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In der Bundesrepublik Deutschland wurden von 1990 bis 2005 in fünfjährigem Abstand sowie in den Jahren 2015/16 und 2020/21 Untersuchungen zur Bestimmung der Inhaltsstoffe von Moosen durchgeführt. Schwerpunkt war die Analyse von Schwermetallen, ab 2005/06 auch von Sticksoff. Seit 2015/16 wurde das Stoffspektrum auf persistente organische Stoffe (POP) und Mikroplastik ausgeweitet. Dieses „Moosmonitoring“ ist der deutsche Beitrag zum europäischen Moosmonitoringprogramm, welches durch das „Internationale Kooperativprogramm zur Wirkung von Luftverunreinigungen auf die natürliche Vegetation und auf landwirtschaftliche Kulturpflanzen“ („International Cooperative Programme on Effects of Air Pollution on Natural Vegetation and Crops“, kurz: ICP Vegetation) der Genfer Luftreinhaltekonvention (Convention on Long-range Transboundary Air Pollution, CLRTAP) koordiniert wird. Mit der Durchführung der einzelnen Probenahmekampagnen sowie der Auswertung der Untersuchungsergebnisse wurden durch das Umweltbundesamt (UBA) wechselnde Institutionen beauftragt, so die Bundesanstalt für Geowissenschaften und Rohstoffe (BGR) mit dem Moosmonitoring 1995/96. Die Ergebnisse der nachfolgenden Monitoringjahre hat das Umweltbundesamt veröffentlicht. Sie sind abrufbar unter https://www.umweltbundesamt.de/daten/luft/bioindikation-von-luftverunreinigungen. Das Moos-Monitoring 1995/96 ist mit 1026 Standorten neben dem Moos-Monitoring 2000 das mit der größten Probenahmedichte und mit 40 analysierten Elementen das mit dem größten Untersuchungsspektrum. Obwohl die in den Jahren 1998 und 1999 fertiggestellten Forschungsberichte (Siewers & Herpin, 1998; Siewers, Herpin & Straßburg, 1999) eine Auswertung (Kurzbeschreibung, statistische Maßzahlen, Verteilungskarten) aller 40 analysierten Elemente enthalten, wurden bislang nur die Daten von 12 der analysierten Elemente veröffentlicht. Darüber hinaus wurden im Jahr 2007 die im Ergebnis der Analytik vorliegenden Rohdaten aus den Laboratorien einer Neubewertung unterzogen. Daraus resultiert eine Reihe von Fehlerkorrekturen, das auswertbare Elementspektrum konnte auf 42 Elemente erweitert werden. Auch die Ergebnisse dieser Neubewertung sind bislang unveröffentlicht. Die ergänzende Bearbeitung der Daten mit modernen Verfahren bringt eine zusätzliche Aufwertung dieser. Die Downloads zeigen die Verteilung der Cergehalte in Moosen in vier verschiedenen farbigen Punkt- und Isoflächenkarten. Die Legenden der Karten sind wahlweise in der Maßeinheit µg/g oder in einer an den Gehaltsbereich des dargestellten Elements angepassten Maßeinheit abrufbar.
technologyComment of cobalt production (GLO): Cobalt, as a co-product of nickel and copper production, is obtained using a wide range of technologies. The initial life cycle stage covers the mining of the ore through underground or open cast methods. The ore is further processed in beneficiation to produce a concentrate and/or raffinate solution. Metal selection and further concentration is initiated in primary extraction, which may involve calcining, smelting, high pressure leaching, and other processes. The final product is obtained through further refining, which may involve processes such as re-leaching, selective solvent / solution extraction, selective precipitation, electrowinning, and other treatments. Transport is reported separately and consists of only the internal movements of materials / intermediates, and not the movement of final product. Due to its intrinsic value, cobalt has a high recycling rate. However, much of this recycling takes place downstream through the recycling of alloy scrap into new alloy, or goes into the cobalt chemical sector as an intermediate requiring additional refinement. Secondary production, ie production from the recycling of cobalt-containing wastes, is considered in this study in so far as it occurs as part of the participating companies’ production. This was shown to be of very limited significance (less than 1% of cobalt inputs). The secondary materials used for producing cobalt are modelled as entering the system free of environmental burden. technologyComment of natural gas production (CA-AB): Canadian data completed with german data. The uncertainty has been adjusted accordingly. Data used in original data contains no information on technology. technologyComment of natural gas production (DE): Data in environmental report contains no information on technology. technologyComment of natural gas production (RoW): The data describes an average onshore technology for natural gas to 13% out of combined oil gas production. Natural gas is assumed to 20% sour. Leakage in exploitation is estimated at 0.38% and production 0.12%. It is further assumed that about 30% of the produced water is discharged in surface water. Water emissions are differentiated between combined oil and gas production and gas production. technologyComment of natural gas production (RU): The data describes an average onshore technology for natural gas with a share of 4% out of combined oil gas production and 96% from mere natural gas production. Natural gas is assumed to 20% sour. It is assumed that about 30% of the produced water is discharged in surface water. Water emissions are differentiated between combined oil and gas production and gas production. technologyComment of natural gas production (US): US data (NREL) for emissions completed with german data. Emissions from NREL include combined production (petroleumm and gas) and off-shore production. The uncertainty has been adjusted accordingly. Data used in original data contains no information on technology. technologyComment of petroleum refinery operation (CH): Average data for the used technology. technologyComment of primary zinc production from concentrate (RoW): The technological representativeness of this dataset is considered to be high as smelting methods for zinc are consistent in all regions. Refined zinc produced pyro-metallurgically represents less than 5% of global zinc production and less than 2% of this dataset. Electrometallurgical Smelting The main unit processes for electrometallurgical zinc smelting are roasting, leaching, purification, electrolysis, and melting. In both electrometallurgical and pyro-metallurgical zinc production routes, the first step is to remove the sulfur from the concentrate. Roasting or sintering achieves this. The concentrate is heated in a furnace with operating temperature above 900 °C (exothermic, autogenous process) to convert the zinc sulfide to calcine (zinc oxide). Simultaneously, sulfur reacts with oxygen to produce sulfur dioxide, which is subsequently converted to sulfuric acid in acid plants, usually located with zinc-smelting facilities. During the leaching process, the calcine is dissolved in dilute sulfuric acid solution (re-circulated back from the electrolysis cells) to produce aqueous zinc sulfate solution. The iron impurities dissolve as well and are precipitated out as jarosite or goethite in the presence of calcine and possibly ammonia. Jarosite and goethite are usually disposed of in tailing ponds. Adding zinc dust to the zinc sulfate solution facilitates purification. The purification of leachate leads to precipitation of cadmium, copper, and cobalt as metals. In electrolysis, the purified solution is electrolyzed between lead alloy anodes and aluminum cathodes. The high-purity zinc deposited on aluminum cathodes is stripped off, dried, melted, and cast into SHG zinc ingots (99.99 % zinc). Pyro-metallurgical Smelting The pyro-metallurgical smelting process is based on the reduction of zinc and lead oxides into metal with carbon in an imperial smelting furnace. The sinter, along with pre-heated coke, is charged from the top of the furnace and injected from below with pre-heated air. This ensures that temperature in the center of the furnace remains in the range of 1000-1500 °C. The coke is converted to carbon monoxide, and zinc and lead oxides are reduced to metallic zinc and lead. The liquid lead bullion is collected at the bottom of the furnace along with other metal impurities (copper, silver, and gold). Zinc in vapor form is collected from the top of the furnace along with other gases. Zinc vapor is then condensed into liquid zinc. The lead and cadmium impurities in zinc bullion are removed through a distillation process. The imperial smelting process is an energy-intensive process and produces zinc of lower purity than the electrometallurgical process. technologyComment of rare earth oxides production, from rare earth oxide concentrate, 70% REO (CN-SC): This dataset refers to the separation (hydrochloric acid leaching) and refining (metallothermic reduction) process used in order to produce high-purity rare earth oxides (REO) from REO concentrate, 70% beneficiated. ''The concentrate is calcined at temperatures up to 600ºC to oxidize carbonaceous material. Then HCl leaching, alkaline treatment, and second HCl leaching is performed to produce a relatively pure rare earth chloride (95% REO). Hydrochloric acid leaching in Sichuan is capable of separating and recovering the majority of cerium oxide (CeO) in a short process. For this dataset, the entire quantity of Ce (50% cerium dioxide [CeO2]/REO) is assumed to be produced here as CeO2 with a grade of 98% REO. Foreground carbon dioxide CO2 emissions were calculated from chemical reactions of calcining beneficiated ores. Then metallothermic reduction produces the purest rare earth metals (99.99%) and is most common for heavy rare earths. The metals volatilize, are collected, and then condensed at temperatures of 300 to 400°C (Chinese Ministryof Environmental Protection 2009).'' Source: Lee, J. C. K., & Wen, Z. (2017). Rare Earths from Mines to Metals: Comparing Environmental Impacts from China's Main Production Pathways. Journal of Industrial Ecology, 21(5), 1277-1290. doi:10.1111/jiec.12491 technologyComment of scandium oxide production, from rare earth tailings (CN-NM): See general comment. technologyComment of sulfur production, petroleum refinery operation (Europe without Switzerland): The technology level in Europe applied here represents a weighted average of BREF types II (62%), III (29%), IV (9%) refineries; API 35; sulfur content 1.03%. technologyComment of sulfur production, petroleum refinery operation (PE): The technology represents BREF type II refinery; API 25; sulfur content 0.51% technologyComment of sulfur production, petroleum refinery operation (BR): The technology represents BREF type II refinery; API 25; sulfur content 0.57% technologyComment of sulfur production, petroleum refinery operation (ZA): The technology represents a weighted average of BREF types II and III refineries; API 35; sulfur content 0.7% technologyComment of sulfur production, petroleum refinery operation (CO): The technology represents a weighted average of BREF types II and IV refineries; API 35; sulfur content 0.56% technologyComment of sulfur production, petroleum refinery operation (IN): The technology represents a weighted average of BREF types II and IV refineries; API 35; sulfur content 1.39% technologyComment of sulfur production, petroleum refinery operation (RoW): This dataset represents the prevailing technology level in Europe, this is a weighted average of BREF complexity types II (62%), III (29%), IV (9%) refineries (see BREF document, European Commission, 2015); API 35; sulfur content 1.03%. Reference(s): European Commission (2015) Best Available Techniques (BAT) Reference Document (BREF) for the Refining of Mineral Oil and Gas, Industrial Emissions Directive 2010/75/EU Integrated Pollution Prevention and control, accessible online at http://eippcb.jrc.ec.europa.eu/reference/BREF/REF_BREF_2015.pdf, February 2019 technologyComment of synthetic fuel production, from coal, high temperature Fisher-Tropsch operations (ZA): SECUNDA SYNFUEL OPERATIONS: Secunda Synfuels Operations operates the world’s only commercial coal-based synthetic fuels manufacturing facility of its kind, producing synthesis gas (syngas) through coal gasification and natural gas reforming. They make use of their proprietary technology to convert syngas into synthetic fuel components, pipeline gas and chemical feedstock for the downstream production of solvents, polymers, comonomers and other chemicals. Primary internal customers are Sasol Chemicals Operations, Sasol Exploration and Production International and other chemical companies. Carbon is produced for the recarburiser, aluminium, electrode and cathodic production markets. Secunda Synfuels Operations receives coal from five mines in Mpumalanga (see figure attached). After being crushed, the coal is blended to obtain an even quality distribution. Electricity is generated by both steam and gas and used to gasify the coal at a temperature of 1300°C. This produces syngas from which two types of reactor - circulating fluidised bed and Sasol Advanced SynthoTM reactors – produce components for making synthetic fuels as well as a number of downstream chemicals. Gas water and tar oil streams emanating from the gasification process are refined to produce ammonia and various grades of coke respectively. imageUrlTagReplacea79dc0c2-0dda-47ec-94e0-6f076bc8cdb6 SECUNDA CHEMICAL OPERATIONS: The Secunda Chemicals Operations hub forms part of the Southern African Operations and is the consolidation of all the chemical operating facilities in Secunda, along with Site Services activities. The Secunda Chemicals hub produces a diverse range of products that include industrial explosives, fertilisers; polypropylene, ethylene and propylene; solvents (acetone, methyl ethyl ketone (MEK), ethanol, n-Propanol, iso-propanol, SABUTOL-TM, PROPYLOL-TM, mixed C3 and C4 alcohols, mixed C5 and C6 alcohols, High Purity Ethanol, and Ethyl Acetate) as well as the co-monomers, 1-hexene, 1-pentene and 1-octene and detergent alcohol (SafolTM).
technologyComment of iron ore beneficiation (IN): Milling and mechanical sorting. Average iron yield is 65% . The process so developed basically involves crushing, classification, processing of lumps, fines and slimes separately to produce concentrate suitable as lump and sinter fines and for pellet making. The quality is essentially defined as Fe contents, Level of SiO2 and Al2O3 contamination. The process aims at maximizing Fe recovery by subjecting the rejects/tailings generated from coarser size processing to fine size reduction and subsequent processing to recover iron values. technologyComment of iron ore beneficiation (RoW): Milling and mechanical sorting. Average iron yield is 84%. technologyComment of iron ore mine operation and beneficiation (CA-QC): Milling and mechanical sorting. Average iron yield is 75%. Specific data were collected on one of the two production site in Quebec. According to the documentation available, the technologies of the 2 mines seems similar. Uncertainity has been adjusted accordingly. technologyComment of niobium mine operation and beneficiation, from pyrochlore ore (BR, RoW): Open-pit mining is applied and hydraulic excavators are used to extract the ore with different grades, which is transported to stockpiles awaiting homogenization through earth-moving equipment in order to attain the same concentration. Conveyor belts (3.5 km) are utilized to transport the homogenized ore to the concentration unit. Initially, the ore passes through a jaw crusher and moves to the ball mills, where the pyrochlore grains (1 mm average diameter) are reduced to diameters less than 0.104 mm. In the ball mills, recycled water is added in order to i) granulate the concentrate and ii) remove the gas from the sintering unit. The granulated ore undergoes i) magnetic separation, where magnetite is removed and is sold as a coproduct and ii) desliming in order to remove fractions smaller than 5μm by utilizing cyclones. Then the ore enters the flotation process - last stage of the beneficiation process – where the pyrochlore particles come into contact with flotation chemicals (hydrochloric & fluorosilic acid, triethylamene and lime), thereby removing the solid fractions and producing pyrochlore concentrate and barite as a coproduct which is also sold. The produced concentrate contains 55% Nb2O5 and 11% water and moves to the sintering unit, via tubes or is transported in bags while the separated and unused minerals enter the tailings dam. In the sintering unit, the pyrochlore concentrate undergoes pelletizing, sintering, crushing and classification. These units not only accumulate the material but are also responsible for removing sulfur and water from the concentrate. Then the concentrate enters the dephosphorization unit, where phosphorus and lead are removed from the concentrate. The removal of sulphur and phosphorus have to be executed because of the local pyrochlore ore composition. Then the concentrate undergoes a carbothermic reduction by using charcoal and petroleum coke, producing a refined concentrate, 63% Nb2O5 and tailings with high lead content that are disposed in the tailings dam again. technologyComment of rare earth element mine operation and beneficiation, bastnaesite and monazite ore (CN-NM): Firstly, open pit, mining (drilling and blasting) is performed in order to obtain the iron ore and a minor quantity of rare earth ores (5−6 % rare earth oxide equivalent). Then, a two-step beneficiation process is applied to produce the REO concentrate. In the first step, ball milling and magnetic separation is used for the isolation of the iron ore. In the second step, the resulting REO tailing (containing monazite and bastnasite), is processed to get a 50% REO equivalent concentrate via flotation. technologyComment of rare earth oxides production, from rare earth oxide concentrate, 70% REO (CN-SC): This dataset refers to the separation (hydrochloric acid leaching) and refining (metallothermic reduction) process used in order to produce high-purity rare earth oxides (REO) from REO concentrate, 70% beneficiated. ''The concentrate is calcined at temperatures up to 600ºC to oxidize carbonaceous material. Then HCl leaching, alkaline treatment, and second HCl leaching is performed to produce a relatively pure rare earth chloride (95% REO). Hydrochloric acid leaching in Sichuan is capable of separating and recovering the majority of cerium oxide (CeO) in a short process. For this dataset, the entire quantity of Ce (50% cerium dioxide [CeO2]/REO) is assumed to be produced here as CeO2 with a grade of 98% REO. Foreground carbon dioxide CO2 emissions were calculated from chemical reactions of calcining beneficiated ores. Then metallothermic reduction produces the purest rare earth metals (99.99%) and is most common for heavy rare earths. The metals volatilize, are collected, and then condensed at temperatures of 300 to 400°C (Chinese Ministryof Environmental Protection 2009).'' Source: Lee, J. C. K., & Wen, Z. (2017). Rare Earths from Mines to Metals: Comparing Environmental Impacts from China's Main Production Pathways. Journal of Industrial Ecology, 21(5), 1277-1290. doi:10.1111/jiec.12491 technologyComment of scandium oxide production, from rare earth tailings (CN-NM): See general comment. technologyComment of vanadium-titanomagnetite mine operation and beneficiation (CN): Natural rutile resources are scarce in China. For that reason, the production of titanium stems from high-grade titanium slag, the production of which includes 2 processes: i) ore mining & dressing process and ii) titanium slag smelting process. During the ore mining and dressing process, ilmenite concentrate (47.82% TiO2) is produced through high-intensity magnetic separation of the middling ore, which is previously produced as a byproduct during the magnetic separation sub-process of the vanadium titano-magnetite ore. During the titanium slag smelting process, the produced ilmenite concentrate from the ore mining & dressing process is mixed with petroleum coke as the reducing agent and pitch as the bonding agent. Afterwards it enters the electric arc furnace, where it is smelted, separating iron from the ilmenite concentrate and obtaining high-grade titanium slag.
Objective: The recycling business is traditionally dominated by SMEs. In the last 5 years a general trend in the electronics recycling sector to bigger companies is very visible. Multinational, multi-sector companies are buying several smaller recyclers every year. Hence the previous project HydroWEEE (03/200902/2012) dealt with the recovery of rare and precious metals from WEEE. The idea has been to develop a mobile plant using hydrometallurgical processes to extract metals like yttrium, indium, lithium, cobalt, zinc, copper, gold, silver, nickel, lead, tin in a high purity. By making this plant mobile several SMEs can benefit from the same plant. By making the processes universal several fractions (lamps, CRTs, LCDs, printed circuit boards and Li-batteries) can be treated in the same mobile plant in batches. This reduces the minimum quantities and necessary investments. In addition these innovative HydroWEEE processes produce pure enough materials that can be directly used for electroplating and other applications. The objective of HydroWEEE Demo is to build 2 industrial, real-life demonstration plants (1 stationary and 1 mobile) in order to test the performance and prove the viability of the processes from an integrated point of view (technical, economical, operational, social) including the assessment of its risks (incl. health) and benefits to the society and the environment as well as remove the barriers for a wide market uptake. Finally the previously developed processes of extracting yttrium, indium, lithium, cobalt, zinc, copper, gold, silver, nickel, lead, tin will be improved and new processes to recover additional metals which are still in this fractions (Cerium, Platinum, Palladium, Europium, Lanthanum, Terbium, ) as well as the integrated treatment of solid and liquid wastes will be developed. Summarized HydroWEEE Demo will boost European competitiveness by applying novel processes for improved resource efficiency by extracting rare and precious metals.
technologyComment of rare earth oxides production, from rare earth oxide concentrate, 70% REO (CN-SC): This dataset refers to the separation (hydrochloric acid leaching) and refining (metallothermic reduction) process used in order to produce high-purity rare earth oxides (REO) from REO concentrate, 70% beneficiated. ''The concentrate is calcined at temperatures up to 600ºC to oxidize carbonaceous material. Then HCl leaching, alkaline treatment, and second HCl leaching is performed to produce a relatively pure rare earth chloride (95% REO). Hydrochloric acid leaching in Sichuan is capable of separating and recovering the majority of cerium oxide (CeO) in a short process. For this dataset, the entire quantity of Ce (50% cerium dioxide [CeO2]/REO) is assumed to be produced here as CeO2 with a grade of 98% REO. Foreground carbon dioxide CO2 emissions were calculated from chemical reactions of calcining beneficiated ores. Then metallothermic reduction produces the purest rare earth metals (99.99%) and is most common for heavy rare earths. The metals volatilize, are collected, and then condensed at temperatures of 300 to 400°C (Chinese Ministryof Environmental Protection 2009).'' Source: Lee, J. C. K., & Wen, Z. (2017). Rare Earths from Mines to Metals: Comparing Environmental Impacts from China's Main Production Pathways. Journal of Industrial Ecology, 21(5), 1277-1290. doi:10.1111/jiec.12491 technologyComment of sodium chloride production, powder (RER, RoW): For the production of dry salt, three different types of sodium chloride production methods can be distinguished namely, underground mining of halite deposits, solution mining with mechanical evaporation and solar evaporation. Their respective products are rock salt, evaporated salt and solar salt: - Underground mining: The main characteristic of this technique is the fact that salt is not dissolved during the whole process. Instead underground halite deposits are mined with traditional techniques like undercutting, drilling and blasting or with huge mining machines with cutting heads. In a second step, the salt is crushed and screened to the desired size and then hoisted to the surface. - Solution mining and mechanical evaporation: In this case, water is injected in a salt deposit, usually in about 150 to 500 m depth. The dissolution of the halite or salt deposits forms a cavern filled with brine. This brine is then pumped from the cavern back to the surface and transported to either an evaporation plant for the production of evaporated salt or transported directly to a chemical processing plant, e.g. a chlor-alkali plant. - Solar evaporation: In this case salt is produced with the aid of the sun and wind out of seawater or natural brine in lakes. Within a chain of ponds, water is evaporated by sun until salt crystallizes on the floor of the ponds. Due to their natural process drivers, such plants must be located in areas with only small amounts of rain and high evaporation rates - e.g. in the Mediterranean area where the rate between evaporation and rainfall is 3:1, or in Australia, where even a ratio up to 15:1 can be found. There are some impurities due to the fact that seawater contains not only sodium chloride. That leads to impurities of calcium and magnesium sulfate as well as magnesium chloride. With the aid of clean brine from dissolved fine salt, these impurities are washed out. As a fourth form on the market, the so-called 'salt in brine' may be found, which is especially used for the production of different chemicals. In this case, the solution mining technique without an evaporation step afterwards is used. This dataset represents the production of dry sodium chloride by underground mining (51%) and by solution mining (49%) with modern solution mining technology (thermo compressing technology). References: Althaus H.-J., Chudacoff M., Hischier R., Jungbluth N., Osses M. and Primas A. (2007) Life Cycle Inventories of Chemicals. ecoinvent report No. 8, v2.0. EMPA Dübendorf, Swiss Centre for Life Cycle Inventories, Dübendorf, CH.
Liquid hydrocarbon fuels are ideal energy carriers for the transportation sector due to their exceptionally high energy density and most convenient handling, without requiring changes in the existing global infrastructure. Currently, virtually all renewable hydrocarbon fuels originate from biomass. Their feasibility to meet the global fuel demand and their environmental impact are controversial. In contrast, SUN-to-LIQUID has the potential to cover future fuel consumption as it establishes a radically different non-biomass non-fossil path to synthesize renewable liquid hydrocarbon fuels from abundant feedstocks of H2O, CO2 and solar energy. Concentrated solar radiation drives a thermochemical redox cycle, which inherently operates at high temperatures and utilizes the full solar spectrum. Thereby, it provides a thermodynamically favourable path to solar fuel production with high energy conversion efficiency and, consequently, economic competitiveness. Recently, the first-ever production of solar jet fuel has been experimentally demonstrated at laboratory scale using a solar reactor containing a ceria-based reticulated porous structure undergoing the redox cyclic process. SUN-to-LIQUID aims at advancing this solar fuel technology from the laboratory to the next field phase: expected key innovations include an advanced high-flux ultra-modular solar heliostat field, a 50 kW solar reactor, and optimized redox materials to produce synthesis gas that is subsequently processed to liquid hydrocarbon fuels. The complete integrated fuel production chain will be experimentally validated at a pre-commercial scale and with record high energy conversion efficiency. The ambition of SUN-to-LIQUID is to advance solar fuels well beyond the state of the art and to guide the further scale-up towards a reliable basis for competitive industrial exploitation. Large-scale solar fuel production is expected to have a major impact on a sustainable future transportation sector.
Es werden synergistische & anatagonistische Toxizitätsmechanismen von Gemischen bestehend aus Nanopartikeln & löslichen Chemikalien in unterschiedlichen Leberzelllinien & Primärhepatozyten untersucht. Als Beispielsubstanzen werden hierbei Ceriumdioxid Nanopartikel und Paracetamol sowohl als Einzelsubstanzen als auch als Substanzgemische exponiert. Neben der Bestimmung von Überlebensraten und der Gentoxizität werden Studien zur Veränderung von Metabolitmustern im Gesamtmetabolom nach Exposition vermittels massenspektrometrischer Analytik durchgeführt. Bei denjenigen Zellkulturansätzen, bei denen sich charakteristische Toxizitätsmerkmale oder signifikante Veränderungen im Gesamtmetabolom zeigen, werden detaillierte Analysen zur Partikelverteilung sowie Biokinetikstudien zur Partikelaufnahme vermittels bildgebender Massenspektrometrie durchgeführt. Die Ergebnisse der Arbeiten sollen aufzeigen ob und wenn ja durch welche Mechanismen sich toxikologisch relevante Wirkmechanismen in den Zellkulturen manifestieren. Die so gewonnenen Daten sollen der Weiterentwicklung der Risikobewertung von Nanomaterialien und regulatorischen Zwecken dienen.
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