Organic matter (OM) composition and dynamic in subsoils is thought to be significantly different from those in surface soils. This has been suggested by increasing apparent 14C ages of bulk soil OM with depth suggesting that the amount of fresh, more easily degradable components is declining. Compositional changes have been inferred from declining ä13C values and C/N ratios indicative for stronger OM transformation. Beside these bulk OM data more specific results on OM composition and preservation mechanisms are very limited but modelling studies and results from incubation experiments suggest the presence and mineralization of younger, 'reactive carbon pool in subsoils. Less refractory OM components may be protected against degradation by interaction with soil mineral particles and within aggregates as suggested by the very limited number of more specific OM analysis e.g., identification of organic compound in soil fractions. The objective of this project is to characterize the composition, transformation, stabilization and bioavailability of OM in subsurface horizons on the molecular level: 1) major sources and compositional changes with depth will be identified by analysis of different lipid compound classes in surface and subsoil horizons, 2) the origin and stabilization of 'reactive OM will be revealed by lipid distributions and 14C values of soil fractions and of selected plant-specific lipids, and 3) organic substrates metabolized by microbial communities in subsoils are identified by distributional and 14C analysis of microbial membrane lipids. Besides detailed analyses of three soil profiles at the subsoil observatory site (Grinderwald), information on regional variability will be gained from analyses of soil profiles at sites with different parent material.
Soil structure determines a large part of the spatial heterogeneity in water storage and fluxes from the plot to the hillslope scale. In recent decades important progress in hydrological research has been achieved by including soil structure in hydrological models. One of the main problems herein remains the difficulty of measuring soil structure and quantifying its influence on hydrological processes. As soil structure is very often of biogenic origin (macropores), the main objective of this project is to use the influence of bioactivity and resulting soil structures to describe and support modelling of hydrological processes at different scales. Therefore, local scale bioactivity will be linked to local infiltration patterns under varying catchment conditions. At hillslope scale, the spatial distribution of bioactivity patterns will be linked to connectivity of subsurface structures to explain subsurface stormflow generation. Then we will apply species distribution modelling of key organisms in order to extrapolate the gained knowledge to the catchment scale. As on one hand, bioactivity influences the hydrological processes, but on the other hand the species distribution also depends on soil moisture contents, including the feedbacks between bioactivity and soil hydrology is pivotal for getting reliable predictions of catchment scale hydrological behavior under land use change and climate change.
Atmospheric CO2 concentrations present a repetitive pattern of gradual decline and rapid increase during the last climate cycles, closely related to temperature and sea level change. During the Last Glacial Maximum (LGM; 23-19 kyr BP), when sea level was ca. 120 m below present, the ocean must have stored additionally about 750 Gt carbon. There is consensus that the Southern Ocean represents a key area governing past and present CO2 change. The latter is not only of high scientific but also of socio-economic and political concern since the Southern Ocean provides the potential for an efficient sink of anthropogenic carbon. However, the sensitivity of this carbon sink to climate-change induced reorganizations in wind patterns, ocean circulation, stratification, sea ice extent and biological production remains under debate. Models were not yet able to reproduce the necessary mechanisms involved, potentially due to a lack of the dynamic representation/resolution of atmospheric and oceanic circulation as well as missing carbon cycling. Data on past Southern Ocean hydrography and productivity are mainly from the Atlantic sector, thus do not adequately document conditions in the Pacific sector. This sector is not only the largest part of the Southern Ocean, but it also represents the main drainage area of the marine-based West Antarctic Ice Sheet (WAIS). In the proposed study we aim to generate paleo-data sets with a newly established proxy method from sediment core transects across the Pacific Southern Ocean. This will enhance the baselines for the understanding and modeling of the Southern Ocean's role in carbon cyling, i.e. ocean/atmosphere CO2 exchange and carbon sequestration. It will also allow insight into the response of the WAIS to past warmer than present conditions. Paired isotope measurements (oxygen, silicon) will be made on purified diatoms and radiolarians to describe glacial/interglacial contrasts in physical and nutrient properties at surface and subsurface water depth. This will be used to test (i) the impact of yet unconsidered dust-borne micronutrient deposition on the glacial South Pacific on shifts of primary productivity, Si-uptake rates and carbon export, (ii) the 'silicic-acid leakage' hypothesis (SALH) and (iii) the formation and extent of surface water stratification. Diatom and radiolarian oxygen isotopes will provide information on the timing of surface ocean salinity anomalies resulting from WAIS melt water. Climate model simulations using a complex coupled atmosphere ocean general circulation model (AOGCM) in combination with a sophisticated ocean biogeochemical model including Si-isotopes will be used for comparison with the paleo records. The analysis will cover spatial as well as temporal variability patterns of Southern Ocean hydrography, nutrient cycling and air-sea CO2-exchange. With the help of the climate model we aim to better separate and statistically analyse the individual impacts of ocean circulation and bio
Ziel: Hydrochemische Analysen, Isotopenhydrologische Analysen.
Die Daten sind aus dem Projekt „Bilanzierung des Grundwasserdargebotes für das Land Brandenburg“ (HGN-Gutachten 2021) im Zusammenhang mit den Daten zum Projekt „Hydroisohypsenplan 2017“ aus dem Umweltplan-Gutachten (2017) aggregiert worden. Auf Grundlage stichtagsbezogener Grundwasser-/ Oberflächenwasserstandsdaten des Frühjahres 2015 erfolgte über das Interpolationsverfahren „Detrended Kriging/Residual Kriging“ in Kombination mit einer geohydraulischen Modellierung, die Berechnung der Hydroisohypsen (Linien gleicher Grundwasserstände auf NHN bezogen). Für die Darstellung der unterirdischen Einzugsgebiete wurden zuerst die oberirdischen Einzugsgebiete ausgegrenzt. Danach erfolgte die Ausgrenzung der unterirdischen Einzugsgebiete in Ableitung der o. g. Hydrodynamik aus dem Frühjahr 2015. Unterirdische Einzugsgebiete werden auch Grundwassereinzugsgebiete genannt. Die Daten sind aus dem Projekt „Bilanzierung des Grundwasserdargebotes für das Land Brandenburg“ (HGN-Gutachten 2021) im Zusammenhang mit den Daten zum Projekt „Hydroisohypsenplan 2017“ aus dem Umweltplan-Gutachten (2017) aggregiert worden. Auf Grundlage stichtagsbezogener Grundwasser-/ Oberflächenwasserstandsdaten des Frühjahres 2015 erfolgte über das Interpolationsverfahren „Detrended Kriging/Residual Kriging“ in Kombination mit einer geohydraulischen Modellierung, die Berechnung der Hydroisohypsen (Linien gleicher Grundwasserstände auf NHN bezogen). Für die Darstellung der unterirdischen Einzugsgebiete wurden zuerst die oberirdischen Einzugsgebiete ausgegrenzt. Danach erfolgte die Ausgrenzung der unterirdischen Einzugsgebiete in Ableitung der o. g. Hydrodynamik aus dem Frühjahr 2015. Unterirdische Einzugsgebiete werden auch Grundwassereinzugsgebiete genannt.
The goal of this project is to quantify freshwater fluxes in the ocean, and improve our understanding of their temporal and spatial changes in terms of the interaction between ocean transport processes, surface net freshwater fluxes and river run-off, as well as mixing processes in the ocean. In particular, we aim at combining all available ocean salinity/freshwater data (including novel satellite-based salinity retrievals and ARGO data), surface freshwater fluxes (including HOAPS and NCEP net surface freshwater fluxes) and river discharge with a numerical model to improve our understanding of net surface sources of freshwater, near-surface freshwater budgets, and full-depth ocean freshwater transports. Respective sub-goals entail: -Improving the quality of SMOS and Aquarius surface salinity data and estimating respective error information required for their subsequent analysis and assimilation. - Expansion of the GECCO data assimilation system to incorporate surface salinity fields. - Evaluation of the sensitivity of subsurface salinity to freshwater fluxes (incl. run-off), surface salinity fields and subsurface salinity changes. - Estimates of surface and subsurface salinity fields, ocean transports of freshwater (including surface freshwater fluxes) from monthly mean SMOS and Aquarius fields, ARGO salinities and underway salinity measurements. - Quantifying the role of surface forcing (E-P-R) versus lateral transports and mixing of freshwater in modulating the freshwater content as function of depths and geographical position. Providing a best possible description of salinity changes and underlying processes in the Atlantic Ocean.
In hydrology, the relationship between water storage and flow is still fundamental in characterizing and modeling hydrological systems. However, this simplification neglects important aspects of the variability of the hydrological system, such as stable or instable states, tipping points, connectivity, etc. and influences the predictability of hydrological systems, both for extreme events as well as long-term changes. We still lack appropriate data to develop theory linking internal pattern dynamics and integral responses and therefore to identify functionally similar hydrological areas and link this to structural features. We plan to investigate the similarities and differences of the dynamic patterns of state variables and the integral response in replicas of distinct landscape units. A strategic and systematic monitoring network is planned in this project, which contributes the essential dynamic datasets to the research group to characterize EFUs and DFUs and thus significantly improving the usual approach of subdividing the landscape into static entities such as the traditional HRUs. The planned monitoring network is unique and highly innovative in its linkage of surface and subsurface observations and its spatial and temporal resolution and the centerpiece of CAOS.
Groundwater contamination by organic compounds represents a widespread environmental problem. The heterogeneity of geological formations and the complexity of physical and biogeochemical subsurface processes, often hamper a quantitative characterization of contaminated aquifers. Compound specific stable isotope analysis (CSIA) has emerged as a novel approach to investigate contaminant transformation and to relate contaminant sources to downgradient contamination. This method generally assumes that only (bio)chemical transformations are associated with isotope effects. However, recent studies have revealed isotope fractionation of organic contaminants by physical processes, therefore pointing to the need of further research to determine the influence of both transport and reactive processes on the observed overall isotope fractionation. While the effect of gasphase diffusion on isotope ratios has been studied in detail, possible effects of aqueous phase diffusion and dispersion have received little attention so far.The goals of this study are to quantify carbon (13C/12C) and, for chlorinated compounds, chlorine (37Cl/35Cl) isotope fractionation during diffusive/dispersive transport of organic contaminants in groundwater and to determine its consequences for source allocation and assessment of reactive processes using isotopes. The proposed research is based on the combination of high-resolution experimental studies, both at the laboratory (i.e. zero-, one- and two-dimensional systems) and at the field scales, and solute transport modeling. The project combines the expertise in the field of contaminant transport with the expertise on isotope methods in contaminant hydrogeology.
Over land, observations of rain rates are more or less operational. To obtain information about precipitation at the coastal zones, weather radars are used. However, over the oceans, especially away from the main shipping routes, no direct precipitation measurements are performed. In these regions, satellite data can provide information about precipitation events. Satellites deploying passive and active microwave sensors can operate independently of cloud cover and time of day. Passive microwave sensors give crude estimates of rain rates over large areas but cannot resolve small-scale rain events of short duration as are often observed in the tropics, for example. Active microwave sensors with high resolutions, such as synthetic aperture radars can provide more reliable information. Though the effect of rain on the atmosphere is a very topical area of research, the radar backscattering mechanisms at the water surface during rain events combined with wind are still not well understood. The purpose of this project is to investigate the radar backscattering from the water surface in the presence of rain and wind in order to interpret satellite radar data produced by active microwave sensors. Furthermore, the results should be embedded into models of the radar backscattering from the water surface to allow for estimating rain rates by using satellite data. Research topics: Rain impinging on a water surfaces generates splash products including crowns, cavities, stalks and secondary drops, which do not propagate, and ring waves and subsurface turbulence. We are investigating this phenomena at the wind-wave tank of the University of Hamburg. The tank is fitted with an artificial rain simulator of 2.3 m2 area mounted 4.5 m over the water surface. Rain drops of 2.1 and 2.9 mm in diameter with rain rates up to 100 mm/h have been produced. Wind with speeds 10 m/s and monomolecular slicks act on the water surface. The influence of the rain on the water surface is measured with a resistance type wire gauge, a two dimensional laser slope gauge and an coherent 9.8 GHz (x band) continuous wave scatterometer operating at VV-, HH- and HV-polarization. The influence of rain below the water surface is measured with colored raindrops which are observed with a video camera to investigate the turbulent motion and the depth of the mixed layer. At the North Sea Port of Buesum in Germany, a scatterometer operating at all polarizations and five frequencies will be mounted during summer of this year. The radar backscatter of the sea surface during rain events will be measured in combination with meteorological observations. With help of these measurements, existing radar backscatter models of the water surface will be improved for the presence of rain events. To validate the improved models, ERS-2 SAR-images will be compared with weather radar data.
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