Groundwater contamination by organic compounds represents a widespread environmental problem. The heterogeneity of geological formations and the complexity of physical and biogeochemical subsurface processes, often hamper a quantitative characterization of contaminated aquifers. Compound specific stable isotope analysis (CSIA) has emerged as a novel approach to investigate contaminant transformation and to relate contaminant sources to downgradient contamination. This method generally assumes that only (bio)chemical transformations are associated with isotope effects. However, recent studies have revealed isotope fractionation of organic contaminants by physical processes, therefore pointing to the need of further research to determine the influence of both transport and reactive processes on the observed overall isotope fractionation. While the effect of gasphase diffusion on isotope ratios has been studied in detail, possible effects of aqueous phase diffusion and dispersion have received little attention so far.The goals of this study are to quantify carbon (13C/12C) and, for chlorinated compounds, chlorine (37Cl/35Cl) isotope fractionation during diffusive/dispersive transport of organic contaminants in groundwater and to determine its consequences for source allocation and assessment of reactive processes using isotopes. The proposed research is based on the combination of high-resolution experimental studies, both at the laboratory (i.e. zero-, one- and two-dimensional systems) and at the field scales, and solute transport modeling. The project combines the expertise in the field of contaminant transport with the expertise on isotope methods in contaminant hydrogeology.
Fusarium species of the Gibberella fujikuroi species complex cause serious diseases on different crops such as rice, wheat and maize. An important group of plant pathogens is the Gibberella fujikuroi species complex (GFC) of closely related Fusarium species which are associated with specific hosts; F. verticillioides and F. proliferatum are particularly associated with maize where they can cause serious ear-, root-, and stalk rot diseases. Two other closely related species of the GFC, F. mangiferae and F. fujikuroi, which share about 90Prozent sequence identity with F. verticillioides, are pathogens on mango and rice, respectively. All of these species produce a broad spectrum of secondary metabolites such as phytohormones (gibberellins, auxins, and cytokinins), and harmful mycotoxins, such as fumonisin, fusarin C, or fusaric acid in large quantities. However, the spectrum of those mycotoxins might differ between closely related species suggesting that secondary metabolites might be determinants for host specificity. In this project, we will study the potential impact of secondary metabolites (i.e. phytohormones and certain mycotoxins) and some other species-specific factors (e.g. species-specific transcription factors) on host specificity. The recently sequenced genomes of F. mangiferae and F. fujikuroi by our groups and the planned sequencing of F. proliferatum will help to identify such determinants by genetic manipulation of the appropriate metabolic pathway(s).
In Fragebogen-Untersuchungen zur Lärmwirkung wurden bisher sehr unterschiedliche Operationalisierungen von Wirkungsvariablen (wie z.B. Belästigung, Störung von Aktivitäten) und außer-akustischen Faktoren (sog. Moderatoren wie z.B. Lärmempfindlichkeit, misfeasance) verwendet. Deshalb hat sich die Arbeitsgruppe community response der International Commission on the Biological Effects of Noise (ICBEN, Team No. 6) als langfristiges Ziel die Entwicklung von Fragebogen-Guidelines und die Formulierung eines Muster-Fragebogens für die Lärmwirkungsforschung gesetzt. D.h. es soll ein Vorschlag erarbeitet werden, in welcher Form globale und spezifische Lärmwirkungen in Befragungen erhoben werden sollten. Um dieses Vorhaben zu unterstützen, hat der Arbeitskreis Ökologische Lärmforschung die Erstellung einer systematischen Übersicht über vorhandene Fragebögen aus Lärmwirkungsstudien auf internationaler Ebene in Angriff genommen. Diese Übersicht soll es u.a. ermöglichen, die Struktur von verschiedenen Fragebögen sowie die in ihnen verwendeten Operationalisierungen für Lärmwirkungs- und Moderatorvariablen (hinsichtlich Art der Frageformulierung sowie der Antwortformate) zu vergleichen. Für den/die einzelne/n Lärmforscher/in bietet diese Übersicht die Möglichkeit, sich auf sehr effiziente Art und Weise darüber zu informieren, wie bestimmte Konstrukte in bisherigen Untersuchungen operationalisiert worden sind bzw. welche Alternativen zu den bereits selbst angewandten Operationalisierungen bestehen. Nach einer systematischen Ermittlung von Namen und Adressen einschlägiger Lärmforscher/innen, wurden diese um die Zusendung von Fragebögen sowie ergänzender Materialien aus eigenen Lärmwirkungsstudien gebeten. Die zugesandten Fragebögen werden gegebenenfalls übersetzt und mit der Methode der qualitativen Inhaltsanalyse ausgewertet. Hierbei werden die Fragebögen im Hinblick auf formelle Aspekte (z.B. Jahr der Erhebung, Sprache, Art der Befragungsmethode) wie auch im Hinblick auf strukturelle Aspekte (z.B. Umfang des Fragebogens, abgefragte Variablengruppen, Antwortformate) ausgewertet. Hauptgegenstand der Auswertung ist aber insbesondere die Auswertung der Lärmwirkungsvariablen (z.B. die Abfrage der globalen Lärmbelästigung, Aktivitätenstörungen, Kommunikationsstörungen) sowie der Moderatorvariablen (z.B. Lärmempfindlichkeit, Lärmbewältigungsvermögen, misfeasance). Parallel dazu wurde eine Datenbank entwickelt, in der die Ergebnisse der Analysen dargestellt und verwaltet werden. Diese Datenbank wird ab November 2001 im Internet unter http://www.eco.psy.ruhr-uni-bochum.de/nqd für jede/n interessierte/n Forscher/in zugänglich und nutzbar sein. Langfristig ist darüber hinaus geplant, ein Archiv mit den Original-Fragebögen aufzubauen, in dem einzelne Fragebögen auf Wunsch eingesehen werden können.
In the last decades agricultural policy has gained increasingly in complexity. Nowadays it influences the food and agricultural sector from the global market down to the farm level. Widespread research questions, like the impact of the WTO negotiations on the farm structure, most often require comprehensive modeling frameworks. Thus, different types of models are utilized according to their comparative advantages and combined in a strategically useful way to more accurately represent micro and macro aspects of the food and agricultural sector. Consequently, in recent years we have seen an increase in the development and application of model linkages. Given this background, the overall objective of this subproject is a systematic sensitivity analysis of model linkages that gradually involves more and more characteristics of the linkage and the corresponding transfer of results between models. In addition, the project aims to answer the following specific question: How does structural change at the farm level influence aggregate supply and technical progress? Under which conditions is it possible to derive macro-relationships from micro-relationships? How does the aggregation level influence the model results and how can possible problems be overcome? This procedure is used to quantify the effects and to derive conditions for optimal interaction of the connected models. The analysis is based on the general equilibrium model GTAP (Global Trade Analysis Project) and the farm group model FARMIS (Farm Modelling Information System) which are employed in conjunction to analyze the effects of WTO negotiations on the farm level.
In structured soils, the interaction of percolating water and reactive solutes with the soil matrix is mostly restricted to the surfaces of preferential flow paths. Flow paths, i.e., macropores, are formed by worm burrows, decayed root channels, cracks, and inter-aggregate spaces. While biopores are covered by earthworm casts and mucilage or by root residues, aggregates and cracks are often coated by soil organic matter (SOM), oxides, and clay minerals especially in the clay illuviation horizons of Luvisols. The SOM as well as the clay mineral composition and concentration strongly determine the wettability and sorption capacity of the coatings and thus control water and solute movement as well as the mass exchange between the preferential flow paths and the soil matrix. The objective of this proposal is the quantitative description of the small-scale distribution of physicochemical properties of intact structural surfaces and flow path surfaces and of their distribution in the soil volume. Samples of Bt horizons of Luvisols from Loess will be compared with those from glacial till. At intact structural surfaces prepared from soil clods, the spatial distribution (mm-scale) of SOM and clay mineral composition will be characterized with DRIFT (Diffuse reflectance infrared Fourier transform) spectroscopy using a self-developed mapping technique. For samples manually separated from coated surfaces and biopore walls, the contents of organic carbon (Corg) and the cation exchange capacity (CEC) will be analyzed and related to the intensities of specific signals in DRIFT spectra using Partial Least Square Regression (PLSR) analysis. The signal intensities of the DRIFT mapping spectra will be used to quantify the spatial distribution of Corg and CEC at these structural surfaces. The DRIFT mapping data will also be used for qualitatively characterizing the small scale distribution of the recalcitrance, humification, and microbial activity of the SOM from structural surfaces. The clay mineral composition of defined surface regions will be characterized by combining DRIFT spectroscopic with X-ray diffractometric analysis of manually separated samples. Subsequently, the spatial distribution of the clay mineral composition at structural surfaces will be determined from the intensities of clay mineral-specific signals in the DRIFT mapping spectra and exemplarily compared to scanning electron microscopic and infrared microscopic analysis of thin sections and thin polished micro-sections. The three-dimensional spatial distribution of the total structural surfaces in the volume of the Bt horizons will be quantified using X-ray computed tomography (CT) analysis of soil cores. The active preferential flow paths will be visualized and quantified by field tracer experiments. These CT and tracer data will be used to transfer the properties of the structural surfaces characterized by DRIFT mapping onto the active preferential flow paths in the Bt horizons.
The energetic efficiency of C4 photosynthesis is strongly affected by bundle sheath leakiness, which is commonly assessed with the 'linear version' of the Farquhar model of 13C discrimination, and leaf gas exchange and 13C composition data. But, the linear Farquhar model is a simplification of the full mechanistic theory of ? in C4 plants, potentially generating errors in the estimation of leakiness. In particular, post-photosynthetic C isotope fractionation could cause large errors, but has not been studied in any detail. The present project aims to improve the understanding of the ecological and developmental/physiological factors controlling discrimination and leakiness of the perennial grass Cleistogenes squarrosa. C. squarrosa is the most important member of the C4 community which has spread significantly in the Mongolia grasslands in the last decades. It has an unusually high and variable discrimination, which suggests very high (and potentially highly variable) leakiness. Specifically, we will conduct the first systematic study of respiratory 13C fractionation in light and dark at leaf- and stand-scale in this C4 species, and assess its effect on discrimination and estimates of leakiness. These experiments are conducted in specialized 13CO2/12CO2 gas exchange mesocosms using ecologically relevant scenarios, testing specific hypotheses on effects of environmental drivers and plant and leaf developmental stage on discrimination and leakiness.
Chlorinated ethylenes are prevalent groundwater contaminants. Numerous studies have addressed the mechanism of their reductive dehalogenation during biodegradation and reaction with zero-valent iron. However, despite insight with purified enzymes and well-characterized chemical model systems, conclusive evidence has been missing that the same mechanisms do indeed prevail in real-world transformations. While dual kinetic isotope effect measurements can provide such lines of evidence, until now this approach has not been possible for chlorinated ethylenes because an adequate method for continuous flow compound specific chlorine isotope analysis has been missing. This study attempts to close this prevalent research gap by a combination of two complementary approaches. (1) A novel analytical method to measure isotope effects for carbon and chlorine. (2) A carefully chosen set of well-defined model reactants representing distinct dehalogenation mechanisms believed to be important in real-world systems. Isotope trends observed in biotic and abiotic environmental dehalogenation will be compared to these model reactions, and the respective mechanistic hypotheses will be confirmed or discarded. With this hypothesis-driven approach it is our goal to elucidate for the first timdehalogenation reactions.
The sorption of anions in geotechnical multibarrier systems of planned high level waste repositories (HLWR) and of non-ionic and organic pollutants in conventional waste disposals are in the center of recent research. In aquatic systems, persistent radionuclides such as 79Se, 99Tc, 129I exist in a form of anions. There is strongly increasing need to find materials with high sorption capacities for such pollutants. Specific requirements on barrier materials are long-term stability of adsorbent under various conditions such as T > 100 C, varying hydrostatic pressure, and the presence of competing ions. Organo-clays are capable to sorb high amounts of cations, anions and non-polar molecules simultaneously having selectivity for certain ions. This project is proposed to improve the understanding of sorption and desorption processes in organo-clays. Additionally, the modification of material properties under varying chemical and thermal conditions will be determined by performing diffusion and advection experiments. Changes by sorption and diffusion will be analyzed by determining surface charge and contact angles. Molecular simulations on models of organo-clays will be conducted in an accord with experiments with aim to understand and analyze experimental results. The computational part of the project will profit from the collaboration of German partner with the group in Vienna, which has a long standing experience in a modeling of clay minerals.
Die temperatur- und feuchteabhängige Eisnukleationseffizlenz von verschiedenen Aerosolen kann in Laborexperimenten genau charakterisiert und für die Beschreibung von primärer Eisbildung in numerischen Modellen auf verschiedensten Skalen parametrisiert werden. Wenn diese Effizienten als bekannt vorausgesetzt werden, unter welchen Bedingungen und wie oft tritt heterogene Eisnukleation in den verschiedenen Nukleationsmoden tatsächlich in typischen Mischphasenwolken auf? Dieser Frage wird in diesem Projekt mit dem Modell ICON-LES (der Large Eddy Version des neuen icosahedrischen nichthydrostatischen Modells, welches zurzeit am Deutschen Wetterdienst und dem Max-Planck-Institut für Meteorologie in Hamburg entwickelt wird) nachgegangen. Dieses Modell enthält ein Zwei-Momenten-Wolkenphysikschema und wird durch aerosolspezifische Eisnukleationsparameterisierungen ergänzt werden. Zusätzlich wird eine einfache Diagnostik von Aerosolen in Wolkentropfen eingeführt, um zwischen potentiellen Immersionseiskeimen und interstitiellen eisnukleierenden Partikeln, die als Kontakt- oder Depositionseiskeime dienen können, zu unterscheiden. In idealisierten Simulationen von verschiedenen Mischphasenwolkentypen, die in Europa häufig auftreten (Winternebel, Altostratus, orographische Wolken, hochreichende Konvektion) und unter Benutzung von klimatologischen Aerosolfeldern wird das Auftreten von Immersions-, Depositions- und Kontaktgefrieren und die Werte der Eiskeimkonzentrationen statistisch ausgewertet und mit den Sensitivitätsbereichen der INUIT Labor- und Feldmessgeräten verglichen. Zusätzlich wird das bevorzugte räumliche Auftreten dieser Prozesse (z. B. Kontaktgefrieren in den Einmischbereichen an den Wolkenrändern) analysiert und quantifiziert werden. Das Modellsetup für die Fallstudie der konvektiven Wolke wird mit RP3 abgestimmt, so dass ein Vergleich zwischen dem spektralen und dem Zwei-Momenten- Mikrophysikschema möglich ist. Außerdem wird in diesem Projekt zusammen mit WP-F und WP-L eine Schließungsstudie für die Messungen in der Mittelmeerkampagne durchgeführt. Dabei wird untersucht, welche Parameter zu den größten Unsicherheiten in der Vorwärtsberechnung von potentiellen Eiskeimen führen.
Magnetic properties of ferrimagnetic minerals depend on their crystal lattice, anisotropy, chemical composition and grain size. The latter parameter is strongly controlled by microstructures, which are significant for the interpretation of the magnetic properties of shocked magnetic minerals. Fracturing and lattice defects are the main causes for magnetic domain size reduction and generate an increase in coercivity and the suppression of magnetic transitions (e.g. 34 K transition in pyrrhotite, Verwey transition in magnetite).Especially for an adequate investigation of shock-induced modifications in ferromagnetic minerals, a combination of microstructural and magnetic measurements is therefore essential.This project focusses on two significant aspects of extreme conditions - the consequence of shock waves on natural material on Earth and on the magnetic mineralogy of exotic magnetic minerals in iron meteorites. In order to obtain general correlations between deformation structures and magnetic properties, the specific magnetic properties and carriers as well as microstructures of samples from two impact structures in marine targets (Lockne and Chesapeake Bay) will be compared with shocked magnetite ore and magnetite-bearing target lithologies from outside the crater (Lockne) as well as from undeformed megablocks within the crater (Chesapeake Bay). We will test the hypothesis if shock-related microstructures and associated magnetic properties can significantly be overprinted by postshock hydrothermal alteration. We especially want to focus on the Verwey transition (TV) as lower TVs are described for shocked impact lithologies. Hence, the main focus of this study lies on magneto-mineralogical investigations which combine low- and high-temperature magnetic susceptibility and saturation isothermal remanent magnetization with mineralogical and microstructural investigations. The same methods will then be used for the investigation of iron meteorites, whose magnetic properties are often controled by exotic magnetic minerals like cohenite, schreibersite and daubreelite in addition to the metal phases. Magnetic transition temperatures of those phases are poorly documented in relation to their chemical composition as well as to their crystallographic and microstructural configuration. For a general understanding of shock-related magnetization processes in extraterrestrial and terrestrial material, however, it is crucial to obtain a general correlation between the initial 'unshocked' state and the subsequent shock- and alteration-related overprints.
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