) and the farm group model FARMIS (Farm Modelling Information System) which are employed in conjunction to analyze the effects of WTO negotiations on the farm level.
In Vivo und in vitro Verabreichung von Nahrungsmittelzusatzstoffen (Tartrazin, Gelborange, Amaranth, Benzoesaeure, Sorbinsaeure, Na-Disulfit, K-Disulfit, Glutamat) und von Nahrungsmitteln (Ei, Milch, Nuesse, Fisch, Rohkost, Fleisch, Mehlsorten) an Patienten mit Verdacht auf entsprechende Unvertraeglichkeiten. Symptome: Kopf- und Bauchschmerzen, Asthma, Rhinitis, Diarrhoe, Urticaria, anaphylaktischer Schock. Mit Hilfe der in vitro Provokationen werden Korrelationen zwischen Mediatorenprofilen und der klinischen Symptomatologie hergestellt. Ziel der Untersuchung: Etablierung eines validen, nicht invarsiven, den Patienten nicht gefaehrdenden diagnostischen Verfahrens zur Objektivierung der nahrungsmittelinduzierten pseudoallergischen Reaktionen.
Our long term activities aim at a functional understanding of alpine plant life. Overall our research shifted gradually from studying resource acquisition (e.g. photosynthesis) toward resource investment and questions of developement. As with treeline, sink activity seems to be the major determinant of growth. A common misconception associated with alpine plant life finds its expression in the use of the terms 'stress' and 'limitation'. See the critique in: Körner C (1998) Alpine plants: stressed or adapted? In: Press MC, Scholes JD, Barker MG (eds.) Physiological Plant Ecology. Blackwell Science , 297-311. Ongoing experimental work: The influence of photoperiod on growth and development in high elevation taxa (Ph.D. by Franziska Keller in cooperation with the Dept. of Geography, University of Fribourg). We test, whether and which species are responsive to earlier snow melt. It appears there exists a suite of different sensitivities, suggesting biodiversity shifts. We also tested the influence of nutrient addition on high elevation pioneer plants and run a longer term project on the interactive effect on sheep tramplng, nitrogen deposition and warming as part of the Swiss National Project NFP 48. A Europe-wide assessment of ground temperatures in alpine grassland is part of ALPNET (see associated organisations). The assessment provides a basis for comparing biodiversity in alpine biota from 69 to 37 degree of northern latitude. (Nagy et al. (2003) Ecological Studies, Vol. 167. 577 p. Springer, Berlin). A synthesis of research in functional ecology of alpine plants over the past 100 years was published in 1999.
Current climate research is challenged by questions on (i) the characteristics of natural climate variability, (ii) the discrimination from anthropogenic forcing, and (iii) ecological, societal and economic risks. Insight into regional climate change is critically important: Instrumental data and high resolution climate reconstructions show that regional climatic trends and extremes strongly exceed changes reported at hemispheric or global scales. Seasonal to annual, quantitative, regional multi-proxy climate reconstructions are fundamental to assess natural (i.e. pre-anthropogenic), forced and stochastic climate variability. Accurate reconstruction with quantified uncertainties of the 'baseline climate' is the precondition for evaluating the sensitivity of the Earth System to different forcing factors, and validating the results of global and regional, past and future climate modelling. In consequence, one of the hotspots of the international research agenda is to assess natural climate variability of the last 1000 years which encompass the 'Medieval Warm Period' and the 'Little Ice Age'. Among the most fundamental conclusions of recent work is the finding that the structure of past climate change in Europe is very different for each of the four seasons of the year. Most significant are deviations during fall, winter and spring, precisely during the seasons that are poorly or not recorded in natural climate archives. Thus new cold-season proxies are critically important and need to be explored. This is where our project and the new equipment come in. The innovation and novelty of our research is that, besides the classic lake-sediment proxies, Chrysophyte stomatocysts (microfossils produced by 'golden algae') are used for quantitative temperature reconstruction. Recent pioneering work has shown that stomatocysts in Alpine lakes are among the very few proxies and the only 'terrestrial' microfossils that allow quantitative winter/spring temperature reconstructions. This information is unique and has a great potential to evolve into the key parameter for cold-season climate reconstructions. Primary target archive for our research is Lake Silvaplana, a lake with 3500 years of varved sediments. High-quality analysis of stomatocysts requires scanning electron microscopy (acquisition of equipment subject to this proposal). International cutting-edge research calls for continuous, high resolution (annual) sampling. Consequently our research plan has two goals: (i) to optimize the efficiency of data collection with automated image acquisition and off-line image analysis, and (ii) to produce annual winter/spring temperature series for the last 1000 years.
In den zurückliegenden 1.5 Jahren des Projektes konzentrierten sich die Arbeiten auf das erste bereits fertiggestellte vertikale Seismometer-Array des ICDP-GONAF-Observatoriums auf der Tuzla Halbinsel im Südosten Istanbuls. Aufgrund des verbesserten Signal-Rausch-Verhältnisses an den Bohrlochseismometern im Vergleich zu den Oberflächenstationen war es möglich, deutlich mehr M kleiner als 0 Mikrobeben zu detektieren. Diese Messdaten stellten die Grundlage für die bereits durchgeführten seismologischen Studien dar. In der hier beantragten Verlängerung werden wir unsere Erdbebendatenbank für das östliche Marmarameer fortlaufend erweitern, indem wir die im Sommer 2014 fertig gestellten Seismometer-Arrays auf der Armutlu-Halbinsel in die Detektionsalgorithmen integrieren, sowie dann auch weitere vier GONAF-Bohrlocharrays, deren Fertigstellung bis Frühjahr 2015 geplant ist. Es wurden verschiedene Methoden zur Bestimmung oberflächennaher Eigenschaften des Tuzla-Standortes, wie z.B. seismische Geschwindigkeiten und Dämpfung, angewendet und angepasst. Dieselben Methoden werden auf die neuen GONAF-Stationen übertragen, um zu verifizieren, ob die Beobachtungen in Tuzla standortspezifisch, oder auch für andere geologische Formationen repräsentativ sind. Die dann erstmals durchgeführte vergleichende Analyse unterschiedlicher Standorte in der Region wird neue Einblicke geben, um die Auswerteverfahren für die Korrektur von Standort-Effekten weiterzuentwickeln. Dies ist z.B. für eine genaue Abschätzung von Erdbeben-Quellparametern essentiell. Darüber hinaus planen wir, Processing-Methoden des Vertical-Seismic Profiling einzusetzen, um die Zweige der Nordanatolischen Verwerfungszone unterhalb des östlichen Marmarameeres abzubilden (passive fault-zone imaging). Dabei wird die lokale Seismizität genutzt, die in kleiner als 20 km Epizentralentfernung von den GONAF-Stationen in Tiefen von 5 bis 20 km auftritt und an den verschiedenen Tiefenstockwerken der GONAF-Arrays registriert wird. Schließlich werden Wellenformen-Registrierungen von erstmals in 300m Tiefe eingesetzten 3-Komponenten 1Hz MARK Seismometern ausgewertet, unter Anderem um verstärkt S-Wellen-Eigenschaften der Region zu untersuchen.
Luminescence dating methods using quartz may suffer from i) incomplete optical resetting (bleaching) of the latent signal at deposition, ii) limited saturation dose and,thus, limited time range using UV-A or blue emissions. The project objectives first consists in exploring and separating OSL emissions from quartz of different sensitivity to light and to isolate components suited for specific dating applications with the Linear Modulation technique. Rapid environmental change with or without human impact will be dated more precisely and more reliably using this sophisticated technique. Secondly it is tried to extend the upper dating limit by using orange-red TL emissions (RTL) from quartz extracted from heated samples (e.g., crustal xenoliths from volcanic eruptions) and from sediments which are too old for conventional OSL dating. Both approaches require fundamental research into the luminescence characteristics of (dose-saturated) quartz crystals from different geological origin (granitic, hydrothermal, sedimentary). Objectives in order: 1. Sampling and refining pure quartz from different geological and petrographic environments and from a well-studied last glacial loess section (Nussloch). 2. Investigating basic luminescence characteristics from different quartz of different origin, with focus on OSL components (LM-OSL) and red TL emissions (RTL). 3. Testing improved techniques (LM-OSL) to recognize incomplete or inhomogeneous signal resetting at deposition and to precisely determine the true burial dose. 4. Extending the upper limit of luminescence dating through use of RTL emissions from heated and from sedimentary quartz. 5. Improving and ensuring of dose rate calculations using different low-level methods including modeling of disequilibrium and spatial non-homogeneity if applicable. 6. Comparing dating results from loess with independent chronologies and other high resolution records of rapid climate change.
The main objective of the project is to determine growth sensitivity, elasticity, and resilience of Douglas-fir provenances to climatic alterations, in particular drought events. To differentiate between the impact of site and genetics, samples from experiments will be analyzed, where identical provenances are planted at different sites. Major research scopes are: Investigating the impact of weather on intra-annual growth patterns We will determine how weather variations affect the provenances' growth. The focus will be on intra-annual variations in wood anatomy and density. A dendrometer study will complement the retrospective analyses to monitor changes in stem hydraulic status and to trace the seasonal timing of growth processes. Fitting genotype- and climate-sensitive growth models for a growth simulation system Retrospective inter-annual growth address long-term trends as well as the effect of distinct climate events on inter-annual growth responses. The goal is to build provenance- and climate-sensitive growth models that can be integrated into a growth simulation system. The assessment of growth responses to drought will be tested and interpreted against the results of the partner projects within the general research concept 'adaptation of forest trees to climatic change - diversity of drought responses in Douglas-fir provenances': P1 (genes), P2 (stable isotopes), and P4 (isoprenoids). A major contribution of our project is to provide the partner projects with research opportunities in the adult stands of the provenance experiments.
More than a decade has passed since the launch of the GRACE satellite mission. Although designed for a nominal mission lifetime of 5 years, it still provides valuable science data. An eventual systems failure and, thus, mission termination is expected any time soon, though. Despite a relative low spatial and temporal resolution, the monthly gravity fields have proved an invaluable and novel parameter set in several geoscience disciplines, allowing new research venues in the study of Global Change phenomena. The hydrological cycle is now subject to quantification at continental scales; the state of the cryosphere, particularly ice sheet melting over Greenland and Antarctica, can be monitored; and steric effects of sea-level change have become separable from non-steric ones. The enormous success of the mission has driven the need for continuation of monitoring mass changes in the Earth system. Indeed, a GRACE Follow-On (GFO) mission has been approved for launch in August 2017. Like its predecessor it will consist of two satellites flying en echelon with intersatellite K-Band ranging as the main gravitational sensor. Despite a number of planned technological improvements, including a laser link as demonstrator, GFO will mostly be based on GRACE heritage. Given a similar orbit configuration and a similar systems setup, the quality of eventual gravity field products can be expected to be in the same range as the current GRACE products. To guarantee the continuation of such successful gravity field time series ESA has embarked several years ago on a long term strategy for future gravity field satellite missions, both in terms of technology development and in terms of consolidating the user community. Scientists from academia and industry held a workshop on The Future of Satellite Gravimetry at ESTEC premises, 12-13 April 2007, (RD-9). Similar workshops have been organized by other organizations, e.g. the joint GGOS/IGCP565 workshop Towards a Roadmap for Future Satellite Gravity Missions in Graz, September 30 - October 2, 2009. ESA furthermore played a key role in consolidating the international user community by funding a series of study projects, cf. (RD-1) to (RD-5). Similar projects have been funded and conducted at national level, e.g. the German BMBF-funded Geotechnologies III project Concepts for future gravity field satellite missions (PI: N. Sneeuw). These studies, together with GRACE experience, have provided a clear understanding of the current limitations of a GRACE-type mission. In particular the limitations in sampling and sensitivity of a single pair of satellites with in-orbit in-line sensitivity are well documented. At the same time, these studies have shown the design options and a roadmap towards a next generation gravity field mission.
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